Web Release Date: January 5,
Electronic Interactions and Polymer Effect in the Functionalization and Solvation of Carbon Nanotubes by Pyrene- and Ferrocene-Containing Poly(1-alkyne)s
and
Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China, and Department of Chemistry, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
Received August 29, 2007
Revised Manuscript Received November 19, 2007
Abstract:
4-[3-(1-Pyrenyl)propylcarbonyloxy]-1-butyne (PyB) and 4-ferrocenylcarbonyloxy-1-butyne (FcB) were effectively polymerized by zwitterionic rhodium complex Rh+(nbd)[C6H5B-(C6H5)3], giving corresponding polymers PPyB and PFcB with high molecular weights (Mw up to 33300) in high yields (up to 83%). The polymers are excellent solvating agents in making carbon nanotubes (CNTs) soluble in common organic solvents. The salvation is aided by the wrapping or coating of CNTs by the polymers through strong electronic interactions between the aromatic pendants and the CNT shells. A pronounced "polymer effect" was observed in the solvating process: the polymers showed much higher solvating power than their monomers. The polymers endowed the CNTs with functional properties: the PPyB/CNT and PFcB/CNT hybrids were light-emitting and redox-active, respectively.
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