Catalytic Asymmetric Dihydroxylation

Hartmuth C. Kolb, Michael S. VanNieuwenhze, K. Barry Sharpless

Chem. Rev., 1994, 94 (8), pp 2483–2547

DOI: 10.1021/cr00032a009

Publication Date: December 1994

Note: In lieu of an abstract, this is the article's first page.

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Enantioselective trans-Dihydroxylation of Aryl Olefins by Cascade Biocatalysis with Recombinant Escherichia coli Coexpressing Monooxygenase and Epoxide Hydrolase
Shuke Wu, Yongzheng Chen, Yi Xu, Aitao Li, Qisong Xu, Anton Glieder, and Zhi Li
ACS Catalysis 2014 4 (2), 409-420
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Amine-Catalyzed Asymmetric Cross-Aldol Reactions Using Heterofunctionalized Acetaldehydes as Nucleophiles
Taichi Kano, Ryu Sakamoto, and Keiji Maruoka
Organic Letters 2014 16 (3), 944-947
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An Organocatalytic Asymmetric Allylic Alkylation Allows Enantioselective Total Synthesis of Hydroxymetasequirin-A and Metasequirin-B Tetramethyl Ether Diacetates
Pu-Sheng Wang, Xiao-Le Zhou, and Liu-Zhu Gong
Organic Letters 2014 16 (3), 976-979
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Aphadilactones A–D, Four Diterpenoid Dimers with DGAT Inhibitory and Antimalarial Activities from a Meliaceae Plant
Jia Liu, Xiu-Feng He, Gai-Hong Wang, Emilio F. Merino, Sheng-Ping Yang, Rong-Xiu Zhu, Li-She Gan, Hua Zhang, Maria B. Cassera, He-Yao Wang, David G. I. Kingston, and Jian-Min Yue
The Journal of Organic Chemistry 2014 79 (2), 599-607
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PhICl₂ and Wet DMF: An Efficient System for Regioselective Chloroformyloxylation/α-Chlorination of Alkenes/α,β-Unsaturated Compounds
Le Liu, Daisy Zhang-Negrerie, Yunfei Du, and Kang Zhao
Organic Letters 2014 16 (2), 436-439
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Scalable Solution-Phase Synthesis of the Biologically Active Cyclodepsipeptide Destruxin E, a Potent Negative Regulator of Osteoclast Morphology
Masahito Yoshida, Hiroshi Sato, Yoshitaka Ishida, Hiroshi Nakagawa, and Takayuki Doi
The Journal of Organic Chemistry 2014 79 (1), 296-306
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An NMR and MD Modeling Insight into Nucleation of 1,2-Alkanediols: Selective Crystallization of Lipase-Catalytically Resolved Enantiomers from the Reaction Mixtures
Omar Parve, Indrek Reile, Jaan Parve, Sergo Kasvandik, Marina Kudrjašova, Sven Tamp, Andrus Metsala, Ly Villo, Tõnis Pehk, Jüri Jarvet, and Lauri Vares
The Journal of Organic Chemistry 2013 78 (24), 12795-12801
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Stereocontrolled Synthesis of 1,2- and 1,3-Diamine Building Blocks from Aziridine Aldehyde Dimers
Sean K. Liew, Zhi He, Jeffrey D. St. Denis, and Andrei K. Yudin
The Journal of Organic Chemistry 2013 78 (23), 11637-11645
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Synthesis of Formylsilanes through Oxidative Cleavage of α-Silyl Glycols
Henrik von Wachenfeldt and Daniel Strand
The Journal of Organic Chemistry 2013 78 (23), 12268-12273
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Alkene Oxyalkylation Enabled by Merging Rhenium Catalysis with Hypervalent Iodine(III) Reagents via Decarboxylation
Yin Wang, Lei Zhang, Yunhui Yang, Ping Zhang, Zhenting Du, and Congyang Wang
Journal of the American Chemical Society 2013 135 (48), 18048-18051
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Exploiting Pseudo C₂-Symmetry for an Efficient Synthesis of the F-Ring of the Spongistatins
Paul S. Tanis, Joshua R. Infantine, and James L. Leighton
Organic Letters 2013 15 (21), 5464-5467
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Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and Tetrahydropyridazines
Xiao-Yong Duan, Xiu-Long Yang, Ran Fang, Xie-Xue Peng, Wei Yu, and Bing Han
The Journal of Organic Chemistry 2013 78 (21), 10692-10704
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Tethered Aminohydroxylation: Synthesis of the β-Amino Acid of Microsclerodermins A and B
Robert D. C. Pullin, Akshat H. Rathi, Ekaterina Y. Melikhova, Christian Winter, Amber L. Thompson, and Timothy J. Donohoe
Organic Letters 2013 15 (21), 5492-5495
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Resolution of Terminal 1,2-Diols via Silyl Transfer
Xixi Sun, Amanda D. Worthy, and Kian L. Tan
The Journal of Organic Chemistry 2013 78 (20), 10494-10499
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Expedient and Versatile Formation of Novel Amino-deoxy-ketoheptuloses
Yevgeniy Leshch, Anna Jacobsen, Julian Thimm, and Joachim Thiem
Organic Letters 2013 15 (19), 4948-4951
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Design, Synthesis, and Characterization of Novel Tetrahydropyran-Based Bacterial Topoisomerase Inhibitors with Potent Anti-Gram-Positive Activity
Jean-Philippe Surivet, Cornelia Zumbrunn, Georg Rueedi, Christian Hubschwerlen, Daniel Bur, Thierry Bruyère, Hans Locher, Daniel Ritz, Wolfgang Keck, Peter Seiler, Christopher Kohl, Jean-Christophe Gauvin, Azely Mirre, Verena Kaegi, Marina Dos Santos, Mika Gaertner, Jonathan Delers, Michel Enderlin-Paput, and Maria Boehme
Journal of Medicinal Chemistry 2013 56 (18), 7396-7415
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A Convergent Total Synthesis of the Potent Cephalostatin/Ritterazine Hybrid -25-epi Ritterostatin G_N1_N
Ananda Kumar Kanduluru, Prabal Banerjee, John A Beutler, and Philip L Fuchs
The Journal of Organic Chemistry 2013 78 (18), 9085-9092
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Dinuclear Zinc–ProPhenol-Catalyzed Enantioselective α-Hydroxyacetate Aldol Reaction with Activated Ester Equivalents
Barry M. Trost, David J. Michaelis, and Mihai I. Truica
Organic Letters 2013 15 (17), 4516-4519
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Total Synthesis of Nhatrangin A
Jhillu Singh Yadav, Goreti Rajendar, Ramisetti Srinivasa Rao, and Srihari Pabbaraja
The Journal of Organic Chemistry 2013 78 (17), 8524-8530
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Total Synthesis of the Proposed Structure of Didemnaketal B
Haruhiko Fuwa, Kumiko Sekine, and Makoto Sasaki
Organic Letters 2013 15 (15), 3970-3973
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Synthesis and Biological Properties of Novel Brefeldin A Analogues
Kai Seehafer, Frank Rominger, Günter Helmchen, Markus Langhans, David G. Robinson, Başak Özata, Britta Brügger, Jeroen R. P. M. Strating, Frank J. M. van Kuppeveld, and Christian D. Klein
Journal of Medicinal Chemistry 2013 56 (14), 5872-5884
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Exploiting Hidden Symmetry in Natural Products: Total Syntheses of Amphidinolides C and F
Subham Mahapatra and Rich G. Carter
Journal of the American Chemical Society 2013 135 (29), 10792-10803
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Preparation of anti-Vicinal Amino Alcohols: Asymmetric Synthesis of d-erythro-Sphinganine, (+)-Spisulosine, and d-ribo-Phytosphingosine
Ewen D. D. Calder, Ahmed M. Zaed, and Andrew Sutherland
The Journal of Organic Chemistry 2013 78 (14), 7223-7233
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Enantioselective Palladium-Catalyzed Diamination of Alkenes Using N-Fluorobenzenesulfonimide
Erica L. Ingalls, Paul A. Sibbald, Werner Kaminsky, and Forrest E. Michael
Journal of the American Chemical Society 2013 135 (24), 8854-8856
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Synthesis and Structure Revision of the C43–C67 Part of Amphidinol 3
Makoto Ebine, Mitsunori Kanemoto, Yoshiyuki Manabe, Yosuke Konno, Ken Sakai, Nobuaki Matsumori, Michio Murata, and Tohru Oishi
Organic Letters 2013 15 (11), 2846-2849
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Stereoselective Synthesis of the Butyrolactone and the Oxazoline/Furan Fragment of Leupyrrin A₁
Thomas Debnar, Tongtong Wang, and Dirk Menche
Organic Letters 2013 15 (11), 2774-2777
