Rudolph A. Marcus
Rudolph A. Marcus of the California Institute of Technology was awarded the Nobel Prize in Chemistry in 1992 "for his contributions to the theory of electron transfer reactions in chemical systems." View the Rudolph A. Marcus Festschrift in The Journal of Physical Chemistry, and read the editorial from the Festschrift.
The following 50+ articles by Prof. Marcus are included in the ACS Legacy Archives:
Global Potential Energy Contour Plots for Chemical Reactions. Stepwise vs Concerted 2 + 2 Cycloaddition
R. A. Marcus
J. Am. Chem. Soc.; 1995; 117(16); 4683-4690.
Theoretical Study of Electron Transfer in Ferrocytochromes
A. A. Stuchebrukhov, R. A. Marcus
J. Phys. Chem.; 1995; 99(19); 7581-7590.
Theory of Electron Transfer Rates across Liquid-Liquid Interfaces [Erratum to document cited in CA114:51796]
R. A. Marcus
J. Phys. Chem.; 1995; 99(15); 5742-5742.
Theory of Electron Transfer Rates across Liquid-Liquid Interfaces. 2. Relationships and Applications. [Erratum to document cited in CA114:110532]
R. A. Marcus
J. Phys. Chem.; 1995; 99(15); 5742-5742.
IVR in Overtones of the Acetylenic C-H Stretch in Propyne
Aseem Mehta, A. A. Stuchebrukhov, R. A. Marcus
J. Phys. Chem.; 1995; 99(9); 2677-2683.
Free Energy of Nonequilibrium Polarization Systems. 4. A Formalism Based on the Nonequilibrium Dielectric Displacement
R. A. Marcus
J. Phys. Chem.; 1994; 98(29); 7170-7174.
Decay and Recurrences of Wave Packets in Nonlinear Quantum Systems
A. A. Stuchebrukhov, R. A. Marcus
J. Phys. Chem.; 1994; 98(13); 3285-3289.
Correlation between theory and experiment in electron-transfer reactions in proteins: electronic couplings in modified cytochrome c and myoglobin derivatives
Prabha Siddarth, R. A. Marcus
J. Phys. Chem.; 1993; 97(50); 13078-13082.
Vibrational superexchange mechanism of intramolecular vibrational relaxation in 3,3-dimethylbut-1-yne molecules
A. A. Stuchebrukhov, A. Mehta, R. A. Marcus
J. Phys. Chem.; 1993; 97(48); 12491-12499.
Electron-transfer reactions in proteins: electronic coupling in myoglobin
Prabha Siddarth, R. A. Marcus
J. Phys. Chem.; 1993; 97(23); 6111-6114.
Electron-transfer reactions in proteins: an artificial intelligence approach to electronic coupling
Prabha Siddarth, R. A. Marcus
J. Phys. Chem.; 1993; 97(10); 2400-2405.
Calculation of electron-transfer matrix elements of bridged systems using a molecular fragment approach
Prabha Siddarth, R. A. Marcus
J. Phys. Chem.; 1992; 96(8); 3213-3217.
Schroedinger equation for strongly interacting electron-transfer systems
R. A. Marcus
J. Phys. Chem.; 1992; 96(4); 1753-1757.
Global potential energy contour plots for chemical reactions: multiple reaction paths, bifurcations, and applicability of transition-state theory
R. A. Marcus
J. Phys. Chem.; 1991; 95(21); 8236-8243.
Theory of electron-transfer rates across liquid-liquid interfaces. 2. Relationships and application
R. A. Marcus
J. Phys. Chem.; 1991; 95(5); 2010-2013.
Electron-transfer reactions in proteins: a calculation of electronic coupling
Prabha Siddarth, R. A. Marcus
J. Phys. Chem.; 1990; 94(22); 8430-8434.
Theory of electron-transfer rates across liquid-liquid interfaces [Erratum to document cited in CA112(24):225352x]
R. A. Marcus
J. Phys. Chem.; 1990; 94(19); 7742-7742.
Theory of charge-transfer spectra in frozen media
R. A. Marcus
J. Phys. Chem.; 1990; 94(12); 4963-4966.
Theory of electron-transfer rates across liquid-liquid interfaces
R. A. Marcus
J. Phys. Chem.; 1990; 94(10); 4152-4155.
Dynamics of electron transfer for a nonsuperexchange coherent mechanism. 2. Numerical calculations
R. Almeida, R. A. Marcus
J. Phys. Chem.; 1990; 94(7); 2978-2985.
Comparison of experimental and theoretical electronic matrix elements for long-range electron transfer
Prabha Siddarth, R. A. Marcus
J. Phys. Chem.; 1990; 94(7); 2985-2989.
Dynamics of electron transfer for a nonsuperexchange coherent mechanism. 1
R. A. Marcus, R. Almeida
J. Phys. Chem.; 1990; 94(7); 2973-2977.
Reorganization free energy for electron transfers at liquid-liquid and dielectric semiconductor-liquid interfaces
R. A. Marcus
J. Phys. Chem.; 1990; 94(3); 1050-1055.
Relation between charge transfer absorption and fluorescence spectra and the inverted region
R. A. Marcus
J. Phys. Chem.; 1989; 93(8); 3078-3086.
Unimolecular reaction rate theory for highly flexible transition states. 2. Conventional coordinate formulas for the various possible fragment combinations: miscellaneous topics
