Web Release Date: October 30,
Fabrication of Three-Dimensional ZnO-Carbon Nanotube (CNT) Hybrids Using Self-Assembled CNT Micropatterns as Framework
School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798, Singapore
Received: July 31, 2007
In Final Form: September 10, 2007
Abstract:
Large-scale pyramid-like micropatterns were prepared via capillarity-driven self-assembly during the evaporation of water from aligned carbon nanotubes (ACNTs) wrapped by a polyelectrolyte, poly (sodium 4-styrenesulfonate) (PSS). PSS wrapping results in providing negative charges on every tube, which makes it possible to balance the capillary force and to form uniformed pyramid-like architecture. By using such regular three-dimensional CNT patterns as an idea candidate for the framework/template, two complex architectures consisting of ZnO nanorods and CNT patterns were successfully fabricated, which show revisable surface wettability properties.
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