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Epi-, Epoxy-, and C2-Modified Bengamides: Synthesis and Biological Evaluation
Francisco Sarabia, Francisca Martín-Gálvez, Cristina García-Ruiz, Antonio Sánchez-Ruiz, and Carlos Vivar-García
The Journal of Organic Chemistry 2013 78 (11), 5239-5253
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Metal-Free, n-Bu₄NI-Catalyzed Regioselective Difunctionalization of Unactivated Alkenes
Qicai Xue, Jin Xie, Pan Xu, Kaidong Hu, Yixiang Cheng, and Chengjian Zhu
ACS Catalysis 2013 3 (6), 1365-1368
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Synthesis of the C1–C21 Domain of Azaspiracids-1 and −3
Zhigao Zhang, Yue Ding, Jianyan Xu, Yong Chen, and Craig J. Forsyth
Organic Letters 2013 15 (10), 2338-2341
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Practical Synthesis of PGI₂ Agonist: Resolution–Inversion–Recycle Approach of Its Chiral Intermediate
Atsushi Ohigashi, Atsushi Kanda, Shigeru Moriki, Yukihisa Baba, Norio Hashimoto, and Minoru Okada
Organic Process Research & Development 2013 17 (4), 658-665
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Pd(II)-Catalyzed Sequential C–C/C–O Bond Formations: A New Strategy to Construct Trisubstituted Furans
Meifang Zheng, Liangbin Huang, Wanqing Wu, and Huanfeng Jiang
Organic Letters 2013 15 (8), 1838-1841
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Oxyanion Hole Stabilization by C–H···O Interaction in a Transition State—A Three-Point Interaction Model for Cinchona Alkaloid-Catalyzed Asymmetric Methanolysis of meso-Cyclic Anhydrides
Hui Yang and Ming Wah Wong
Journal of the American Chemical Society 2013 135 (15), 5808-5818
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Identification of RO4597014, a Glucokinase Activator Studied in the Clinic for the Treatment of Type 2 Diabetes
Yimin Qian, Wendy L. Corbett, Steven J. Berthel, Duk Soon Choi, Mark T. Dvorozniak, Wanping Geng, Paul Gillespie, Kevin R. Guertin, Nancy-Ellen Haynes, Robert F. Kester, Francis A. Mennona, David Moore, Jagdish Racha, Roumen Radinov, Ramakanth Sarabu, Nathan R. Scott, Joseph Grimsby, and Navita L. Mallalieu
ACS Medicinal Chemistry Letters 2013 4 (4), 414-418
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Hydrolytic and Aminolytic Kinetic Resolution of Terminal Bis-Epoxides
Jevgenia Bredihhina, Piret Villo, Ka̅rlis Andersons, Lauri Toom, and Lauri Vares
The Journal of Organic Chemistry 2013 78 (6), 2379-2385
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Development of Intramolecular Vicinal Diamination of Alkenes: From Palladium to Bromine Catalysis
Kilian Muñiz and Claudio Martínez
The Journal of Organic Chemistry 2013 78 (6), 2168-2174
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Osmium-Catalyzed Oxidative Cyclization of Dienes and Their Derivatives
Ben S. Pilgrim and Timothy J. Donohoe
The Journal of Organic Chemistry 2013 78 (6), 2149-2167
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N-Monoalkylation of Amines with Alcohols by Tandem Photocatalytic and Catalytic Reactions on TiO₂ Loaded with Pd Nanoparticles
Yasuhiro Shiraishi, Keisuke Fujiwara, Yoshitsune Sugano, Satoshi Ichikawa, and Takayuki Hirai
ACS Catalysis 2013 3 (3), 312-320
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Green Diacetoxylation of Alkenes in a Microchemical System
Jeong Hyeon Park, Chan Yi Park, Hyun Seung Song, Yun Suk Huh, Geon Hee Kim, and Chan Pil Park
Organic Letters 2013 15 (4), 752-755
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14-Membered Macrocyclic Ring-Derived Toolbox: The Identification of Small Molecule Inhibitors of Angiogenesis and Early Embryo Development in Zebrafish Assay
Madhu Aeluri, Chinmoy Pramanik, Lakshindra Chetia, Naveen Kumar Mallurwar, Sridhar Balasubramanian, Gayathri Chandrasekar, Satish Srinivas Kitambi, and Prabhat Arya
Organic Letters 2013 15 (3), 436-439
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C–H Bond Activation of the Methyl Group of the Supporting Ligand in an Osmium(III) Complex upon Reaction with H₂O₂: Formation of an Organometallic Osmium(IV) Complex
Hideki Sugimoto, Kenji Ashikari, and Shinobu Itoh
Inorganic Chemistry 2013 52 (2), 543-545
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Asymmetric Chiral Ligand-Directed Alkene Dioxygenation
Sharon R. Neufeldt and Melanie S. Sanford
Organic Letters 2013 15 (1), 46-49
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Alkene Dihydroxylation with Malonoyl Peroxides: Catalysis Using Fluorinated Alcohols
Sylvain Picon, Michael Rawling, Matthew Campbell, and Nicholas C. O. Tomkinson
Organic Letters 2012 14 (24), 6250-6253
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An Osmium(III)/Osmium(V) Redox Couple Generating Os^V(O)(OH) Center for cis-1,2-Dihydroxylation of Alkenes with H₂O₂: Os Complex with a Nitrogen-Based Tetradentate Ligand
Hideki Sugimoto, Kazuhiro Kitayama, Seiji Mori, and Shinobu Itoh
Journal of the American Chemical Society 2012 134 (46), 19270-19280
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Total Synthesis and Biological Activity of the Proposed Structure of Phaeosphaeride A
Anthoula Chatzimpaloglou, Maria P. Yavropoulou, Karien E. Rooij, Ralf Biedermann, Uwe Mueller, Stefan Kaskel, and Vasiliki Sarli
The Journal of Organic Chemistry 2012 77 (21), 9659-9667
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Development of Enantioselective Synthetic Routes to (−)-Kinamycin F and (−)-Lomaiviticin Aglycon
Christina M. Woo, Shivajirao L. Gholap, Liang Lu, Miho Kaneko, Zhenwu Li, P. C. Ravikumar, and Seth B. Herzon
Journal of the American Chemical Society 2012 134 (41), 17262-17273
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Studies toward the Unique Pederin Family Member Psymberin: Full Structure Elucidation, Two Alternative Total Syntheses, and Analogs
Yu Feng, Xin Jiang, and Jef K. De Brabander
Journal of the American Chemical Society 2012 134 (41), 17083-17093
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Palladium-Catalyzed Oxidation of Unsaturated Hydrocarbons Using Molecular Oxygen
Wanqing Wu and Huanfeng Jiang
Accounts of Chemical Research 2012 45 (10), 1736-1748
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Origins of Stereoselectivities of Dihydroxylations of cis-Bicyclo[3.3.0]octenes
Hao Wang, Philipp Kohler, Larry E. Overman, and K. N. Houk
Journal of the American Chemical Society 2012 134 (38), 16054-16058
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Mechanism of the MeReO₃-Catalyzed Deoxygenation of Epoxides
Siwei Bi, Jiayong Wang, Lingjun Liu, Ping Li, and Zhenyang Lin
Organometallics 2012 31 (17), 6139-6147
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Biomass Conversion to High Value Chemicals: From Furfural to Chiral Hydrofuroins in Two Steps
Anzhelika Kabro, Eduardo C. Escudero-Adán, Vladimir V. Grushin, and Piet W. N. M. van Leeuwen
Organic Letters 2012 14 (15), 4014-4017
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Total Syntheses of Cladoacetals A and B: Confirmation of Absolute Configurations
Day-Shin Hsu and Shih-Chung Lin
The Journal of Organic Chemistry 2012 77 (14), 6139-6146
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Total Synthesis and Structure Confirmation of Elatenyne: Success of Computational Methods for NMR Prediction with Highly Flexible Diastereomers
Bryony S. Dyson, Jonathan W. Burton, Te-ik Sohn, Byungsook Kim, Hoon Bae, and Deukjoon Kim
Journal of the American Chemical Society 2012 134 (28), 11781-11790
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One-Pot Synthesis of Phthalazines and Pyridazino-aromatics: A Novel Strategy for Substituted Naphthalenes
Simon N. Kessler and Hermann A. Wegner
Organic Letters 2012 14 (13), 3268-3271
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Metal-Free, Organocatalytic Syn Diacetoxylation of Alkenes
Wenhe Zhong, Shan Liu, Jun Yang, Xiangbao Meng, and Zhongjun Li
Organic Letters 2012 14 (13), 3336-3339
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Total Synthesis of (−)-Polycavernoside A: Suzuki–Miyaura Coupling Approach
