J. Org. Chem., 72 (25), 9481 -9490, 2007. 10.1021/jo701400t S0022-3263(70)01400-7
Web Release Date: November 14, 2007

Copyright © 2007 American Chemical Society

Synthetic Routes toward Carborane-Wheeled Nanocars

Jean-François Morin, Takashi Sasaki, Yasuhiro Shirai, Jason M. Guerrero, and James M. Tour*

Department of Chemistry, Department of Mechanical Engineering and Materials Science, and the Smalley Institute for Nanoscale Science and Technology, Rice University, MS 222, 6100 Main Street, Houston, Texas 77005

tour@rice.edu

Received June 27, 2007

Abstract:

A new set of aryleneethynylene derivatives bearing three, four, and six p-carboranes as potential wheels attached to a semirigid chassis have been designed and synthesized. These molecules are expected to move in predetermined patterns on atomically smooth surfaces, depending on their specific configuration.


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