Development of Biodegradable Foamlike Materials Based on Casein and Sodium Montmorillonite Clay

Tassawuth Pojanavaraphan, Rathanawan Magaraphan, Bor-Sen Chiou, and David A. Schiraldi*§
Polymer Processing and Polymer Nanomaterials Research Unit, The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok 10330, Thailand, Bioproduct Chemistry and Engineering, USDA/WRRC/ARS, 800 Buchanan Street, Albany, California 94710, and Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106-7202
Biomacromolecules, 2010, 11 (10), pp 2640–2646
DOI: 10.1021/bm100615a
Publication Date (Web): August 31, 2010
Copyright © 2010 American Chemical Society
* To whom correspondence should be addressed. Tel.: (216) 368 4243. Fax: (216) 368 4202. E-mail: das44@case.edu., †

Chulalongkorn University.

, ‡

USDA/WRRC/ARS.

, §

Case Western Reserve University.

Abstract

Abstract Image

Biodegradable foamlike materials based on a naturally occurring polymer (casein protein) and sodium montmorillonite clay (Na+-MMT) were produced through a simple freeze-drying process. By utilizing dl-glyceraldehyde (GC) as a chemical cross-linking agent, the structural integrity of these new aerogels were remarkably improved when compared to those of the control system (without GC), with a minimal increase in the density from 0.11 to 0.12 g cm−3. The degree of perfection of the foamlike structures was another parameter that had a significant influence on the physical and thermal performances of the low density composites. The biodegradability of the aerogels was investigated in terms of the carbon dioxide (CO2) evolution for up to 8 weeks in compost media under controlled conditions.

Citing Articles

View all 2 citing articles

Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.

This article has been cited by 1 ACS Journal articles (1 most recent appear below).

Tools

SciFinder Links

SciFinder subscribers:  Click to sign in | Not a SciFinder subscriber? Learn more at www.cas.org

Explore by:


History

  • Published In Issue October 11, 2010
  • Article ASAPAugust 31, 2010
  • Received: June 3, 2010
    Revised: August 18, 2010

Recommend & Share

  • Share on ACS NetworkACS Network
  • Add to FacebookFacebook
  • Tweet ThisTweet This
  • Add to CiteULikeCiteULike
  • Add to NewsvineNewsvine
  • Digg ThisDigg This
  • Add to DeliciousDelicious

Related Content

Other ACS content by these authors: