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Perovskite–Ion Beam Interactions: Toward Controllable Light Emission and Lasing

  • Yue Wang
    Yue Wang
    Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
    MIIT Key Laboratory of Advanced Display Materials and Devices, Institute of Optoelectronics & Nanomaterials, College of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
    More by Yue Wang
    Orcidhttp://orcid.org/0000-0003-0098-5359
  • , 
  • Zhiyuan Gu
    Zhiyuan Gu
    Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
    More by Zhiyuan Gu
  • , 
  • Yinjuan Ren
    Yinjuan Ren
    Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore
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  • , 
  • Ziming Wang
    Ziming Wang
    MIIT Key Laboratory of Advanced Display Materials and Devices, Institute of Optoelectronics & Nanomaterials, College of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
    More by Ziming Wang
  • , 
  • Bingqing Yao
    Bingqing Yao
    School of Materials Science and Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798, Singapore
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  • , 
  • Zhili Dong
    Zhili Dong
    School of Materials Science and Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798, Singapore
    More by Zhili Dong
    Orcidhttp://orcid.org/0000-0001-8116-6747
  • , 
  • Giorgio Adamo
    Giorgio Adamo
    Division of Physics and Applied Physics, School of Physical and Mathematical Sciences  and  Centre for Disruptive Photonic Technologies (CDPT), Nanyang Technological University, Singapore 637371, Singapore
    More by Giorgio Adamo
  • , 
  • Haibo Zeng*
    Haibo Zeng
    MIIT Key Laboratory of Advanced Display Materials and Devices, Institute of Optoelectronics & Nanomaterials, College of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
    *E-mail: [email protected] (H.Z.).
    More by Haibo Zeng
    Orcidhttp://orcid.org/0000-0002-0281-3617
  • , and 
  • Handong Sun*
    Handong Sun
    Division of Physics and Applied Physics, School of Physical and Mathematical Sciences  and  Centre for Disruptive Photonic Technologies (CDPT), Nanyang Technological University, Singapore 637371, Singapore
    MajuLab, International Joint Research Unit UMI 3654, CNRS, Université Côte d’Azur, Sorbonne Université, National University of Singapore, Nanyang Technological University, Singapore 637371, Singapore
    *E-mail: [email protected] (H.S.).
    More by Handong Sun
    Orcidhttp://orcid.org/0000-0002-2261-7103
Cite this: ACS Appl. Mater. Interfaces 2019, 11, 17, 15756–15763
Publication Date (Web):April 10, 2019
https://doi.org/10.1021/acsami.9b01592
Copyright © 2019 American Chemical Society
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    Abstract

    Abstract Image

    Achieving controllable coherent and incoherent light sources is crucial to meet the requests of the constantly developing integrated optics, which, however, remains challenging for the existing semiconductor materials and techniques. All-inorganic lead halide perovskites (ILHPs) are emerging as the promising semiconductors, featuring the defect-tolerant nature and tunable band gap. Herein, an experimental design, based on the interaction between ILHPs and energetic ions, for achieving controllable light emitters and microlasers is reported. We reveal that the photoluminescence intensity from ILHPs can be modulated by more than 1 order of magnitude upon low-dose gallium ion (∼1015 ions/cm2) irradiation, which can be attributed to the generation of vacancy/interstitial defects, metallic lead, and crystal-to-amorphization transition. Such ion-dependent light emission can be exploited to make the colorful photopatterns and in situ tailor the lasing behavior from CsPbBr3 microplates. Further, a strong sputtering effect is observed with the increase of the ion dose (∼1017 ions/cm2), which enables the top-down fabrication of microlasers based on ILHPs. These findings represent a significant step toward controllable light sources leveraging on perovskite–ion interactions.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsami.9b01592.

    • Materials and methods, composition analysis of the sample by EDXS; XRD pattern of the sample; XPS of the sample; SEM images of the original sample and ion-treated sample; and lasing spectra of the ion-treated microdisks (PDF)

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    Cited By

    This article is cited by 38 publications.

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    3. Guodong Liu, Shangtong Jia, Ju Wang, Yifan Li, Hong Yang, Shufeng Wang, Qihuang Gong. Toward Microlasers with Artificial Structure Based on Single-Crystal Ultrathin Perovskite Films. Nano Letters 2021, 21 (20) , 8650-8656. https://doi.org/10.1021/acs.nanolett.1c02618
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    17. Deepika Gupta, Rajesh Kumar. Ion implantation as an approach for tuning of electronic structure, optical, morphological and electrical transport properties of sputtered molybdenum disulfide thin films. Materials Science in Semiconductor Processing 2023, 158 , 107326. https://doi.org/10.1016/j.mssp.2023.107326
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