J. Phys. Chem. C, 112 (11), 4036 -4041, 2008. 10.1021/jp800277x S1932-7447(80)00277-4
Web Release Date: February 28, 2008

Copyright © 2008 American Chemical Society

Fabrication of High Aspect Ratio Core-Shell CdS-Mn/ZnS Nanowires by a Two Step Solvothermal Process

Soumitra Kar,* Swadeshmukul Santra,* and Helge Heinrich#

NanoScience Technology Center, Department of Chemistry, Biomolecular Science Center, Advanced Materials Processing and Analysis Center, Department of Physics, Department of Mechanical, Materials, and Aerospace Engineering, University of Central Florida, Orlando, Florida 32816

Received: January 11, 2008

In Final Form: February 14, 2008

Abstract:

Synthesis of thin (5-8 nm) CdS-Mn/ZnS core-shell nanowires (CSNWs) with high aspect ratio (up to ~150) is reported for the first time. The modified solvothermal synthesis of CSNW involved two steps: the formation of Mn-doped CdS core followed by the ZnS shell. The CSNW growth process is engineered in such a way that the ZnS shell layer grew radially onto the prematurely grown CdS-Mn core, that is, prior to the formation of its well-faceted surface.


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