J. Am. Chem. Soc., 129 (4), 762 -763, 2007. 10.1021/ja0680562 S0002-7863(06)08056-5
Web Release Date: January 4, 2007

Copyright © 2007 American Chemical Society

A Facile Pd(0)-Catalyzed Regio- and Stereoselective Diamination of Conjugated Dienes and Trienes

Haifeng Du, Baoguo Zhao, and Yian Shi*

Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523

yian@lamar.colostate.edu

Received November 10, 2006

Abstract:

This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.


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