Computational Chemistry
Home | This Week's Contents  |  C&EN ClassifiedsSearch C&EN Online

 
Related Stories
X-RAY ABSORPTION SPECTROSCOPY
[C&EN, Aug, 6, 2001]

Synchroton Radiation Shines
[C&EN, Jan. 15, 2001]

Fast And Bright: Ultrashort X-Rays
[C&EN, Mar. 27, 2000]]

Related People
Matthew F. DeCamp

Philip H. Bucksbaum

E-mail this article to a friend
Print this article
E-mail the editor
 
 
 
 
 
 
 Table of Contents
 C&EN Classifieds
 News of the Week
 Cover Story
 Editor's Page
 Business
 Government & Policy
 Science/Technology
 Concentrates
  Business
  Government & Policy
  Science/Technology
 Education
 ACS News
 Calendars
 Books
 Digital Briefs
 ACS Comments
 Career & Employment
 Special Reports
 Letters
 Newscripts
 Nanotechnology
 What's That Stuff?
 Pharmaceutical Century

 Hot Articles
 Safety  Letters
 Chemcyclopedia

 Back Issues

 How to Subscribe
 Subscription Changes
 About C&EN
 Copyright Permission
 E-mail webmaster
NEWS OF THE WEEK
MOLECULAR DYNAMICS
October 29, 2001
Volume 79, Number 44
CENEAR 79 44 p.12
ISSN 0009-2347
[Previous Story] [Next Story]

FAST SWITCH X-RAY
Technique may lead to high-resolution movies of chemical reactions

MITCH JACOBY

A new technique can control beams of high-energy X-rays on an ultrafast timescale. The procedure may enable scientists to study subtle changes in atomic positions and other phenomena in chemical reaction dynamics with very high time resolution.

IN AND OUT Passing through a thin germanium crystal (top), an X-ray beam is split into two equal-intensity beams. But when a short, intense laser pulse is directed at the crystal, the lattice spacings in a thin surface region (yellow) are altered--leading to picosecond switching between the diffracted beams.
By shining intense laser light on a thin germanium crystal while the crystal is transmitting X-rays, University of Michigan physicists Matthew F. DeCamp, David A. Reis, and Philip H. Bucksbaum and colleagues can control X-ray transmission [Nature, 413, 825 (2001)]. In the absence of the laser pulse, an X-ray beam passes through the crystal and emerges as two diffracted beams with roughly equal intensity. But when the laser light irradiates the crystal, the lattice spacings are altered rapidly, allowing the team to switch the X-ray beams on and off on a subpicosecond timescale.

A number of other advances in ultrafast methods for probing reaction dynamics using light have been reported in the past several years, but they have all had shortcomings. For example, scientists developed techniques in which femtosecond pulses of visible light are used to take snapshots of reactions as they occur. But the long wavelength of the fast laser limits the technique to fairly simple molecules.

High-energy (hard) X-rays have also been used as the basis of fast techniques in dynamics, but while not limited to simple systems, they do have shortcomings. For example, one technique uses commercial lasers to generate hard X-rays indirectly. The pulse duration is less than 1 picosecond, but the intensity is low. A high-intensity synchrotron method was recently reported, but it requires much costly equipment.

The Michigan group may have just found a way around those problems with their fast X-ray on-off switch.

[Previous Story] [Next Story]



Top


Chemical & Engineering News
Copyright © 2001 American Chemical Society


Computational Chemistry
Home | Table of Contents | News of the Week | Cover Story
Business | Government & Policy | Science/Technology
Chemical & Engineering News
Copyright © 2001 American Chemical Society - All Right Reserved
1155 16th Street NW • Washington DC 20036 • (202) 872-4600 • (800) 227-5558


CASChemPortChemCenterPubs Page