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Structural dynamics and charge transfer via complexation with fullerene in large area conjugated polymer honeycomb thin films†
‡ Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States
⊥ Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton New York 11973, United States
# Center for Condensed Matter Sciences, National Taiwan University, 106 Taipei, Taiwan
¶ Center for Integrated Nanotechnologies, Materials Physics and Applications Division, Los Alamos, New Mexico 87545, United States
Chem. Mater., 2011, 23 (3), pp 759–761
DOI: 10.1021/cm102160m
Publication Date (Web): November 1, 2010
Copyright © 2010 American Chemical Society
*Corresponding author. E-mail: hwang@lanl.gov (H.-L.W.); cotlet@bnl.gov (M.C.)., §
These authors made equal contributions to this work
Synopsis
Conducting poly-(phenylene vinylene) honeycomb hexagonal framework of large area (1 mm2) are demonstrated by the breath-figure technique. These honeycomb frameworks are then dopped with fullerenes to undergo dramatic quenching by charge transfer.
Section:P1-honeycomb preparation, complexation with fullerene, details on FLIM, stationary spectroscopy, AFM experiments, concentration-dependent honeycomb morphology (PDF). This material is available free of charge via the Internet at http://pubs.acs.org.
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History
- Published In Issue February 08, 2011
- Article ASAPNovember 01, 2010
- Received: July 31, 2010
Revised: September 28, 2010
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