J. Am. Chem. Soc., 129 (49), 15124 -15125, 2007. 10.1021/ja076700m S0002-7863(07)06700-5
Web Release Date: November 17, 2007

Copyright © 2007 American Chemical Society

Interfacial Trapping of Single-Walled Carbon Nanotube Bundles

Randy K. Wang, Ryan D. Reeves, and Kirk J. Ziegler*

Department of Chemical Engineering, University of Florida, Gainesville, Florida 32611

kziegler@che.ufl.edu

Received September 5, 2007

Abstract:

A new technique to remove single-walled carbon nanotube (SWNT) bundles from individual SWNTs in an aqueous suspension is introduced. Fluorescence and absorbance data suggest that liquid-liquid systems preferentially trap nanotube bundles at the interface. The resulting aqueous SWNT suspensions display strong fluorescence indicative of a large population of individually suspended SWNTs. The interfacial trapping process offers a simple route to the large-scale preparation of aqueous SWNT suspensions.


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