Langmuir, 24 (6), 2407 -2411, 2008. 10.1021/la703044t S0743-7463(70)03044-5
Web Release Date: February 9, 2008

Copyright © 2008 American Chemical Society

Growth of Diameter-Controlled Carbon Nanotubes from Fe-V-O Nanoparticles Size-Classified by Ligand-Exchanged Fractional Precipitation

Itaru Gunjishima,* Takashi Inoue, and Atsuto Okamoto

Toyota Central R&D Laboratories, Inc., Nagakute, Aichi, 480-1192, Japan

Received October 3, 2007

In Final Form: December 12, 2007

Abstract:

Colloidal Fe-V-O nanoparticles prepared as carbon nanotube (CNT) growth catalysts were precisely size-classified by fractional precipitation. Furthermore, the classification ability was improved by the fractional precipitation after ligand exchange process, which allowed us to obtain narrower size distributions of nanoparticles. CNTs were grown from the nanoparticles in order to investigate the dependence of diameter distribution of CNTs on that of nanoparticles. The results show that the diameter distribution of CNTs grown from classified nanoparticles was narrower than that of CNTs grown from as-prepared nanoparticles.


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