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Formation of Strong Basicity on Covalent Triazine Frameworks as Catalysts for the Oxidation of Methylene Compounds

  • Guozhi Zhu
    Guozhi Zhu
    State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
    University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China
    More by Guozhi Zhu
  • , 
  • Song Shi*
    Song Shi
    State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
    *E-mail: [email protected] (S.S.).
    More by Song Shi
    Orcidhttp://orcid.org/0000-0002-4306-1933
  • , 
  • Meng Liu
    Meng Liu
    State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
    University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China
    More by Meng Liu
  • , 
  • Li Zhao
    Li Zhao
    State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
    University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China
    More by Li Zhao
  • , 
  • Min Wang
    Min Wang
    State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
    More by Min Wang
    Orcidhttp://orcid.org/0000-0002-9072-8331
  • , 
  • Xi Zheng
    Xi Zheng
    State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
    More by Xi Zheng
  • , 
  • Jin Gao
    Jin Gao
    State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
    More by Jin Gao
  • , and 
  • Jie Xu*
    Jie Xu
    State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, People’s Republic of China
    *E-mail: [email protected] (J.X.).
    More by Jie Xu
    Orcidhttp://orcid.org/0000-0003-2535-094X
Cite this: ACS Appl. Mater. Interfaces 2018, 10, 15, 12612–12617
Publication Date (Web):March 30, 2018
https://doi.org/10.1021/acsami.7b19001
Copyright © 2018 American Chemical Society
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    Abstract

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    Porous solid bases are increasingly attractive for applications in green chemistry and heterogeneous catalysis under relatively mild conditions. Here, covalent triazine frameworks (CTFs) were first applied as a support for the porous solid strong bases through a redox process between the base precursor KNO3 and CTFs, leading to a relatively low calcination temperature (400 °C). As a result, porous organic frameworks possessing ordered microstructures as well as strong basic sites were successfully synthesized. The materials were characterized by X-ray diffraction, Fourier transform infrared, high-resolution transmission electron microscopy, temperature programmed desorption of CO2, and so forth. The obtained solid bases displayed remarkable catalytic activity in the aerobic oxidation of methylene compounds, and the yield of fluorenones could reach 93.6% at 120 °C, which was nearly 3 times higher than that of the control catalyst. The current research may present a new idea for the construction of porous organic polymers with strong basicity.

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