J. Am. Chem. Soc., 130 (9), 2742 -2743, 2008. 10.1021/ja710749q S0002-7863(71)00749-2
Web Release Date: February 12, 2008

Copyright © 2008 American Chemical Society

A Templating Approach for Monodisperse Self-Assembled Organic Nanostructures

Steve R. Bull, Liam C. Palmer, Nathaniel J. Fry, Megan A. Greenfield, Benjamin W. Messmore, Thomas J. Meade, and Samuel I. Stupp*

Departments of Chemistry, Biochemistry and Molecular and Cellular Biology, Neurobiology and Physiology, and Radiology, and Departments of Chemical & Biological Engineering, Materials Science & Engineering, and Feinberg School of Medicine, Northwestern University, Evanston, Illinois 60208

s-stupp@northwestern.edu

Received November 30, 2007

Abstract:

The precise structural control is known for self-assembly into closed spherical structures (e.g., micelles), but similar control of open structures is much more challenging. Inspired by natural tobacco mosaic virus, we present the use of a rigid-rod template to control the size of a one-dimensional self-assembly. We believe that this strategy is novel for organic self-assembly and should provide a general approach to controlling size and dimension.


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