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Communication

An Aqua-Soluble Copper(II)−Sodium Two-Dimensional Coordination Polymer with Intercalated Infinite Chains of Decameric Water Clusters

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Yauhen Yu. Karabach, Alexander M. Kirillov, M. Fátima C. Guedes da Silva, Maximilian N. Kopylovich, and Armando J. L. Pombeiro*

Centro de Qumica Estrutural, Complexo I, Instituto Superior Tcnico, Av. Rovisco Pais, 1049-001 Lisbon, Portugal

Crystal Growth & Design, 2006, 6 (10), pp 2200–2203

DOI: 10.1021/cg060310e

Publication Date (Web): September 6, 2006

To whom correspondence should be sent. Fax +351-21-846 4455. E-mail: pombeiro@ist.utl.pt.

Abstract

Self-assembly synthesis in water, at room temperature, with dinuclear copper triethanolaminate and aqua−sodium building blocks as well as benzene-1,2,4,5-tetracarboxylate linkers leads to the formation of an heteronuclear Cu−Na assembly with a two-dimensional metal−organic framework, providing the first example of an aqua-soluble copper-containing coordination polymer that hosts infinite chains of decameric water clusters (H₂O)₁₀ formed by quasiplanar cyclic water octamers with two pendent water molecules.

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History

Published In Issue October 04, 2006
Received May 26, 2006
Revised Manuscript Received July 11, 2006

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Communication

An Aqua-Soluble Copper(II)−Sodium Two-Dimensional Coordination Polymer with Intercalated Infinite Chains of Decameric Water Clusters

Abstract

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SciFinder Links

History

Recommend & Share

Related Content

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks

A Rare-Earth MOF Series: Fascinating Structure, Efficient Light Emitters, and Promising Catalysts

Supramolecular Assemblies of Trinuclear Triangular Copper(II) Secondary Building Units through Hydrogen Bonds. Generation of Different Metal−Organic Frameworks, Valuable Catalysts for Peroxidative Oxidation of Alkanes

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