J. Phys. Chem. C, 111 (49), 18135 -18142, 2007. 10.1021/jp076425q S1932-7447(07)06425-4
Web Release Date: November 20, 2007

Copyright © 2007 American Chemical Society

Precious Metal Core-Shell Spindles

X. Xu and M. B. Cortie*

Institute for Nanoscale Technology, University of Technology Sydney, P.O. Box 123, Broadway, NSW 2007, Australia

Received: August 10, 2007

In Final Form: October 1, 2007

Abstract:

A simplified method to produce spindle-shaped particles with a hematite core and a silica shell is described. The silica shell can, in turn, serve as the substrate for an outer coating of Ag or Au nanoparticles. The resulting multilayer core-shell particles display a flexible optical extinction spectrum, due primarily to the sensitivity of their plasmon resonance to the morphology of the precious metal outer coating.


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