J. Am. Chem. Soc., 130 (16), 53905391, 2008. 10.1021/ja7106146
Web Release Date: April 1, 2008

Copyright © 2008 American Chemical Society

Metal-Organic Framework as a Template for Porous Carbon Synthesis

Bo Liu, Hiroshi Shioyama, Tomoki Akita, and Qiang Xu*

National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan, and Graduate School of Engineering, Kobe University, Nada Ku, Kobe, Hyogo 657-8501, Japan

q.xu@aist.go.jp

Received November 26, 2007

Abstract:

Porous carbon was synthesized by heating the precursor FA within the pores of MOF-5. The resultant carbon displayed a high specific surface area (BET, 2872 m2·g−1) and important hydrogen uptake (2.6 wt % at 760 Torr, −196 °C) as well as excellent electrochemical properties as an electrode material for electrochemical double-layered capacitor (EDLC).

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