Web Release Date: February 1,
Polymer Microcapsules with a Fiber-Reinforced Nanocomposite Shell








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Food Physics Group and Food Process Engineering Group, Wageningen University, Bomenweg 2, 6703HD Wageningen, The Netherlands, and Laboratory of Plant Cell Biology, Wageningen University, Arboretumlaan 4, 6703BD Wageningen, The Netherlands
Received October 16, 2007
In Final Form: December 20, 2007

Abstract:
Polymer microcapsules can be used as controlled release systems in drugs or in foods. Using layer-by-layer adsorption of common food proteins and polysaccharides, we produced a new type of microcapsule with tunable strength and permeability. The shell consists of alternating layers of pectin and whey protein fibrils, yielding a fiber-reinforced nanocomposite shell. The strength can be tightly controlled by varying the number of layers or the density and length of the fibrils in the protein layers. The mechanical stability of these microcapsules appears to be superior to that of currently available multilayer capsules. The method involves only standard unit operations and has the potential for scaling up to industrial production volumes.
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