Web Release Date: October 19,
Resonance Conditions for Multipole Plasmon Excitations in Noble Metal Nanorods
INFIQC, CLCM, Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Córdoba 5000, Argentina
Received: July 25, 2007
In Final Form: September 3, 2007
Abstract:
A resonance condition has been obtained for the position of plasmon peaks of any multipole order in the extinction spectra of silver and gold nanorods, as a function of their material, size, shape, and dielectric environment. The expression has been derived combining electrodynamics simulations with the aid of a nanoantenna-standing wave model approach. Some scaling laws, emerging from the above expression, are also demonstrated, in very good agreement with recent experiments and theoretical studies.
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