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Clean Electrocatalysis in a Li2O2 Redox-Based Li–O2 Battery Built with a Hydrate-Melt Electrolyte

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Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1, Umezono, Tsukuba 305-8568, Japan
Center of Energy Storage Materials & Technology, College of Engineering and Applied Sciences, National Laboratory of Solid State Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, People’s Republic of China
§ National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
*E-mail for H.Z.: [email protected]
Cite this: ACS Catal. 2018, 8, 2, 1082–1089
Publication Date (Web):December 27, 2017
https://doi.org/10.1021/acscatal.7b02960
Copyright © 2017 American Chemical Society

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    Abstract

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    The electrocatalysis of the oxygen reduction reaction and oxygen evolution reaction in nonaqueous Li–O2 batteries suffers from severe side reactions and high charge potential. Herein, we design an unreported hydrate-melt Li–O2 battery without use of an unstable organic solvent. Its redox reaction depends on the formation of Li2O2 in high yield (96%) and its full decomposition. The designed battery shows an ultralow charge potential of ∼3.16 V, a high discharge capacity of 38 mAh cm–2, and stable cycling ability. After careful comparison of the discharge and charge products by XRD, SEM, Raman, FTIR, NMR, and quantitative titration, the great improvement in performance is attributed to the efficient avoidance of side reactions related to organic solvent degradation, which may be the primary cause of the high charge potential in a nonaqueous Li–O2 battery. These results should initiate a deep understanding of Li–O2 batteries and indicate another strategy toward practical Li–air batteries with moisture-proof properties and high safety.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acscatal.7b02960.

    • Experimental section, properties of the electrolyte, performance of a conventional aqueous Li–O2 cell, SEM images of products discharged at different current densities, and 19F NMR spectra after discharge (PDF)

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