Vicarious nucleophilic substitution of hydrogen

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This article has been cited by 35 ACS Journal articles (5 most recent appear below).

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  Amination Reaction on Copper and Germanium β-Nitrocorrolates

  Manuela Stefanelli, Federica Mandoj, Marco Mastroianni, Sara Nardis, Pruthviray Mohite, Frank R. Fronczek, Kevin M. Smith, Karl M. Kadish, Xiao Xiao, Zhongping Ou, Ping Chen, and Roberto Paolesse
  Inorganic Chemistry2011 Article ASAP

  • Amination Reaction on Copper and Germanium β-Nitrocorrolates

    Manuela Stefanelli, Federica Mandoj, Marco Mastroianni, Sara Nardis, Pruthviray Mohite, Frank R. Fronczek, Kevin M. Smith, Karl M. Kadish, Xiao Xiao, Zhongping Ou, Ping Chen, and Roberto Paolesse
    Inorganic Chemistry2011 Article ASAP

    Copper and germanium complexes of β-substituted nitrocorroles were reacted with 4-amino-4H-1,2,4-triazole to give the corresponding β-amino-β-nitro derivatives, in moderate to good yields. This is the first successful example of a vicarious nucleophilic ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  The Kinetics and Mechanisms of Aromatic Nucleophilic Substitution Reactions in Liquid Ammonia

  Pengju Ji, John H. Atherton, and Michael I. Page
  The Journal of Organic Chemistry2011 76 (9), 3286-3295

  • The Kinetics and Mechanisms of Aromatic Nucleophilic Substitution Reactions in Liquid Ammonia

    Pengju Ji, John H. Atherton, and Michael I. Page
    The Journal of Organic Chemistry2011 76 (9), 3286-3295

    The rates of aromatic nucleophilic substitution reactions in liquid ammonia are much faster than those in protic solvents indicating that liquid ammonia behaves like a typical dipolar aprotic solvent in its solvent effects on organic reactions. ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Preparation of SF5 aromatics by vicarious nucleophilic substitution reactions of nitro-(pentafluorosulfanyl)benzenes with carbanions

  Petr Beier , Tereza Pastýříková , and George Iakobson
  The Journal of Organic Chemistry 0 (ja),

  • Preparation of SF5 aromatics by vicarious nucleophilic substitution reactions of nitro-(pentafluorosulfanyl)benzenes with carbanions

    Petr Beier , Tereza Pastýříková , and George Iakobson
    The Journal of Organic Chemistry 0 (ja),

    Vicarious nucleophilic substitutions (VNS) of hydrogen in 1-nitro-4-(pentafluorosulfanyl)benzene with carbanions provide 2-substituted 1-nitro-4-(pentafluorosulfanyl)benzenes in good to high yields. VNS of 1-nitro-3-(pentafluorosulfanyl)benzene gives a ...

    Abstract | Hi-Res PDF | PDF w/ Links
• 

  Development of an Efficient Synthesis of Two CRF Antagonists for the Treatment of Neurological Disorders

  David K. Leahy, Jun Li, Justin B. Sausker, Jason Zhu, Monica A. Fitzgerald, Chiajen Lai, Frederic G. Buono, Alan Braem, Nuria de Mas, Zerene Manaloto, Ehrlic Lo, William Merkl, Bao-Ning Su, Qi Gao, Alicia T. Ng, and Richard A. Hartz
  Organic Process Research & Development2010 14 (5), 1221-1228

  • Development of an Efficient Synthesis of Two CRF Antagonists for the Treatment of Neurological Disorders

    David K. Leahy, Jun Li, Justin B. Sausker, Jason Zhu, Monica A. Fitzgerald, Chiajen Lai, Frederic G. Buono, Alan Braem, Nuria de Mas, Zerene Manaloto, Ehrlic Lo, William Merkl, Bao-Ning Su, Qi Gao, Alicia T. Ng, and Richard A. Hartz
    Organic Process Research & Development2010 14 (5), 1221-1228

    BMS-764459 (1) and BMS-763534 (2) are CRF1 antagonists for the treatment of neurological disorders such as depression and anxiety. An efficient synthesis of 1 and 2 is described, which features an efficient palladium-catalyzed cyanation of a 5-...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
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  Indium Triflate-Assisted Nucleophilic Aromatic Substitution Reactions of Nitrosobezene-Derived Cycloadducts with Alcohols

  Baiyuan Yang and Marvin J. Miller
  Organic Letters2010 12 (2), 392-395

  • Indium Triflate-Assisted Nucleophilic Aromatic Substitution Reactions of Nitrosobezene-Derived Cycloadducts with Alcohols

    Baiyuan Yang and Marvin J. Miller
    Organic Letters2010 12 (2), 392-395

    Exclusive nucleophilic aromatic substitution of hydrogen in conjunction with cleavage of the N−O bond was observed when nitrosobenzene-derived nitroso cycloadducts were treated with indium triflate in the presence of alcohols. Aromatic alkoxylated syn-1,...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

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