Yusuke Kasai, Takanori Ito, and Makoto Sasaki
Organic Letters 2012 14 (12), 3186-3189
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Minimal Fluorous Tagging Strategy that Enables the Synthesis of the Complete Stereoisomer Library of SCH725674 Macrolactones
Jared D. Moretti, Xiao Wang, and Dennis P. Curran
Journal of the American Chemical Society 2012 134 (18), 7963-7970
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Site-Selective Catalysis: Toward a Regiodivergent Resolution of 1,2-Diols
Amanda D. Worthy, Xixi Sun, and Kian L. Tan
Journal of the American Chemical Society 2012 134 (17), 7321-7324
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Total Synthesis of the Proposed Structure of Aldingenin B
Michael T. Crimmins and Colin O. Hughes
Organic Letters 2012 14 (8), 2168-2171
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Diastereoselective Additions of Allylmetal Reagents to Free and Protected syn-α,β-Dihydroxyketones Enable Efficient Synthetic Routes to Methyl Trioxacarcinoside A
Daniel J. Smaltz, Jakub Švenda, and Andrew G. Myers
Organic Letters 2012 14 (7), 1812-1815
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Sequential Allylic C–H Amination/Vinylic C–H Arylation: A Strategy for Unnatural Amino Acid Synthesis from α-Olefins
Chao Jiang, Dustin J. Covell, Antonia F. Stepan, Mark S. Plummer, and M. Christina White
Organic Letters 2012 14 (6), 1386-1389
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Desmethyl Macrolides: Synthesis and Evaluation of 4,10-Didesmethyl Telithromycin
Venkata Velvadapu, Ian Glassford, Miseon Lee, Tapas Paul, Charles DeBrosse, Dorota Klepacki, Meagan C. Small, Alexander D. MacKerell, Jr., and Rodrigo B. Andrade
ACS Medicinal Chemistry Letters 2012 3 (3), 211-215
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Triflic Acid Catalyzed Oxidative Lactonization and Diacetoxylation of Alkenes Using Peroxyacids as Oxidants
Yan-Biao Kang and Lutz H. Gade
The Journal of Organic Chemistry 2012 77 (3), 1610-1615
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Exploring the Chemistry of Epoxy Amides for the Synthesis of the 2′′-epi-Diazepanone Core of Liposidomycins and Caprazamycins
Francisco Sarabia, Carlos Vivar-García, Cristina García-Ruiz, Laura Martín-Ortiz, and Antonio Romero-Carrasco
The Journal of Organic Chemistry 2012 77 (3), 1328-1339
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Studies toward the Synthesis of Spirolide C: Exploration into the Formation of the 23-Membered All-Carbon Macrocyclic Framework
Craig E. Stivala, Zhenhua Gu, Lindsay L. Smith, and Armen Zakarian
Organic Letters 2012 14 (3), 804-807
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Oxidative Hydroxylation Mediated by Alkoxysulfonium Ions
Yosuke Ashikari, Toshiki Nokami, and Jun-ichi Yoshida
Organic Letters 2012 14 (3), 938-941
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De Novo Synthesis of l-Colitose and l-Rhodinose Building Blocks
Oliviana Calin, Rajan Pragani, and Peter H. Seeberger
The Journal of Organic Chemistry 2012 77 (2), 870-877
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Metal-Free Dihydroxylation of Alkenes using Cyclobutane Malonoyl Peroxide
Kevin M. Jones and Nicholas C. O. Tomkinson
The Journal of Organic Chemistry 2012 77 (2), 921-928
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Total Synthesis of Nominal Lyngbouilloside Aglycon
Abdelatif ElMarrouni, Raphael Lebeuf, Julian Gebauer, Montserrat Heras, Stellios Arseniyadis, and Janine Cossy
Organic Letters 2012 14 (1), 314-317
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Dihydroxylation-Based Approach for the Asymmetric Syntheses of Hydroxy-γ-butyrolactones
Jennifer Peed, Iwan R. Davies, Lucy R. Peacock, James E. Taylor, Gabriele Kociok-Köhn, and Steven D. Bull
The Journal of Organic Chemistry 2012 77 (1), 543-555
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BF₃·OEt₂-Promoted Diastereoselective Diacetoxylation of Alkenes by PhI(OAc)₂
Wenhe Zhong, Jun Yang, Xiangbao Meng, and Zhongjun Li
The Journal of Organic Chemistry 2011 76 (24), 9997-10004
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De Novo Asymmetric Synthesis of Fridamycin E
Qian Chen, Michael Mulzer, Pei Shi, Penny J. Beuning, Geoffrey W. Coates, and George A. O’Doherty
Organic Letters 2011 13 (24), 6592-6595
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Semisynthesis and Biological Evaluation of Ganodermanontriol and Its Stereoisomeric Triols
Erin M. Kennedy, Steven J. P’Pool, Jiahua Jiang, Daniel Sliva, and Robert E. Minto
Journal of Natural Products 2011 74 (11), 2332-2337
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Manganese Triazacyclononane Oxidation Catalysts Grafted under Reaction Conditions on Solid Cocatalytic Supports
Nicholas J. Schoenfeldt, Zhenjuan Ni, Andrew W. Korinda, Randall J. Meyer, and Justin M. Notestein
Journal of the American Chemical Society 2011 133 (46), 18684-18695
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Synthesis of the Bis-Spiroacetal Core of the Antimitotic Agent Spirastrellolide B
Jack Li-Yang Chen and Margaret A. Brimble
The Journal of Organic Chemistry 2011 76 (22), 9417-9428
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Photochemical Activation of Ruthenium(II)–Pyridylamine Complexes Having a Pyridine-N-Oxide Pendant toward Oxygenation of Organic Substrates
Takahiko Kojima, Kazuya Nakayama, Miyuki Sakaguchi, Takashi Ogura, Kei Ohkubo, and Shunichi Fukuzumi
Journal of the American Chemical Society 2011 133 (44), 17901-17911
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Scalable Synthesis of Enantiomerically Pure syn-2,3-Dihydroxybutyrate by Sharpless Asymmetric Dihydroxylation of p-Phenylbenzyl Crotonate
Daniel J. Smaltz and Andrew G. Myers
The Journal of Organic Chemistry 2011 76 (20), 8554-8559
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Chiral Guanidinium Ionic Liquids for Asymmetric Dihydroxylation of Olefins with Recycling of the Catalytic System by Supercritical CO₂
Luis C. Branco, Ana Serbanovic, Manuel N. da Ponte, and Carlos A. M. Afonso
ACS Catalysis 2011 1 (10), 1408-1413
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Convergent Synthesis and Discovery of a Natural Product-Inspired Paralog-Selective Hsp90 Inhibitor
Valer Jeso, Lisa Cherry, Todd K. Macklin, Subhas Chandra Pan, Philip V. LoGrasso, and Glenn C. Micalizio
Organic Letters 2011 13 (19), 5108-5111
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Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation
Jun Xu, Yao Fu, Dong-Fen Luo, Yuan-Ye Jiang, Bin Xiao, Zhao-Jing Liu, Tian-Jun Gong, and Lei Liu
Journal of the American Chemical Society 2011 133 (39), 15300-15303
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Direct Entry to Erythronolides via a Cyclic Bis[Allene]
Kai Liu, Hiyun Kim, Partha Ghosh, Novruz G. Akhmedov, and Lawrence J. Williams
Journal of the American Chemical Society 2011 133 (38), 14968-14971
Abstract | Full Text HTML | PDF | PDF w/ Links
Multigram Synthesis of Glyceollin I
Amarjit Luniwal, Rahul Khupse, Michael Reese, Jidong Liu, Mohammad El-Dakdouki, Neha Malik, Lei Fang, and Paul Erhardt
Organic Process Research & Development 2011 15 (5), 1149-1162
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Total Synthesis of (−)-4,8,10-Tridesmethyl Telithromycin
Venkata Velvadapu, Tapas Paul, Bharat Wagh, Ian Glassford, Charles DeBrosse, and Rodrigo B. Andrade
The Journal of Organic Chemistry 2011 76 (18), 7516-7527
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Synthesis of Bryostatin 7 via C–C Bond-Forming Hydrogenation
Yu Lu, Sang Kook Woo, and Michael J. Krische
Journal of the American Chemical Society 2011 133 (35), 13876-13879
Abstract | Full Text HTML | PDF | PDF w/ Links
Iron-Catalyzed Olefin Epoxidation and cis-Dihydroxylation by Tetraalkylcyclam Complexes: the Importance of cis-Labile Sites
Yan Feng, Jason England, and Lawrence Que, Jr.
