Cu(I)-Catalyzed Intermolecular
Diamination of Activated Terminal
Olefins
Baoguo Zhao,Weicheng Yuan,Haifeng Du, andYian Shi*
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523
yian@lamar.colostate.edu
Received August 21, 2007
Abstract:
This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen
source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions.
