Nano Lett., 7 (11), 3418 -3423, 2007. 10.1021/nl071893x S1530-6984(07)01893-0
Web Release Date: October 18, 2007

Copyright © 2007 American Chemical Society

Tunability of the Refractive Index of Gold Nanoparticle Dispersions

Shoichi Kubo, Andres Diaz, Yan Tang, Theresa S. Mayer, Iam Choon Khoo,* and Thomas E. Mallouk*

Department of Chemistry and Department of Electrical Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802, and Chemical Resources Laboratory, Tokyo Institute of Technology, R1-11, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Received August 2, 2007

Revised October 3, 2007

Abstract:

Alkanethiol-capped gold nanoparticles dispersed in n-dodecane were studied by spectroscopic ellipsometry and were modeled using Mie scattering theory. The refractive index in the visible and near-infrared depended on the volume fraction of gold nanoparticles, in good agreement with the theoretical expectation that such dispersed plasmonic nanoparticles can act as low or tunable refractive index materials at specific optical wavelengths.


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