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Original contributions reporting novel, important findings of fundamental research in all branches of the theory and practice of organic and bioorganic chemistry.

Editors: C. Dale Poulter & Associate Editors

Volume: 73, 24 issues

ACS Division of Organic Chemistry

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Web Release Date: May 16, 2008

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Synthesis and Structure−Activity Relationship Study of Isoglobotrihexosylceramide Analogues
Wenlan Chen, Chengfeng Xia, Jinhua Wang, Prakash Thapa, Yusen Li, Arindam Talukdar, Janos Nadas, Wenpeng Zhang, Dapeng Zhou, and Peng George Wang
Web Release Date: 16-May-2008; (Addition/Correction) DOI: 10.1021/jo8007918

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Web Release Date: May 15, 2008

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Expedient Synthesis of N-Methyl Tubulysin Analogues with High Cytotoxicity
Andrew W. Patterson, Hillary M. Peltier, and Jonathan A. Ellman
Web Release Date: 15-May-2008; (Featured Article) DOI: 10.1021/jo800384x

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Sequential One-Pot Glycosidations Catalytically Promoted: Unprecedented Strategy in Oligosaccharide Synthesis for the Straightforward Assemblage of the Antitumor PI-88 Pentasaccharide
Silvia Valerio, Antonello Pastore, Matteo Adinolfi, and Alfonso Iadonisi
Web Release Date: 15-May-2008; (Article) DOI: 10.1021/jo8003953

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An Activated Sulfonylating Agent That Undergoes General Base-Catalyzed Hydrolysis by Amines in Preference to Aminolysis
Wing Y. Tsang, Naveed Ahmed, Karl Hemming, and Michael I. Page
Web Release Date: 15-May-2008; (Article) DOI: 10.1021/jo800407x

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Rate Constants and Arrhenius Functions for Ring Opening of a Cyclobutylcarbinyl Radical Clock and for Hydrogen Atom Transfer From the Et₃B−MeOH Complex
Jing Jin and Martin Newcomb
Web Release Date: 15-May-2008; (Note) DOI: 10.1021/jo800500e

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Web Release Date: May 14, 2008

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Stable Ion and Electrophilic Chemistry of the Sterically Crowded Stilbene 1,1′-Bi(benzocyclobutenylidene) and Its Derivatives
Kenneth K. Laali, Takao Okazaki, Scott D. Bunge, and Dieter Lenoir
Web Release Date: 14-May-2008; (Article) DOI: 10.1021/jo800175d

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Highly β-(E)-Selective Hydrosilylation of Terminal and Internal Alkynes Catalyzed by a (IPr)Pt(diene) Complex
Guillaume Berthon-Gelloz, Jean-Marc Schumers, Guillaume De Bo, and István E. Markó
Web Release Date: 14-May-2008; (Article) DOI: 10.1021/jo800411e

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Superacid-Catalyzed Intramolecular Cyclization Reaction of Arylcyanopropionate: Geminal Substitution Effect on Superelectrophilicity
Satoshi Nakamura, Hiromichi Sugimoto, and Tomohiko Ohwada
Web Release Date: 14-May-2008; (Article) DOI: 10.1021/jo800674h

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Web Release Date: May 13, 2008

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Bisphosphonate Derivatives of Nucleoside Antimetabolites: Hydrolytic Stability and Hydroxyapatite Adsorption of 5′-β,γ-Methylene and 5′-β,γ-(1-Hydroxyethylidene) Triphosphates of 5-Fluorouridine and ara-Cytidine
Mikko Ora, Tuomas Lönnberg, Diana Florea-Wang, Shawn Zinnen, Alexander Karpeisky, and Harri Lönnberg
Web Release Date: 13-May-2008; (Article) DOI: 10.1021/jo800317e

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Total Synthesis of (−)-Martinellic Acid via Radical Addition−Cyclization−Elimination Reaction
Atsushi Shirai, Okiko Miyata, Norimitsu Tohnai, Mikiji Miyata, David J. Procter, David Sucunza, and Takeaki Naito
Web Release Date: 13-May-2008; (Article) DOI: 10.1021/jo800560p

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Quaternary Ammonium Bromide Functionalized Polyethylene Glycol: A Highly Efficient and Recyclable Catalyst for Selective Synthesis of 5-Aryl-2-oxazolidinones from Carbon Dioxide and Aziridines Under Solvent-Free Conditions
Ya Du, Ying Wu, An-Hua Liu, and Liang-Nian He
Web Release Date: 13-May-2008; (Note) DOI: 10.1021/jo800269v

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Electrophile-Induced Cyclization/Migration Reaction for the Synthesis of 2,3-Dihydro-5-iodopyran-4-one
Shu-Guang Wen, Wei-Min Liu, and Yong-Min Liang
Web Release Date: 13-May-2008; (Note) DOI: 10.1021/jo800556e

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Web Release Date: May 10, 2008

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Stereostructure Assignment of Flexible Five-Membered Rings by GIAO ¹³C NMR Calculations: Prediction of the Stereochemistry of Elatenyne
Steven G. Smith, Robert S. Paton, Jonathan W. Burton, and Jonathan M. Goodman
Web Release Date: 10-May-2008; (Article) DOI: 10.1021/jo8003138

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Synthesis and Electrochemical Properties of Peripheral Carbazole Functional Ter(9,9-spirobifluorene)s
Shi Tang, Meirong Liu, Cheng Gu, Yang Zhao, Ping Lu, Dan Lu, Linlin Liu, Fangzhong Shen, Bing Yang, and Yuguang Ma
Web Release Date: 10-May-2008; (Article) DOI: 10.1021/jo8006094

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Iminyl Radicals from α-Azido o-Iodoanilides via 1,5-H Transfer Reactions of Aryl Radicals: New Transformation of α-Azido Acids to Decarboxylated Nitriles
Giorgio Bencivenni, Tommaso Lanza, Rino Leardini, Matteo Minozzi, Daniele Nanni, Piero Spagnolo, and Giuseppe Zanardi
Web Release Date: 10-May-2008; (Note) DOI: 10.1021/jo800453z

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Synthesis of N-Substituted Indole-3-carboxylic Acid Derivatives via Cu(I)-Catalyzed Intramolecular Amination of Aryl Bromides
Ferdinand S. Melkonyan, Alexander V. Karchava, and Marina A. Yurovskaya
Web Release Date: 10-May-2008; (Note) DOI: 10.1021/jo800630v

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Web Release Date: May 9, 2008

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Synthetic Studies on Amipurimycin: Total Synthesis of a Thymine Nucleoside Analogue
Christina S. Stauffer and Apurba Datta
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/jo8004815

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Intrinsic Conformational Preferences of C^α,α-Dibenzylglycine
Jordi Casanovas, Ruth Nussinov, and Carlos Alemán
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/jo8005528

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Web Release Date: May 8, 2008

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Synthesis of Bis-18,18′-desmethyl Ritterazine N
Douglass F. Taber and Jean-Michel Joerger
Web Release Date: 08-May-2008; (Article) DOI: 10.1021/jo800454w

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Synthetic Applications with Use of a Silica-Supported Alkyne Metathesis Catalyst
Hyeon Mo Cho, Haim Weissman, and Jeffrey S. Moore
Web Release Date: 08-May-2008; (Note) DOI: 10.1021/jo8003919