ACS Catalysis 2011 1 (9), 1035-1042
Abstract | Full Text HTML | PDF | PDF w/ Links
Metal-Free, Aerobic Dioxygenation of Alkenes Using Simple Hydroxamic Acid Derivatives
Benjamin C. Giglio, Valerie A. Schmidt, and Erik J. Alexanian
Journal of the American Chemical Society 2011 133 (34), 13320-13322
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A Synthesis of Pseudoconhydrine and Its Epimer via Hydroformylation and Dihydroxylation
Roderick W. Bates, K. Sivarajan, and Bernd F. Straub
The Journal of Organic Chemistry 2011 76 (16), 6844-6848
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Synthetic Versatility in C–H Oxidation: A Rapid Approach to Differentiated Diols and Pyrans from Simple Olefins
Paul E. Gormisky and M. Christina White
Journal of the American Chemical Society 2011 133 (32), 12584-12589
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Chemical Synthesis Enables Biochemical and Antibacterial Evaluation of Streptolydigin Antibiotics
Sergey V. Pronin, Anthony Martinez, Konstantin Kuznedelov, Konstantin Severinov, Howard A. Shuman, and Sergey A. Kozmin
Journal of the American Chemical Society 2011 133 (31), 12172-12184
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Conformation-Specific Spectroscopy and Populations of Diastereomers of a Model Monolignol Derivative: Chiral Effects in a Triol Chain
Jacob C. Dean, Evan G. Buchanan, William H. James, III, Anna Gutberlet, Bidyut Biswas, P. Veeraraghavan Ramachandran, and Timothy S. Zwier
The Journal of Physical Chemistry A 2011 115 (30), 8464-8478
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Iron-Catalyzed Carbonylation-Peroxidation of Alkenes with Aldehydes and Hydroperoxides
Weiping Liu, Yuanming Li, Kaisheng Liu, and Zhiping Li
Journal of the American Chemical Society 2011 133 (28), 10756-10759
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Highly Efficient Synthesis of Ketoheptoses
Daniel Waschke, Julian Thimm, and Joachim Thiem
Organic Letters 2011 13 (14), 3628-3631
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Synthesis of Pinnatoxins A and G and Revision of the Mode of Action of Pinnatoxin A
Romulo Araoz, Denis Servent, Jordi Molgó, Bogdan I. Iorga, Carole Fruchart-Gaillard, Evelyne Benoit, Zhenhua Gu, Craig Stivala, and Armen Zakarian
Journal of the American Chemical Society 2011 133 (27), 10499-10511
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Total Synthesis of Bryostatin 9
Paul A. Wender and Adam J. Schrier
Journal of the American Chemical Society 2011 133 (24), 9228-9231
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Synthesis of β,γ-Dihydroxyhomotyrosines by a Tandem Petasis–Asymmetric Dihydroxylation Approach
Quentin I. Churches, Jonathan M. White, and Craig A. Hutton
Organic Letters 2011 13 (11), 2900-2903
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Regio- and Stereoselective Concurrent Oxidations with Whole Cell Biocatalyst: Simple and Green Syntheses of Enantiopure 1,2-Diols via Oxidative Kinetic Resolution
Xin Jia, Yi Xu, and Zhi Li
ACS Catalysis 2011 1 (6), 591-596
Abstract | Full Text HTML | PDF | PDF w/ Links
Biomimetic Syntheses and Antiproliferative Activities of Racemic, Natural (−), and Unnnatural (+) Glyceollin I
Rahul S. Khupse, Jeffrey G. Sarver, Jill A. Trendel, Nicole R. Bearss, Michael D. Reese, Thomas E. Wiese, Stephen M. Boue, Matthew E. Burow, Thomas E. Cleveland, Deepak Bhatnagar, and Paul W. Erhardt
Journal of Medicinal Chemistry 2011 54 (10), 3506-3523
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11-Step Enantioselective Synthesis of (−)-Lomaiviticin Aglycon
Seth B. Herzon, Liang Lu, Christina M. Woo, and Shivajirao L. Gholap
Journal of the American Chemical Society 2011 133 (19), 7260-7263
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Ruthenium-Catalyzed Oxidation of Alkenes at Room Temperature: A Practical and Concise Approach to α-Diketones
Shulin Chen, Zhaojun Liu, Erbo Shi, Long Chen, Wei Wei, Hong Li, Yannan Cheng, and Xiaobing Wan
Organic Letters 2011 13 (9), 2274-2277
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Aerobic Pd-Catalyzed sp³ C−H Olefination: A Route to Both N-Heterocyclic Scaffolds and Alkenes
Kara J. Stowers, Kevin C. Fortner, and Melanie S. Sanford
Journal of the American Chemical Society 2011 133 (17), 6541-6544
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Pd(II)-Catalyzed Intramolecular Amidoarylation of Alkenes with Molecular Oxygen as Sole Oxidant
Kai-Tai Yip and Dan Yang
Organic Letters 2011 13 (8), 2134-2137
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Computational Investigation of Coverage-Dependent Behavior on Functionalization of the Semiconductor X (100)-2 × 1 Surface (X = C, Si, and Ge) by Cycloaddition of Transition Metal Oxides
Bao-Zhen Sun, Wen-Kai Chen, and Yi-Jun Xu
The Journal of Physical Chemistry C 2011 115 (13), 5800-5808
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The Nature of the Catalytically Active Species in Olefin Dioxygenation with PhI(OAc)₂: Metal or Proton?
Yan-Biao Kang and Lutz H. Gade
Journal of the American Chemical Society 2011 133 (10), 3658-3667
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Reactivity by Design—Metallaoxetanes as Centerpieces in Reaction Development
Alexander Dauth and Jennifer A. Love
Chemical Reviews 2011 111 (3), 2010-2047
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Scope and Limitations of the Photooxidations of 2-(α-Hydroxyalkyl)furans: Synthesis of 2-Hydroxy-exo-brevicomin
Dimitris Noutsias, Antonia Kouridaki, and Georgios Vassilikogiannakis
Organic Letters 2011 13 (5), 1166-1169
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Catalytic Enantioselective Synthesis of Naturally Occurring Butenolides via Hetero-Allylic Alkylation and Ring Closing Metathesis
Bin Mao, Koen Geurts, Martín Fañanás-Mastral, Anthoni W. van Zijl, Stephen P. Fletcher, Adriaan J. Minnaard, and Ben L. Feringa
Organic Letters 2011 13 (5), 948-951
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Asymmetric Dihydroxylations of 1-Substituted (E)- and (Z)-3-Methylpent-2-en-4-ynes: Full Compliance with the Sharpless Mnemonic Re-established and Embellished
Heike Burghart-Stoll, Oliver Böhnke, and Reinhard Brückner
Organic Letters 2011 13 (5), 1020-1023
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Total Synthesis of Broussonetine F: The Orthoamide Overman Rearrangement of an Allylic Diol
Naoto Hama, Toshihiro Aoki, Shohei Miwa, Miki Yamazaki, Takaaki Sato, and Noritaka Chida
Organic Letters 2011 13 (4), 616-619
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Heterogeneous Catalysts for the One-Pot Synthesis of Chemicals and Fine Chemicals
Maria J. Climent, Avelino Corma, and Sara Iborra
Chemical Reviews 2011 111 (2), 1072-1133
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Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates
Jing Nie, Hong-Chao Guo, Dominique Cahard, and Jun-An Ma
Chemical Reviews 2011 111 (2), 455-529
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Synthesis and Stereochemical Assignment of (+)-Chamuvarinin
Gordon J. Florence, Joanne C. Morris, Ross G. Murray, Jonathan D. Osler, Vanga R. Reddy, and Terry K. Smith
Organic Letters 2011 13 (3), 514-517
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An Enantioselective Synthesis of (+)-Polyoxamic Acid via Phase-Transfer Catalytic Conjugate Addition and Asymmetric Dihydroxylation
Yeon-Ju Lee, Yohan Park, Mi-hyun Kim, Sang-sup Jew, and Hyeung-geun Park
The Journal of Organic Chemistry 2011 76 (2), 740-743
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Gold-Catalyzed Regioselective Hydration of Propargyl Acetates Assisted by a Neighboring Carbonyl Group: Access to α-Acyloxy Methyl Ketones and Synthesis of (±)-Actinopolymorphol B
Nayan Ghosh, Sanatan Nayak, and Akhila K. Sahoo
The Journal of Organic Chemistry 2011 76 (2), 500-511
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Desmethyl Macrolides: Synthesis and Evaluation of 4,8,10-Tridesmethyl Telithromycin
Venkata Velvadapu, Tapas Paul, Bharat Wagh, Dorota Klepacki, Olgun Guvench, Alexander MacKerell, Jr., and Rodrigo B. Andrade
ACS Medicinal Chemistry Letters 2011 2 (1), 68-72
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Olefin Cis-Dihydroxylation with Bio-Inspired Iron Catalysts. Evidence for an Fe^II/Fe^IV Catalytic Cycle
Paul D. Oldenburg, Yan Feng, Iweta Pryjomska-Ray, Daniel Ness, and Lawrence Que, Jr.
