Chem. Mater., 19 (25), 61456149 10.1021/cm0715895
Web Release Date: November 8, 2007

Copyright © 2007 American Chemical Society

Super-Hydrophobic Surfaces via Micrometer-Scale Templated Pillars

Nicole E. Zander, Joshua A. Orlicki, Afia S. Karikari, Timothy E. Long, and Adam M. Rawlett*

United States Army Research Laboratory, Aberdeen Proving Ground, Maryland 21005, and Department of Chemistry, Macromolecules and Interfaces Institute, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061

Received June 14, 2007

Revised Manuscript Received September 11, 2007

Abstract:

The fabrication of enhanced hydrophobic surfaces via simple and inexpensive means will be discussed. Regular arrays of microscale pores were prepared in polymer matrices via the spontaneous assembly of water-vapor condensation, the so-called breath figure method. Using these regular arrays of pores as templates, the analogous array of pillars (inverse pores) was transferred to polymeric films. These microtextured surfaces have greatly enhanced the hydrophobicity of the polymer when measured by the contact angle. This method of producing super-hydrophobic textured surfaces should be amenable to high-throughput, low-cost manufacturing of many polymeric surfaces.

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