Chem. Mater., 20 (3), 922931, 2008. 10.1021/cm7031866
Web Release Date: December 15, 2007

Copyright © 2008 American Chemical Society

Template Effects in Porous Coordination Polymers

Daisuke Tanaka and Susumu Kitagawa*

Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Received November 8, 2007

Abstract:

In recent years, a new class of porous materials based on a combination of organic components and metal centers has emerged, called porous coordination polymers (PCPs). PCPs have unique characteristics: regular nanosized spaces, flexibility, and a designed pore surface. The interaction between PCP nanospaces and guest molecules controls the nanoscale molecular assembly. In this short review, correlations between PCPs and guest molecules will be introduced under the rubric of “template”.

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