Journal of the American Chemical Society 2010 132 (50), 17713-17723
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Advancing the Mechanistic Understanding of an Enantioselective Palladium-Catalyzed Alkene Difunctionalization Reaction
Katrina H. Jensen, Jonathan D. Webb, and Matthew S. Sigman
Journal of the American Chemical Society 2010 132 (49), 17471-17482
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Capturing the Essence of Organic Synthesis: From Bioactive Natural Products to Designed Molecules in Today’s Medicine
Arun K. Ghosh
The Journal of Organic Chemistry 2010 75 (23), 7967-7989
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SmI₂-Mediated Radical Cyclizations Directed by a C−Si Bond
Hassan Y. Harb, Karl D. Collins, Jose V. Garcia Altur, Sue Bowker, Leonie Campbell, and David J. Procter
Organic Letters 2010 12 (23), 5446-5449
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Total Synthesis of Bryostatin 16 Using a Pd-Catalyzed Diyne Coupling as Macrocyclization Method and Synthesis of C20-epi-Bryostatin 7 as a Potent Anticancer Agent
Barry M. Trost and Guangbin Dong
Journal of the American Chemical Society 2010 132 (46), 16403-16416
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Convergent Assembly of the Spiroacetal Subunit of Didemnaketal B
Haruhiko Fuwa, Sayaka Noji, and Makoto Sasaki
Organic Letters 2010 12 (22), 5354-5357
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Alkene Syn Dihydroxylation with Malonoyl Peroxides
James C. Griffith, Kevin M. Jones, Sylvain Picon, Michael J. Rawling, Benson M. Kariuki, Matthew Campbell, and Nicholas C. O. Tomkinson
Journal of the American Chemical Society 2010 132 (41), 14409-14411
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Synthesis of Streptolydigin, a Potent Bacterial RNA Polymerase Inhibitor
Sergey V. Pronin and Sergey A. Kozmin
Journal of the American Chemical Society 2010 132 (41), 14394-14396
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A Synthesis of Oseltamivir (Tamiflu) Starting from d-Mannitol
Ji S. Ko, Ji E. Keum, and Soo Y. Ko
The Journal of Organic Chemistry 2010 75 (20), 7006-7009
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Toward the Macrocidins: Macrocyclization via Williamson Etherification of a Phenolate
Bertram Barnickel and Rainer Schobert
The Journal of Organic Chemistry 2010 75 (19), 6716-6719
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Synthesis of the Sponge-Derived Plakortone Series of Bioactive Compounds
Patricia Y. Hayes, Sharon Chow, Fredrik Rahm, Paul V. Bernhardt, James J. De Voss, and William Kitching
The Journal of Organic Chemistry 2010 75 (19), 6489-6501
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An Approach to Lauroxanes by Iterative Use of Co₂(CO)₆-Acetylenic Complexes. A Formal Synthesis of (+)-Laurencin
Nuria Ortega, Victor S. Martín, and Tomás Martín
The Journal of Organic Chemistry 2010 75 (19), 6660-6672
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cis-Dihydroxylation of Alkenes with Oxone Catalyzed by Iron Complexes of a Macrocyclic Tetraaza Ligand and Reaction Mechanism by ESI-MS Spectrometry and DFT Calculations
Toby Wai-Shan Chow, Ella Lai-Ming Wong, Zhen Guo, Yungen Liu, Jie-Sheng Huang, and Chi-Ming Che
Journal of the American Chemical Society 2010 132 (38), 13229-13239
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Highly α-Selective Hydrolysis of α,β-Epoxyalcohols using Tetrabutylammonium Fluoride
Purba Mukerjee, Mohammed Abid, and Frank C. Schroeder
Organic Letters 2010 12 (18), 3986-3989
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Total Synthesis and Anticancer Activities of (−)- and (+)-Thespesone
Sandra Breyer, Katharina Effenberger-Neidnicht, and Rainer Schobert
The Journal of Organic Chemistry 2010 75 (18), 6214-6218
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Palladium-Catalyzed Alkoxyamination of Alkenes with Use of N-Fluorobenzenesulfonimide as Oxidant
Dmitry V. Liskin, Paul A. Sibbald, Carolyn F. Rosewall, and Forrest E. Michael
The Journal of Organic Chemistry 2010 75 (18), 6294-6296
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Highly Diastereo- and Enantioselective Synthesis of Monodifferentiated syn-1,2-Diol Derivatives through Asymmetric Transfer Hydrogenation via Dynamic Kinetic Resolution
Damien Cartigny, Kurt Püntener, Tahar Ayad, Michelangelo Scalone and Virginie Ratovelomanana-Vidal
Organic Letters 2010 12 (17), 3788-3791
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Total Synthesis of Fostriecin: Via a Regio- and Stereoselective Polyene Hydration, Oxidation, and Hydroboration Sequence
Dong Gao and George A. O’Doherty
Organic Letters 2010 12 (17), 3752-3755
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Total Synthesis of Sporolide B and 9-epi-Sporolide B
K. C. Nicolaou, Jianhua Wang, Yefeng Tang and Lorenzo Botta
Journal of the American Chemical Society 2010 132 (32), 11350-11363
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Ruthenium-Catalyzed Hydroxylation of Unactivated Tertiary C−H Bonds
Eric McNeill and J. Du Bois
Journal of the American Chemical Society 2010 132 (29), 10202-10204
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Asymmetric Formal trans-Dihydroxylation and trans-Aminohydroxylation of α,β-Unsaturated Aldehydes via an Organocatalytic Reaction Cascade
Łukasz Albrecht, Hao Jiang, Gustav Dickmeiss, Björn Gschwend, Signe Grann Hansen and Karl Anker Jørgensen
Journal of the American Chemical Society 2010 132 (26), 9188-9196
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Synthesis of Taurospongin A
BoShen Wu, Aurélie Mallinger and Jeremy Robertson
Organic Letters 2010 12 (12), 2818-2821
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Efficient Diacetoxylation of Alkenes via Pd(II)/Pd(IV) Process with Peracetic Acid and Acetic Anhydride
Chan Pil Park, Joo Ho Lee, Kyung Soo Yoo and Kyung Woon Jung
Organic Letters 2010 12 (11), 2450-2452
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Enantioselective Synthesis of α-Methylene-β-hydroxy Carboxylic Acid Derivatives via a Diastereoselective Aldol/β-Elimination Sequence: Application to the C(15)−C(21) Fragment of Tedanolide C
Roland Barth and William R. Roush
Organic Letters 2010 12 (10), 2342-2345
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Synthesis of the ABCDEFG Ring System of Maitotoxin
K. C. Nicolaou, Robert J. Aversa, Jian Jin and Fatima Rivas
Journal of the American Chemical Society 2010 132 (19), 6855-6861
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Effects of Primary and Secondary Surface Groups in Enantioselective Catalysis Using Nanoporous Materials with Chiral Walls
Andreas Kuschel and Sebastian Polarz
Journal of the American Chemical Society 2010 132 (18), 6558-6565
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Synthetic Studies toward the Mannopeptimycins: Synthesis of Orthogonally Protected β-Hydroxyenduracididines
Kevin S. Olivier and Michael S. Van Nieuwenhze
Organic Letters 2010 12 (8), 1680-1683
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Copper-Catalyzed Diacetoxylation of Olefins using PhI(OAc)₂ as Oxidant
Jayasree Seayad, Abdul Majeed Seayad and Christina L. L. Chai
Organic Letters 2010 12 (7), 1412-1415
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Palladium-Catalyzed Direct Oxidation of Alkenes with Molecular Oxygen: General and Practical Methods for the Preparation of 1,2-Diols, Aldehydes, and Ketones
Azhong Wang and Huanfeng Jiang
The Journal of Organic Chemistry 2010 75 (7), 2321-2326
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Discovery and Development of Natural Product-Derived Chemotherapeutic Agents Based on a Medicinal Chemistry Approach
Kuo-Hsiung Lee
Journal of Natural Products 2010 73 (3), 500-516
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Stereoselective OsO₄-Catalyzed Oxidative Cyclization of 1,5-Dienes
Alexander Poethig and Thomas Strassner
The Journal of Organic Chemistry 2010 75 (6), 1967-1973
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Rigid Hydrophilic Structures for Improved Properties of Conjugated Polymers and Nitrotyrosine Sensing in Water
Brett VanVeller, Koji Miki and Timothy M. Swager
Organic Letters 2010 12 (6), 1292-1295
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An Organocatalytic Asymmetric Chlorolactonization
Daniel C. Whitehead, Roozbeh Yousefi, Arvind Jaganathan and Babak Borhan
Journal of the American Chemical Society 2010 132 (10), 3298-3300
Abstract | Full Text HTML | PDF | PDF w/ Links
Copper-Catalyzed Diacetoxylation of Olefins using PhI(OAc)₂ as Oxidant
Jayasree Seayad, Abdul Majeed Seayad and Christina L. L. Chai
Organic Letters 0 (proofing),
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Mechanism and Regioselectivity of the Osmium-Catalyzed Aminohydroxylation of Olefins
Dominik Munz and Thomas Strassner
The Journal of Organic Chemistry 2010 75 (5), 1491-1497
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Synthetic Studies toward the Mannopeptimycins: Synthesis of Orthogonally Protected β-Hydroxyenduracididines
Kevin S. Olivier and Michael S. Van Nieuwenhze
Organic Letters 0 (proofing),
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Development of a Convergent Entry to the Diazofluorene Antitumor Antibiotics: Enantioselective Synthesis of Kinamycin F
Christina M. Woo, Liang Lu, Shivajirao L. Gholap, Devin R. Smith and Seth B. Herzon
Journal of the American Chemical Society 2010 132 (8), 2540-2541
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A Concise Enantioselective Synthesis of the Chlorosulfolipid Malhamensilipin A
D. Karl Bedke, Grant M. Shibuya, Alban R. Pereira, William H. Gerwick and Christopher D. Vanderwal
Journal of the American Chemical Society 2010 132 (8), 2542-2543
