Construction of Gold Microbead Ultramicroelectrodes

Deon T. Miles, Andrew Knedlik, and David O. Wipf*
Department of Chemistry, Box 9573, Mississippi State University, Mississippi State, Mississippi 39762
Anal. Chem., 1997, 69 (6), pp 1240–1243
DOI: 10.1021/ac960970y
Publication Date (Web): March 15, 1997
Copyright © 1997 American Chemical Society
*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

Abstract

A new way to construct small electrodes by the use of metal microbeads is described. Gold beads of 1.5−3.0 μm diameter were used to construct inexpensive and disposable microelectrodes with overall structural diameters of ≤6 μm and electrode diameters of ≤5 μm. The voltammetric response of these electrodes is consistent with existing theory, and the electrodes exhibited the sigmoidal waves expected at ultramicroelectrodes.

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History

  • Published In Issue March 15, 1997
  • Received for review September 23, 1996. Accepted December 11, 1996.

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