J. Phys. Chem. B, 112 (3), 824 -827, 2008. 10.1021/jp0767664 S1520-6106(07)06766-1
Web Release Date: December 22, 2007

Copyright © 2007 American Chemical Society

Influence of Substrate Treatment on Self-Organized Pattern Formation by Langmuir-Blodgett Transfer

Michael Hirtz, Harald Fuchs, and Lifeng Chi*

Physikalisches Institut, Westfälische Wilhelms-Universität, Wilhelm-Klemm-Strasse 10, 48149 Münster, Germany, and Center for Nanotechnology (CeNTech), Gievenbeckweg 11, 48149 Münster, Germany

Received: August 23, 2007

In Final Form: October 16, 2007

Abstract:

Mesoscopic stripe patterns can be obtained by Langmuir-Blodgett (LB) transfer of L--dipalmitoylphosphatidylcholine (DPPC) onto solid substrates. In order to investigate the influence of substrates on the pattern formation, silicon slides treated by different cleaning processes were taken as model systems. A shift in the transfer pressure range for patterning was observed between plasma- and RCA-treated silicon. This can be explained with a model of equivalent states and taking into account the influence of microscale water films on the substrates.


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