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Palladium-Catalyzed Direct Oxidation of Alkenes with Molecular Oxygen: General and Practical Methods for the Preparation of 1,2-Diols, Aldehydes, and Ketones
Azhong Wang and Huanfeng Jiang
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Rigid Hydrophilic Structures for Improved Properties of Conjugated Polymers and Nitrotyrosine Sensing in Water
Brett VanVeller, Koji Miki and Timothy M. Swager
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Bis(NHC)-Palladium(II) Complex-Catalyzed Dioxygenation of Alkenes
Wenfeng Wang, Feijun Wang and Min Shi
Organometallics 2010 29 (4), 928-933
Abstract | Full Text HTML | PDF | PDF w/ Links
An Organocatalytic Asymmetric Chlorolactonization
Daniel C. Whitehead, Roozbeh Yousefi, Arvind Jaganathan and Babak Borhan
Journal of the American Chemical Society 0 (proofing),
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Stereoselective OsO₄-Catalyzed Oxidative Cyclization of 1,5-Dienes
Alexander Poethig and Thomas Strassner
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Development of a Convergent Entry to the Diazofluorene Antitumor Antibiotics: Enantioselective Synthesis of Kinamycin F
Christina M. Woo, Liang Lu, Shivajirao L. Gholap, Devin R. Smith and Seth B. Herzon
Journal of the American Chemical Society 0 (proofing),
Abstract | Full Text HTML
Metal-Free Highly Regioselective Aminotrifluoroacetoxylation of Alkenes
Helena M. Lovick and Forrest E. Michael
Journal of the American Chemical Society 2010 132 (4), 1249-1251
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A Concise Enantioselective Synthesis of the Chlorosulfolipid Malhamensilipin A
D. Karl Bedke, Grant M. Shibuya, Alban R. Pereira, William H. Gerwick and Christopher D. Vanderwal
Journal of the American Chemical Society 0 (proofing),
Abstract | Full Text HTML
Discovery and Development of Natural Product-Derived Chemotherapeutic Agents Based on a Medicinal Chemistry Approach
Kuo-Hsiung Lee
Journal of Natural Products 0 (proofing),
Abstract | Full Text HTML
Mechanism and Regioselectivity of the Osmium-Catalyzed Aminohydroxylation of Olefins
Dominik Munz and Thomas Strassner
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Bis(NHC)-Palladium(II) Complex-Catalyzed Dioxygenation of Alkenes
Wenfeng Wang, Feijun Wang and Min Shi
Organometallics 0 (proofing),
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Total Synthesis of Bengazole A
Srivari Chandrasekhar and Ambadi Sudhakar
Organic Letters 2010 12 (2), 236-238
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Dihydroxylation of Vinyl Sulfones: Stereoselective Synthesis of (+)- and (−)-Febrifugine and Halofuginone
Noel P. McLaughlin and Paul Evans
The Journal of Organic Chemistry 2010 75 (2), 518-521
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Peloruside B, A Potent Antitumor Macrolide from the New Zealand Marine Sponge Mycale hentscheli: Isolation, Structure, Total Synthesis, and Bioactivity
A. Jonathan Singh, Chun-Xiao Xu, Xiaoming Xu, Lyndon M. West, Anja Wilmes, Ariane Chan, Ernest Hamel, John H. Miller, Peter T. Northcote and Arun K. Ghosh
The Journal of Organic Chemistry 2010 75 (1), 2-10
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Metal-Free Highly Regioselective Aminotrifluoroacetoxylation of Alkenes
Helena M. Lovick and Forrest E. Michael
Journal of the American Chemical Society 0 (proofing),
Abstract | Full Text HTML
Enantioselective Total Synthesis of (−)-Acylfulvene and (−)-Irofulven
Dustin S. Siegel, Grazia Piizzi, Giovanni Piersanti and Mohammad Movassaghi
The Journal of Organic Chemistry 2009 74 (24), 9292-9304
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Total Synthesis of Bengazole A
Srivari Chandrasekhar and Ambadi Sudhakar
Organic Letters 0 (proofing),
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Dihydroxylation of Vinyl Sulfones: Stereoselective Synthesis of (+)- and (−)-Febrifugine and Halofuginone
Noel P. McLaughlin and Paul Evans
The Journal of Organic Chemistry 0 (proofing),
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Convergent Synthesis of Fostriecin via Selective Alkene Couplings and Regioselective Asymmetric Dihydroxylation
Omar Robles and Frank E. McDonald
Organic Letters 2009 11 (23), 5498-5501
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Palladium-Catalyzed Enantioselective Addition of Two Distinct Nucleophiles across Alkenes Capable of Quinone Methide Formation
Katrina H. Jensen, Tejas P. Pathak, Yang Zhang and Matthew S. Sigman
Journal of the American Chemical Society 2009 131 (47), 17074-17075
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Layered Transition Metal Carboxylates: Efficient Reusable Heterogeneous Catalyst for Epoxidation of Olefins
Rupam Sen, Susmita Bhunia, Dasarath Mal, Subratanath Koner, Yoshitaro Miyashita and Ken-Ichi Okamoto
Langmuir 2009 25 (23), 13667-13672
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Syntheses of Racemic and Natural Glycinol
Amarjit Luniwal, Rahul S. Khupse, Michael Reese, Lei Fang and Paul W. Erhardt
Journal of Natural Products 2009 72 (11), 2072-2075
Abstract | Full Text HTML | PDF | PDF w/ Links
Peloruside B, A Potent Antitumor Macrolide from the New Zealand Marine Sponge Mycale hentscheli: Isolation, Structure, Total Synthesis, and Bioactivity
A. Jonathan Singh, Chun-Xiao Xu, Xiaoming Xu, Lyndon M. West, Anja Wilmes, Ariane Chan, Ernest Hamel, John H. Miller, Peter T. Northcote and Arun K. Ghosh
The Journal of Organic Chemistry 0 (proofing),
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Stereoselective Synthesis of the C31−C40/C43−C52 Unit of Amphidinol 3
Mitsunori Kanemoto, Michio Murata and Tohru Oishi
The Journal of Organic Chemistry 2009 74 (22), 8810-8813
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Total Syntheses of All Stereoisomers of Phenatic Acid B
Rodney A. Fernandes and Asim K. Chowdhury
The Journal of Organic Chemistry 2009 74 (22), 8826-8829
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Stereoselective Synthesis of Erythronolide A via Nitrile Oxide Cycloadditions and Related Studies
Dieter Muri and Erick M. Carreira
The Journal of Organic Chemistry 2009 74 (22), 8695-8712
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Structure Determination of a New Juvenile Hormone from a Heteropteran Insect
Toyomi Kotaki, Tetsuro Shinada, Kanako Kaihara, Yasufumi Ohfune, and Hideharu Numata
Organic Letters 2009 11 (22), 5234-5237
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Total Synthesis of (−)-Acylfulvene and (−)-Irofulven
Dustin S. Siegel, Grazia Piizzi, Giovanni Piersanti and Mohammad Movassaghi
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Convergent Synthesis of Fostriecin via Selective Alkene Couplings and Regioselective Asymmetric Dihydroxylation
Omar Robles and Frank E. McDonald
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Palladium-Catalyzed Enantioselective Addition of Two Distinct Nucleophiles across Alkenes Capable of Quinone Methide Formation
Katrina H. Jensen, Tejas P. Pathak, Yang Zhang and Matthew S. Sigman
Journal of the American Chemical Society 0 (proofing),
Abstract | Full Text HTML
Total Syntheses of Racemic and Natural Glycinol
Amarjit Luniwal, Rahul S. Khupse, Michael Reese, Lei Fang and Paul W. Erhardt
Journal of Natural Products 0 (proofing),
Abstract | Full Text HTML
Layered Transition Metal Carboxylates: Efficient Reusable Heterogeneous Catalyst for Epoxidation of Olefins
Rupam Sen, Susmita Bhunia, Dasarath Mal, Subratanath Koner, Yoshitaro Miyashita and Ken-Ichi Okamoto
Langmuir 0 (proofing),
Abstract | Full Text HTML
Enantioselective Synthesis of 2-Methyl-1,2-syn- and 2-Methyl-1,2-anti-3-butenediols via Allene Hydroboration−Aldehyde Allylboration Reaction Sequences
Ming Chen, Masaki Handa and William R. Roush
Journal of the American Chemical Society 2009 131 (41), 14602-14603
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Total Syntheses of All Stereoisomers of Phenatic Acid B
Rodney A. Fernandes and Asim K. Chowdhury
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Stereoselective Synthesis of Azetidines and Pyrrolidines from N-tert-Butylsulfonyl(2-aminoalkyl)oxiranes
Mohamed Medjahdi, José C. González-Gómez, Francisco Foubelo and Miguel Yus
The Journal of Organic Chemistry 2009 74 (20), 7859-7865
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Synthesis of the Monomeric Counterpart of Marinomycin A
Dominique Amans, Laurianne Bareille, Véronique Bellosta and Janine Cossy
The Journal of Organic Chemistry 2009 74 (20), 7665-7674
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Second Generation Synthesis of C27−C35 Building Block of E7389, a Synthetic Halichondrin Analogue
Yu-Rong Yang, Dae-Shik Kim and Yoshito Kishi
Organic Letters 2009 11 (20), 4516-4519
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γ-Spiroketal γ-Lactones from 2-(γ-Hydroxyalkyl)furans: Syntheses of epi-Pyrenolides D and Crassalactone D
Elias Pavlakos, Thomas Georgiou, Maria Tofi, Tamsyn Montagnon and Georgios Vassilikogiannakis
Organic Letters 2009 11 (20), 4556-4559
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Structure Determination of a New Juvenile Hormone from a Heteropteran Insect
Toyomi Kotaki, Tetsuro Shinada, Kanako Kaihara, Yasufumi Ohfune and Hideharu Numata
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Stereoselective Synthesis of the C31−C40/C43−C52 Unit of Amphidinol 3
Mitsunori Kanemoto, Michio Murata and Tohru Oishi
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Palladium-Catalyzed Diacetoxylation of Methylenecyclopropanes via C(sp³)−C(sp³) Bond Breaking
Min Jiang and Min Shi
Organometallics 2009 28 (19), 5600-5602
Abstract | Full Text HTML | PDF | PDF w/ Links
New Insight into Chiroptical Properties of 1,2-Diols Cyclic Sulfites.
