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Toward Perfection: Kapellasite, Cu₃Zn(OH)₆Cl₂, a New Model S = 1/2 Kagome Antiferromagnet

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R. H. Colman^†, C. Ritter^‡ and A. S. Wills*^†^§

Christopher Ingold Laboratories, Department of Chemistry, University College London, 20 Gordon Street, London, United Kingdom WC1H 0AJ, The London Centre for Nanotechnology, 17−19 Gordon Street, London, United Kingdom WC1H 0AH, and The Institut Laue-Langevin, 6 Rue Jules Horowitz, BP156, 38042 Grenoble, Cedex 9, France

Chem. Mater., 2008, 20 (22), pp 6897–6899

DOI: 10.1021/cm802060n

Publication Date (Web): October 24, 2008

* Corresponding author. E-mail: a.s.wills@ucl.ac.uk., †

University College London.

, ‡

The Institut Laue-Langevin.

, §

The London Centre for Nanotechnology.

Section:

Magnetic Phenomena

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This article has been cited by 3 ACS Journal articles (3 most recent appear below).

Structure and Magnetism of the Quasi-1-d K₄Cu(MoO₄)₃ and the Structure of K₄Zn(MoO₄)₃
Melissa C. Menard, Rieko Ishii, Satoru Nakatsuji, and Julia Y. Chan
Inorganic Chemistry2011 Article ASAP
- Structure and Magnetism of the Quasi-1-d K₄Cu(MoO₄)₃ and the Structure of K₄Zn(MoO₄)₃
  Melissa C. Menard, Rieko Ishii, Satoru Nakatsuji, and Julia Y. Chan
  Inorganic Chemistry2011 Article ASAP
  Single crystals of K4Cu(MoO4)3 and nonmagnetic K4Zn(MoO4)3 have been grown by the flux-growth method. K4Cu(MoO4)3 can be described as a quantum quasi-1-d antiferromagnet with correlations between neighboring Cu2+ ions but no magnetic long-range ordering ...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
Magnetic and Crystallographic Studies of Mg-Herbertsmithite, γ-Cu₃Mg(OH)₆Cl₂—A New S = 1/2 Kagome Magnet and Candidate Spin Liquid
R. H. Colman, A. Sinclair, and A. S. Wills
Chemistry of Materials2011 23 (7), 1811-1817
- Magnetic and Crystallographic Studies of Mg-Herbertsmithite, γ-Cu₃Mg(OH)₆Cl₂—A New S = 1/2 Kagome Magnet and Candidate Spin Liquid
  R. H. Colman, A. Sinclair, and A. S. Wills
  Chemistry of Materials2011 23 (7), 1811-1817
  Studies are presented of the synthesis, crystal structure, and magnetic properties of the new quantum kagome magnet Mg-herbertsmithite, γ-Cu3Mg(OH)6Cl2. The material features strong antiferromagnetic exchange characterized by a Weiss temperature of θW −...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
Comparisons between Haydeeite, α-Cu₃Mg(OD)₆Cl₂, and Kapellasite, α-Cu₃Zn(OD)₆Cl₂, Isostructural S = 1/2 Kagome Magnets
R.H. Colman, A. Sinclair, and A.S. Wills
Chemistry of Materials2010 22 (20), 5774-5779
- Comparisons between Haydeeite, α-Cu₃Mg(OD)₆Cl₂, and Kapellasite, α-Cu₃Zn(OD)₆Cl₂, Isostructural S = 1/2 Kagome Magnets
  R.H. Colman, A. Sinclair, and A.S. Wills
  Chemistry of Materials2010 22 (20), 5774-5779
  The search for new S = 1/2 kagome antiferromagnets has been an ongoing challenge for the researchers interested in frustrated magnetism. Intrigue has surrounded these materials since the proposal that the high frustration of the kagome antiferromagnet and ...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

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History

Published In Issue November 25, 2008
Article ASAPOctober 25, 2008
Received: July 30, 2008
Revised: September 19, 2008

Select a CAS section from the 5 main topical divisions below:

Communication

Toward Perfection: Kapellasite, Cu₃Zn(OH)₆Cl₂, a New Model S = 1/2 Kagome Antiferromagnet

Citing Articles

Structure and Magnetism of the Quasi-1-d K₄Cu(MoO₄)₃ and the Structure of K₄Zn(MoO₄)₃

Structure and Magnetism of the Quasi-1-d K₄Cu(MoO₄)₃ and the Structure of K₄Zn(MoO₄)₃

Magnetic and Crystallographic Studies of Mg-Herbertsmithite, γ-Cu₃Mg(OH)₆Cl₂—A New S = 1/2 Kagome Magnet and Candidate Spin Liquid

Magnetic and Crystallographic Studies of Mg-Herbertsmithite, γ-Cu₃Mg(OH)₆Cl₂—A New S = 1/2 Kagome Magnet and Candidate Spin Liquid

Comparisons between Haydeeite, α-Cu₃Mg(OD)₆Cl₂, and Kapellasite, α-Cu₃Zn(OD)₆Cl₂, Isostructural S = 1/2 Kagome Magnets