Langmuir, 24 (5), 1608 -1612, 2008. 10.1021/la7032115 S0743-7463(70)03211-0
Web Release Date: February 1, 2008

Copyright © 2008 American Chemical Society

Polymer Microcapsules with a Fiber-Reinforced Nanocomposite Shell

Leonard M. C. Sagis,* Riëlle de Ruiter, Francisco J. Rossier Miranda, Jolet de Ruiter, Karin Schroën, Adriaan C. van Aelst, Henk Kieft, Remko Boom, and Erik van der Linden

Food Physics Group and Food Process Engineering Group, Wageningen University, Bomenweg 2, 6703HD Wageningen, The Netherlands, and Laboratory of Plant Cell Biology, Wageningen University, Arboretumlaan 4, 6703BD Wageningen, The Netherlands

Received October 16, 2007

In Final Form: December 20, 2007

Abstract:

Polymer microcapsules can be used as controlled release systems in drugs or in foods. Using layer-by-layer adsorption of common food proteins and polysaccharides, we produced a new type of microcapsule with tunable strength and permeability. The shell consists of alternating layers of pectin and whey protein fibrils, yielding a fiber-reinforced nanocomposite shell. The strength can be tightly controlled by varying the number of layers or the density and length of the fibrils in the protein layers. The mechanical stability of these microcapsules appears to be superior to that of currently available multilayer capsules. The method involves only standard unit operations and has the potential for scaling up to industrial production volumes.


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