J. Phys. Chem. C, 111 (48), 17879 -17886, 2007. 10.1021/jp071387w S1932-7447(07)01387-8
Web Release Date: October 24, 2007

Copyright © 2007 American Chemical Society

Improved Synthesis of Aligned Arrays of Single-Walled Carbon Nanotubes and Their Implementation in Thin Film Type Transistors

Coskun Kocabas,# Seong Jun Kang, Taner Ozel, Moonsub Shim, and John A. Rogers*,,,

Department of Physics, Department of Materials Science and Engineering, Department of Mechanical Science and Engineering, Department of Electrical and Computer Engineering, Department of Chemistry, Beckman Institute for Advanced Science and Technology, Frederick Seitz Materials Research Laboratory at the University of Illinois, Urbana-Champaign, Illinois, and Division of Advanced Technology, Korea Research Institute of Standards and Science, Daejeon, 305-340 South Korea

Received: February 18, 2007

In Final Form: July 6, 2007

Abstract:

We report optimized chemical vapor deposition growth procedures that can produce arrays of individual single walled carbon nanotubes (SWNTs) in horizontal configurations with perfect linear shapes to within experimental uncertainties and with levels of alignment >99.9%. This process also enables simultaneous growth of random networks of SWNTs integrated with the arrays in complex layouts. The electrical properties of thin film type transistors formed with SWNTs grown in this fashion approach expectations based on the intrinsic properties of the pristine, individual SWNTs. The procedures described here might represent a strategy to large scale integration of SWNTs into devices for applications in electronics and optoelectronics, sensing, nanomechanical systems, and other areas.


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