J. Phys. Chem. C, 112 (10), 3591 -3596, 2008. 10.1021/jp077709d S1932-7447(07)07709-6
Web Release Date: February 14, 2008

Copyright © 2008 American Chemical Society

Highly Stabilized Conductivity of Metallic Single Wall Carbon Nanotube Thin Films

Yasumitsu Miyata, Kazuhiro Yanagi, Yutaka Maniwa, and Hiromichi Kataura*

Department of Physics, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397, Japan, and Nanotechnology Research Institute (NRI), National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562, Japan

Received: September 25, 2007

In Final Form: December 27, 2007

Abstract:

The extremely stable conductivity against molecular physisorptions was revealed in thin films of high-purity metallic single wall carbon nanotubes (SWCNTs). The stability of the metallic SWCNTs results from their constant electronic density of state near the Fermi level. In the case of a mixture of metallic and semiconducting SWCNTs, the existence of semiconducting SWCNTs in the films makes the sheet resistance more sensitive to the adsorption of molecules mainly due to carrier doping. In the practical use for the transparent electrode, stability of the resistance is important and pure metallic SWCNTs have great advantages for such kind of applications.


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