Anal. Chem., 69 (20), 4083 -4091, 1997. 10.1021/ac970540n S0003-2700(97)00540-4

Copyright © 1997 American Chemical Society

Real-Time Analysis of Individual Atmospheric Aerosol Particles: Design and Performance of a Portable ATOFMS

Eric Gard, Joseph E. Mayer, Brad D. Morrical, Tas Dienes, David P. Fergenson, and Kimberly A. Prather*

Department of Chemistry, University of California at Riverside, Riverside, California 92521

Received for review May 27, 1997. Accepted July 28, 1997.

Abstract:

Two portable aerosol time-of-flight mass spectrometers (ATOFMS) of identical design are described. These instruments are powerful new tools for providing temporal and spatial information on the origin, reactivity, and fate of atmospheric aerosols. Each is capable of analyzing the size and composition of individual particles from a polydisperse aerosol in real-time. Particles are introduced into the instrument through a particle beam interface, sized by measuring the delay time between two scattering lasers, and compositionally analyzed using a dual-polarity laser desorption/ionization time-of-flight mass spectrometer. These are the first dual-ion TOFMS instruments to utilize a dual reflectron design. The instruments measure 72 in. long × 28 in. wide × 60 in. high and weigh ~500 lb. Pneumatic tires allow them to be transported through standard doorways, elevators, and handicap ramps, granting access to virtually any location. Furthermore, because of rugged construction they will be able to operate during transport by automobile, boat, or aircraft.


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