Pawel̷ Chochrek, Jadwiga Frelek, Marcin Kwit and Jerzy Wicha
The Journal of Organic Chemistry 2009 74 (19), 7300-7308
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereoselective Synthesis of Erythronolide A via Nitrile Oxide Cycloadditions and Related Studies
Dieter Muri and Erick M. Carreira
The Journal of Organic Chemistry 0 (proofing),
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Poly(bisnorbornanediol)
Nai-Ti Lin, Sherng-Long Lee, Jian-Yuan Yu, Chun-hsien Chen, Shou-Ling Huang and Tien-Yau Luh
Macromolecules 2009 42 (18), 6986-6991
Abstract | Full Text HTML | PDF | PDF w/ Links
Organocatalytic Activity of Cinchona Alkaloids: Which Nitrogen Is More Nucleophilic?
Mahiuddin Baidya, Markus Horn, Hendrik Zipse and Herbert Mayr
The Journal of Organic Chemistry 2009 74 (18), 7157-7164
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Stereoselective Synthesis of Azetidines and Pyrrolidines from N-tert-Butylsulfonyl(2-aminoalkyl)oxiranes
Mohamed Medjahdi, José C. González-Gómez, Francisco Foubelo and Miguel Yus
The Journal of Organic Chemistry 0 (proofing),
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Enantioselective Synthesis of 2-Methyl-1,2-syn- and 2-Methyl-1,2-anti-3-butenediols via Allene Hydroboration−Aldehyde Allylboration Reaction Sequences
Ming Chen, Masaki Handa and William R. Roush
Journal of the American Chemical Society 0 (proofing),
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Palladium-Catalyzed Diacetoxylation of Methylenecyclopropanes via C(sp³)−C(sp³) Bond Breaking
Min Jiang and Min Shi
Organometallics 0 (proofing),
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Second Generation Synthesis of C27−C35 Building Block of E7389, a Synthetic Halichondrin Analogue
Yu-Rong Yang, Dae-Shik Kim and Yoshito Kishi
Organic Letters 0 (proofing),
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Concise Syntheses of the Natural Products (+)-Sylvaticin and (+)-cis-Sylvaticin
Timothy J. Donohoe, Robert M. Harris, Oliver Williams, Gráinne C. Hargaden, Jeremy Burrows and Jeremy Parker
Journal of the American Chemical Society 2009 131 (35), 12854-12861
Abstract | Full Text HTML | PDF | PDF w/ Links
γ-Spiroketal γ-Lactones from 2-(γ-Hydroxyalkyl)furans: Syntheses of epi-Pyrenolides D and Crassalactone D
Elias Pavlakos, Thomas Georgiou, Maria Tofi, Tamsyn Montagnon and Georgios Vassilikogiannakis
Organic Letters 0 (proofing),
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Synthesis of the Monomeric Counterpart of Marinomycin A
Dominique Amans, Laurianne Bareille, Véronique Bellosta and Janine Cossy
The Journal of Organic Chemistry 0 (proofing),
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Oxygen Atom Transfer Reactions of Iridium and Osmium Complexes: Theoretical Study of Characteristic Features and Significantly Large Differences Between These Two Complexes
Atsushi Ishikawa, Yoshihide Nakao, Hirofumi Sato and Shigeyoshi Sakaki
Inorganic Chemistry 2009 48 (17), 8154-8163
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Stereoselective Synthesis and Absolute Configuration of the C1′−C25′ Fragment of Symbiodinolide
Hiroyoshi Takamura, Takeshi Murata, Takahiro Asai, Isao Kadota and Daisuke Uemura
The Journal of Organic Chemistry 2009 74 (17), 6658-6666
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Total Syntheses of (+)- and (−)-Pestalotiopsin A
Ken-ichi Takao, Nobuhiko Hayakawa, Reo Yamada, Taro Yamaguchi, Hiroshi Saegusa, Masatoshi Uchida, Suguru Samejima and Kin-ichi Tadano
The Journal of Organic Chemistry 2009 74 (17), 6452-6461
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Functionalization of the Semiconductor Surfaces of Diamond (100), Si (100), and Ge (100) by Cycloaddition of Transition Metal Oxides: A Theoretical Prediction
Yi-Jun Xu and Xianzhi Fu
Langmuir 2009 25 (17), 9840-9846
Abstract | Full Text HTML | PDF | PDF w/ Links
New Insight into Chiroptical Properties of 1,2-Diols Cyclic Sulfites.
Pawel̷ Chochrek, Jadwiga Frelek, Marcin Kwit and Jerzy Wicha
The Journal of Organic Chemistry 0 (proofing),
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Synthesis of All Possible Isomers Corresponding to the Proposed Structure of Montanacin E, and Their Antitumor Activity
Shunya Takahashi, Ryotaro Takahashi, Yayoi Hongo, Hiroyuki Koshino, Kazunori Yamaguchi and Taeko Miyagi
The Journal of Organic Chemistry 2009 74 (16), 6382-6385
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Total Synthesis of (−)- and (+)-Tedanalactam
Mahesh S. Majik, Perunninakulath S. Parameswaran and Santosh G. Tilve
The Journal of Organic Chemistry 2009 74 (16), 6378-6381
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Stereoselective Synthesis of anti-N-Protected 3-Amino-1,2-epoxides by Nucleophilic Addition to N-tert-Butanesulfinyl Imine of a Glyceraldehyde Synthon
Scott S. Harried, Michael D. Croghan, Matthew R. Kaller, Patricia Lopez, Wenge Zhong, Randall Hungate and Paul J. Reider
The Journal of Organic Chemistry 2009 74 (16), 5975-5982
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Organocatalytic Activity of Cinchona Alkaloids: Which Nitrogen Is More Nucleophilic?
