Organometallics Home Page (ACS Publications)

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Reporting progress in one of the most active fields for organometallic, inorganic, organic and materials chemists detailing the synthesis, structure, bonding, chemical reactivity and reaction mechanisms, and applications of organometallic and organometalloidal compounds.

Editors: Dietmar Seyferth & Associate Editors

Volume: 27, 24 issues

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The following list of Articles ASAP is limited to the latest 20 articles. Visit the All Articles ASAP page for the complete listing.

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Web Release Date: May 15, 2008

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Homoleptic Complexes of Bisstannylenes with Nickel(0): Synthesis, X-Ray Diffraction Studies, and ¹¹⁹Sn NMR Investigations
Alexander V. Zabula, Tania Pape, Alexander Hepp, and F. Ekkehardt Hahn
Web Release Date: 15-May-2008; (Article) DOI: 10.1021/om800096f

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Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Sachiko Arita, Takashi Koike, Yoshihito Kayaki, and Takao Ikariya
Web Release Date: 15-May-2008; (Article) DOI: 10.1021/om800124f

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Web Release Date: May 14, 2008

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Thermodynamics of N-Heterocyclic Carbene Dimerization: The Balance of Sterics and Electronics
Albert Poater, Francesco Ragone, Simona Giudice, Chiara Costabile, Reto Dorta, Steven P. Nolan, and Luigi Cavallo
Web Release Date: 14-May-2008; (Communication) DOI: 10.1021/om8001119

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Benzene Hydrogenation by Silica-Supported Catalysts Made of Palladium Nanoparticles and Electrostatically Immobilized Rhodium Single Sites
Pierluigi Barbaro, Claudio Bianchini, Vladimiro Dal Santo, Andrea Meli, Simonetta Moneti, Claudio Pirovano, Rinaldo Psaro, Laura Sordelli, and Francesco Vizza
Web Release Date: 14-May-2008; (Article) DOI: 10.1021/om800223d

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Web Release Date: May 13, 2008

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Reactivity of Cp*Mo(NO)(CHCMe₃) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Peter M. Graham, Miriam S. A. Buschhaus, Craig B. Pamplin, and Peter Legzdins
Web Release Date: 13-May-2008; (Article) DOI: 10.1021/om800157s

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Web Release Date: May 10, 2008

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Introduction to the Review by Schmidbaur and Schier in This Issue of Organometallics
Dietmar Seyferth
Web Release Date: 10-May-2008; (Editorial) DOI: 10.1021/om800287q

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Enhanced Charge-Carrier Mobility Derived from Cyclization of a Silanylene Unit on Dithienosiloles: Syntheses, Photophysical Properties, and Device Fabrication of Dithieno-spiro-siloles
Ho-Jin Son, Won-Sik Han, Ji-Yun Chun, Soon-Nam Kwon, Jaejung Ko, and Sang Ook Kang
Web Release Date: 10-May-2008; (Article) DOI: 10.1021/om7012088

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Silapentadienyl−Iridium−Phosphine Chemistry¹
John R. Bleeke, Todsapon Thananatthanachon, and Nigam P. Rath
Web Release Date: 10-May-2008; (Article) DOI: 10.1021/om800041b

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Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Daniela I. Bezuidenhout, Elisia van der Watt, David C. Liles, Marilé Landman, and Simon Lotz
Web Release Date: 10-May-2008; (Article) DOI: 10.1021/om8001735

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π-Complexation of Post-Transition Metals by Neutral Aromatic Hydrocarbons: The Road from Observations in the 19th Century to New Aspects of Supramolecular Chemistry
Hubert Schmidbaur and Annette Schier
Web Release Date: 10-May-2008; (Review/Perspective) DOI: 10.1021/om701044e

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Web Release Date: May 9, 2008

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Influence of the Spacer Length on the in Vitro Anticancer Activity of Dinuclear Ruthenium−Arene Compounds
Maria-Grazia Mendoza-Ferri, Christian G. Hartinger, Rene E. Eichinger, Natalya Stolyarova, Kay Severin, Michael A. Jakupec, Alexey A. Nazarov, and Bernhard K. Keppler
Web Release Date: 09-May-2008; (Communication) DOI: 10.1021/om800207t

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A Measure for σ-Donor and π-Acceptor Properties of Diiminepyridine-Type Ligands
Di Zhu and Peter H. M. Budzelaar
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/om701160b

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Palladium-Catalyzed Deallylation of Allyl Ethers with a Xanthene Phosphole Ligand. Experimental and DFT Mechanistic Studies
Guilhem Mora, Olivier Piechaczyk, Xavier F. Le Goff, and Pascal Le Floch
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/om800051n

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Structure and Properties of the Macrocyclic Tridentate Ferrocenylphosphine Ligand (−PhPC₅H₄FeC₅H₄−)₃
Tsutomu Mizuta, Tomoyuki Aotani, Yuki Imamura, Kazuyuki Kubo, and Katsuhiko Miyoshi
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/om800057w

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Cationic, Neutral, and Anionic Platinum(II) Complexes Based on an Electron-Rich PNN Ligand. New Modes of Reactivity Based on Pincer Hemilability and Dearomatization
Dana Vuzman, Elena Poverenov, Linda J. W. Shimon, Yael Diskin-Posner, and David Milstein
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/om8001069

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Rate and Mechanism of the Oxidative Addition of Aryl Halides to Palladium(0) Complexes Generated in Situ from a Pd(0)−Triolefinic Macrocyclic Complex and Phosphines
Anna Serra-Muns, Anny Jutand, Marcial Moreno-Mañas, and Roser Pleixats
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/om800135n

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Synthesis and Structural Analysis of (Arylimido)vanadium(V) Complexes Containing Phenoxyimine Ligands: New, Efficient Catalyst Precursors for Ethylene Polymerization
Yoshifumi Onishi, Shohei Katao, Michiya Fujiki, and Kotohiro Nomura
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/om800177g

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Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene
William Clegg, Joaquín García-Álvarez, Pablo García-Álvarez, David V. Graham, Ross W. Harrington, Eva Hevia, Alan R. Kennedy, Robert E. Mulvey, and Luca Russo
Web Release Date: 09-May-2008; (Article) DOI: 10.1021/om8001813

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Iridium Complexes in Olefination Reactions
Hélène Lebel and Chehla Ladjel
Web Release Date: 09-May-2008; (Note) DOI: 10.1021/om800255c

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Web Release Date: May 8, 2008

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Isovalent Gold(I), -(II), and -(III) and Mixed-Valent Gold(I)/Gold(III) Phosphorus Ylide Complexes. Combined ab Initio and Density Functional Study of Electronic Structures and Spectroscopic Properties
Qing-Jiang Pan, Xin Zhou, Hong-Gang Fu, and Hong-Xing Zhang
Web Release Date: 08-May-2008; (Article) DOI: 10.1021/om701114z