Stephen J. Klippenstein, R. A. Marcus
J. Phys. Chem.; 1988; 92(19); 5412-5417.
Unimolecular reaction rate theory for highly flexible transition states: use of conventional coordinates
Stephen J. Klippenstein, R. A. Marcus
J. Phys. Chem.; 1988; 92(11); 3105-3109.
Unimolecular reaction rate theory for transition states of any looseness. 3. Application to methyl radical recombination
David M. Wardlaw, R. A. Marcus
J. Phys. Chem.; 1986; 90(21); 5383-5393.
Theory, experiment, and reaction rates. A personal view
R. A. Marcus
J. Phys. Chem.; 1986; 90(16); 3460-3465.
Mutual orientation effects on electron transfer between porphyrins
Robert J. Cave, Paul Siders, R. A. Marcus
J. Phys. Chem.; 1986; 90(7); 1436-1444.
Semiclassical dressed state theory for the vibrational excitation of a Morse oscillator by radiation
Gregory A. Voth, R. A. Marcus
J. Phys. Chem.; 1985; 89(11); 2208-2213.
RRKM and non-RRKM behavior in chemical activation and related studies
R. A. Marcus, William L. Hase, Kandadai Swamy
J. Phys. Chem.; 1984; 88(26); 6717-6720.
Semiclassical and quantum vibrational intensities
D. M. Wardlaw, D. W. Noid, R. A. Marcus
J. Phys. Chem.; 1984; 88(3); 536-547.
Densities of vibrational states of given symmetry species and their use in statistical estimates involving Coriolis and anharmonic effects
Steven M. Lederman, John H. Runnels, R. A. Marcus
J. Phys. Chem.; 1983; 87(22); 4364-4367.
Methods for plotting trajectories for triatomic molecules and visualizing the caustics
D. W. Noid, D. M. Wardlaw, M. L. Koszykowski, R. A. Marcus
J. Phys. Chem.; 1983; 87(15); 2733-2738.
Unimolecular reactions at low energies and RRKM behavior: isomerization and dissociation
L. R. Khundkar, R. A. Marcus, A. H. Zewail
J. Phys. Chem.; 1983; 87(14); 2473-2476.
Semiclassical theory of intensities of vibrational fundamentals, overtones, and combination bands
M. L. Koszykowski, D. W. Noid, R. A. Marcus
J. Phys. Chem.; 1982; 86(12); 2113-2117.
Theory of highly exothermic electron transfer reactions
R. A. Marcus, Paul Siders
J. Phys. Chem.; 1982; 86(5); 622-630.
Quantum effects in electron-transfer reactions
P. Siders, R. A. Marcus
J. Am. Chem. Soc.; 1981; 103(4); 741-747.
Quantum effects for electron-transfer reactions in the "inverted region"
P. Siders, R. A. Marcus
J. Am. Chem. Soc.; 1981; 103(4); 748-752.
Semiclassical comparison of quasi-classical and quantum moments of distribution of state in molecular collisions
R. A. Marcus
J. Phys. Chem.; 1979; 83(8); 944-946.
Vibrational nonadiabaticity and tunneling effects in transition state theory
R. A. Marcus
J. Phys. Chem.; 1979; 83(1); 204-207.
Electron-transfer reactions with unusual activation parameters. Treatment of reactions accompanied by large entropy decreases
R. A. Marcus, N. Sutin
Inorg. Chem.; 1975; 14(1); 213-216.
Unusual slopes of free energy plots in kinetics
Rudolph A. Marcus
J. Am. Chem. Soc.; 1969; 91(26); 7224-7225.
ON THE THEORY OF OXIDATION-REDUCTION REACTIONS INVOLVING ELECTRON TRANSFER. V. COMPARISON AND PROPERTIES OF ELECTROCHEMICAL AND CHEMICAL RATE CONSTANTS1
R. A. Marcus
J. Phys. Chem.; 1963; 67(4); 853-857.
Highly Sensitive Low Temperature Fractionation Method for Separation and Measurement of Boron Hydrides.
W. C. Kreye, R. A. Marcus
Anal. Chem.; 1962; 34(12); 1665-1666.
Kinetic Studies of Nitration with Nitronium Fluoroborate1
L. L. Ciaccio, R. A. Marcus
J. Am. Chem. Soc.; 1962; 84(10); 1838-1841.
ACTIVITY COEFFICIENTS OF BIPOLAR ELECTROLYTES. SILVER SUCCINATE AND SEBACATE IN AQUEOUS SODIUM NITRATE1
F. R. Meeks, R. A. Marcus
J. Phys. Chem.; 1961; 65(2); 306-309.
Ionic Polymerization. IX. The Effect of Water in the Cationic Polymerization of Styrene Catalyzed by Stannic Chloride1
C. G. Overberger, R. J. Ehrig, R. A. Marcus
J. Am. Chem. Soc.; 1958; 80(10); 2456-2463.
Studies on Ion-exchange Resins. XIII. Selectivity Coefficients of Quaternary Base Anion-exchange Resins Toward Univalent Anions
Harry P. Gregor, Jack Belle, R. A. Marcus
J. Am. Chem. Soc.; 1955; 77(10); 2713-2719.
Titration of Polyelectrolytes at Higher Ionic Strengths
R. A. Marcus
J. Phys. Chem.; 1954; 58(8); 621-623.
Studies on Ion Exchange Resins. IX. Capacity and Specific Volumes of Quaternary Base Anion Exchange Resins1
Harry P. Gregor, Jack Belle, R. A. Marcus
J. Am. Chem. Soc.; 1954; 76(7); 1984-1987.
The Kinetics of the Recombination of Methyl Radicals and Iodine Atoms.
R. A. Marcus, O. K. Rice
J. Phys. Chem.; 1951; 55(6); 894-908.
