J. Am. Chem. Soc., 129 (51), 16029 -16033, 2007. 10.1021/ja075604i S0002-7863(07)05604-1
Web Release Date: November 29, 2007

Copyright © 2007 American Chemical Society

Stable Aqueous Dispersion of ZnO Quantum Dots with Strong Blue Emission via Simple Solution Route

Ying-Song Fu, Xi-Wen Du,* Sergei A. Kulinich, Jian-Sheng Qiu, Wen-Jing Qin, Rui Li, Jing Sun, and Jim Liu

Contribution from the School of Materials Science and Engineering, Tianjin University, Tianjin 300072, P. R. China, PRRC-Asia, Motorola (China) Electronics Ltd., No. 10, 4th Avenue, TEDA, Tianjin 300457, P. R. China, and Department of Applied Sciences, University of Quebec, Saguenay, PQ, Canada G7H 2B1

xwdu@tju.edu.cn

Received July 26, 2007

Abstract:

The aqueous dispersion of ZnO quantum dots (QDs) with strong blue emission (quantum yield of 76%) was synthesized through a simple solution route. The water stability of such QDs is provided by the hydroxyl groups on their surface, and the strong blue emission is suggested to arise from the formation of surface ZnO/oleic acid complexes. Under irradiation, these complexes are thought to absorb the excitation light with 3.54 eV and then generate the blue emission with 2.82 eV.


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