Letters to Nature
Nature 422, 53-55 (6 March 2003) | doi:10.1038/nature01450; Received 18 October 2002; Accepted 28 January 2003
Superconductivity in two-dimensional CoO2 layers
Kazunori Takada1,3, Hiroya Sakurai2, Eiji Takayama-Muromachi2, Fujio Izumi1, Ruben A. Dilanian1 and Takayoshi Sasaki1,3
- Advanced Materials Laboratory, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, Japan
- Superconducting Materials Center, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, Japan
- CREST, Japan Science and Technology Corporation
Correspondence to: Kazunori Takada1,3 Correspondence and requests for materials should be addressed to K.T. (e-mail: Email: takada.kazunori@nims.go.jp).
Since the discovery of high-transition-temperature (high-Tc) superconductivity in layered copper oxides1, many researchers have searched for similar behaviour in other layered metal oxides involving 3d-transition metals, such as cobalt and nickel. Such attempts have so far failed, with the result that the copper oxide layer is thought to be essential for superconductivity. Here we report that NaxCoO2
yH2O (x
0.35, y
1.3) is a superconductor with a Tc of about 5 K. This compound consists of two-dimensional CoO2 layers separated by a thick insulating layer of Na+ ions and H2O molecules. There is a marked resemblance in superconducting properties between the present material and high-Tc copper oxides, suggesting that the two systems have similar underlying physics.
