J. Phys. Chem. C, 112 (10), 3558 -3567, 2008. 10.1021/jp7103962 S1932-7447(71)00396-0
Web Release Date: February 14, 2008

Copyright © 2008 American Chemical Society

Controllable Synthesis of 4ZnO·B2O3·H2O Nano-/Microstructures with Different Morphologies: Influence of Hydrothermal Reaction Parameters and Formation Mechanism

Xixi Shi, Liangjie Yuan,* Xuzhuo Sun, Caixian Chang, and Jutang Sun*

College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, People's Republic of China

Received: October 28, 2007

In Final Form: December 18, 2007

Abstract:

4ZnO·B2O3·H2O nano-/microstructures with different morphologies (rod-, wire-, and lamellar-like shapes and microspheres of nano-/microrods) were successfully fabricated through a facile surfactant-assisted hydrothermal method. These 4ZnO·B2O3·H2O nano-/microstructures were characterized by XRD, SEM, and BET specific surface area analysis and TEM equipped with SAED. The influence of hydrothermal reaction parameters, including the initial pH, hydrothermal temperature and time, and concentrations of raw materials, on the formation of 4ZnO·B2O3·H2O nano-/microstructures was investigated. The surfactant of poly(ethylene glycol) 300 played a crucial role in the formation of crystalline 4ZnO·B2O3·H2O with different nano-/microstructures. The structure formation mechanism is briefly discussed. In addition, this work preliminarily demonstrates the fungistatic and bacteriostatic activities of 4ZnO·B2O3·H2O nanocrystals.

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