Mahiuddin Baidya, Markus Horn, Hendrik Zipse and Herbert Mayr
The Journal of Organic Chemistry 0 (proofing),
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A Divergent Synthesis of the Δ¹³-9-Isofurans
Douglass F. Taber, Peiming Gu and Rui Li
The Journal of Organic Chemistry 2009 74 (15), 5516-5522
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Indoxamycins A−F. Cytotoxic Tricycklic Polypropionates from a Marine-Derived Actinomycete
Seizo Sato, Fumie Iwata, Takako Mukai, Shoichi Yamada, Jiro Takeo, Akihisa Abe and Hiroyuki Kawahara
The Journal of Organic Chemistry 2009 74 (15), 5502-5509
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Total Syntheses of (+)- and (−)-Pestalotiopsin A
Ken-ichi Takao, Nobuhiko Hayakawa, Reo Yamada, Taro Yamaguchi, Hiroshi Saegusa, Masatoshi Uchida, Suguru Samejima and Kin-ichi Tadano
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Stereoselective Synthesis and Absolute Configuration of the C1′−C25′ Fragment of Symbiodinolide
Hiroyoshi Takamura, Takeshi Murata, Takahiro Asai, Isao Kadota and Daisuke Uemura
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Oxygen Atom Transfer Reactions of Iridium and Osmium Complexes: Theoretical Study of Characteristic Features and Significantly Large Differences Between These Two Complexes
Atsushi Ishikawa, Yoshihide Nakao, Hirofumi Sato and Shigeyoshi Sakaki
Inorganic Chemistry 0 (proofing),
Abstract | Full Text HTML
Poly(bisnorbornanediol)
Nai-Ti Lin, Sherng-Long Lee, Jian-Yuan Yu, Chun-hsien Chen, Shou-Ling Huang and Tien-Yau Luh
Macromolecules 0 (proofing),
Abstract | Full Text HTML
Concise Syntheses of the Natural Products (+)-Sylvaticin and (+)-cis-Sylvaticin
Timothy J. Donohoe, Robert M. Harris, Oliver Williams, Gráinne C. Hargaden, Jeremy Burrows and Jeremy Parker
Journal of the American Chemical Society 0 (proofing),
Abstract | Full Text HTML
Dihydroxylation of 4-Substituted 1,2-Dioxines: A Concise Route to Branched Erythro Sugars
Tony V. Robinson, Daniel Sejer Pedersen, Dennis K. Taylor and Edward R. T. Tiekink
The Journal of Organic Chemistry 2009 74 (14), 5093-5096
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The Halichondrins and E7389
Katrina L. Jackson, James A. Henderson and Andrew J. Phillips
Chemical Reviews 2009 109 (7), 3044-3079
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Synthesis of All Possible Isomers Corresponding to the Proposed Structure of Montanacin E, and Their Antitumor Activity
Shunya Takahashi, Ryotaro Takahashi, Yayoi Hongo, Hiroyuki Koshino, Kazunori Yamaguchi and Taeko Miyagi
The Journal of Organic Chemistry 0 (proofing),
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Total Synthesis of Phoslactomycin A
Christian M. König, Björn Gebhardt, Cornelia Schleth, Mario Dauber and Ulrich Koert
Organic Letters 2009 11 (13), 2728-2731
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CuBr-Mediated Oxyalkylation of Vinylarenes under Aerobic Conditions via Cleavage of sp³ C−H Bonds α to Oxygen
Kai Cheng, Lehao Huang and Yuhong Zhang
Organic Letters 2009 11 (13), 2908-2911
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereoselective Synthesis of anti-N-Protected 3-Amino-1,2-epoxides by Nucleophilic Addition to N-tert-Butanesulfinyl Imine of a Glyceraldehyde Synthon
Scott S. Harried, Michael D. Croghan, Matthew R. Kaller, Patricia Lopez, Wenge Zhong, Randall Hungate and Paul J. Reider
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Total Synthesis of (−)- and (+)-Tedanalactam
Mahesh S. Majik, Peruninakulath S. Parameswaran and Santosh G. Tilve
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Indoxamycins A−F. Cytotoxic Tricycklic Polypropionated from a Marine-Derived Actinomycete
Seizo Sato, Fumie Iwata, Takako Mukai, Shoichi Yamada, Jiro Takeo, Akihisa Abe and Hiroyuki Kawahara
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
A Divergent Synthesis of the Δ¹³-9-Isofurans
Douglass F. Taber, Peiming Gu and Rui Li
The Journal of Organic Chemistry 0 (proofing),
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Stereoselective Synthesis of anti-β-Hydroxy-α-Amino Acids Using anti-Selective Asymmetric Hydrogenation
Yasumasa Hamada and Kazuishi Makino
2009, 227-238
Abstract | PDF | PDF w/ Links
Synthesis and Application of Chiral α-Amino Acids by Kinetic Resolution of Urethane-Protected α-Amino Acid N-Carboxyanhydrides with Modified Cinchona Alkaloid Catalysts
Jianfeng Hang, Yutaka Ishii, Yoshiro Furukawa, and Li Deng
2009, 265-287
Abstract | PDF | PDF w/ Links
Peptides Containing γ,δ-Dihydroxy-l-leucine
Benson J. Edagwa and Carol M. Taylor
The Journal of Organic Chemistry 2009 74 (11), 4132-4136
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A Concise Route to Branched Erythrono-γ-lactones. Synthesis of the Leaf-Closing Substance Potassium (±)-(2R,3R)-2,3,4-Trihydroxy-2-methylbutanoate
Daniel Sejer Pedersen, Tony V. Robinson, Dennis K. Taylor and Edward R. T. Tiekink
The Journal of Organic Chemistry 2009 74 (11), 4400-4403
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Rationally Improved Chiral Brønsted Acid for Catalytic Enantioselective Allylboration of Aldehydes with an Expanded Reagent Scope
Vivek Rauniyar and Dennis G. Hall
The Journal of Organic Chemistry 2009 74 (11), 4236-4241
Abstract | Full Text HTML | PDF | PDF w/ Links
The Halichondrins and E7389
Katrina L. Jackson, James A. Henderson and Andrew J. Phillips
Chemical Reviews 0 (proofing),
Abstract | Full Text HTML
CuBr-Mediated Oxyalkylation of Vinylarenes under Aerobic Conditions via Cleavage of sp³ C−H Bonds α to Oxygen
Kai Cheng, Lehao Huang and Yuhong Zhang
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Functionalization of the Semiconductor Surfaces of Diamond (100), Si (100), and Ge (100) by Cycloaddition of Transition Metal Oxides: A Theoretical Prediction
Yi-Jun Xu and Xianzhi Fu
Langmuir 0 (proofing),
Abstract | Full Text HTML
Synthesis and Biophysical Characterization of Chlorambucil Anticancer Ether Lipid Prodrugs
Palle J. Pedersen, Mikkel S. Christensen, Tristan Ruysschaert, Lars Linderoth, Thomas L. Andresen, Fredrik Melander, Ole G. Mouritsen, Robert Madsen and Mads H. Clausen
Journal of Medicinal Chemistry 2009 52 (10), 3408-3415
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Total Synthesis of Phoslactomycin A
Christian M. König, Björn Gebhardt, Cornelia Schleth, Mario Dauber and Ulrich Koert
Organic Letters 0 (proofing),
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Dihydroxylation of 4-Substituted 1,2-Dioxines: A Concise Route to Branched Erythro Sugars
Tony V. Robinson, Daniel Sejer Pedersen, Dennis K. Taylor and Edward R. T. Tiekink
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Total Synthesis of (±)-5-Deoxystrigol via Reductive Carbon−Carbon Bond Formation
Mitsuru Shoji, Eriko Suzuki and Minoru Ueda
The Journal of Organic Chemistry 2009 74 (10), 3966-3969
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Asymmetric Total Synthesis and Revision of the Absolute Configuration of 4-Keto-Clonostachydiol
Junjie Han, Yingpeng Su, Tuo Jiang, Yanfen Xu, Xing Huo, Xuegong She and Xinfu Pan
The Journal of Organic Chemistry 2009 74 (10), 3930-3932
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Peptides Containing γ,δ-Dihydroxy-l-leucine
Benson J. Edagwa and Carol M. Taylor
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Synthesis and Biophysical Characterization of Chlorambucil Anticancer Ether Lipid Prodrugs
Palle J. Pedersen, Mikkel S. Christensen, Tristan Ruysschaert, Lars Linderoth, Thomas L. Andresen, Fredrik Melander, Ole G. Mouritsen, Robert Madsen and Mads H. Clausen
Journal of Medicinal Chemistry 0 (proofing),
Abstract | Full Text HTML
Rationally Improved Chiral Brønsted Acid for Catalytic Enantioselective Allylboration of Aldehydes with an Expanded Reagent Scope
Vivek Rauniyar and Dennis G. Hall
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
A Concise Route to Branched Erythrono-γ-lactones. Synthesis of the Leaf-Closing Substance Potassium (±)-(2R,3R)-2,3,4-Trihydroxy-2-methylbutanoate
Daniel Sejer Pedersen, Tony V. Robinson, Dennis K. Taylor and Edward R. T. Tiekink
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Methanesulfonamide: a Cosolvent and a General Acid Catalyst in Sharpless Asymmetric Dihydroxylations
Mikko H. Junttila and Osmo O. E. Hormi
The Journal of Organic Chemistry 2009 74 (8), 3038-3047
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Asymmetric Total Synthesis and Revision of the Absolute Configuration of 4-Keto-Clonostachydiol
Junjie Han, Yingpeng Su, Tuo Jiang, Yanfen Xu, Xing Huo, Xuegong She and Xinfu Pan
The Journal of Organic Chemistry 0 (proofing),
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Diastereoselective Room-Temperature Pd-Catalyzed α-Arylation and Vinylation of Arylmandelic Acid Derivatives
Lei Jiang, Stefan Weist and Susanna Jansat
Organic Letters 2009 11 (7), 1543-1546
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Total Synthesis of (±)-5-Deoxystrigol via Reductive Carbon−Carbon Bond Formation
Mitsuru Shoji, Eriko Suzuki and Minoru Ueda
The Journal of Organic Chemistry 0 (proofing),
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Palladium-Catalyzed Diacetoxylation of Alkenes with Molecular Oxygen as Sole Oxidant
Azhong Wang, Huanfeng Jiang and Huoji Chen
Journal of the American Chemical Society 2009 131 (11), 3846-3847
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Diphosphination of Electron Poor Alkenes
Imre Hajdók, Falk Lissner, Martin Nieger, Sabine Strobel and Dietrich Gudat
Organometallics 2009 28 (6), 1644-1651
Abstract | Full Text HTML | PDF | PDF w/ Links
Ring-Opening Metathesis Polymerization-Based Synthesis of ICG-Containing Amphiphilic Triblock Copolymers for in Vivo Tumor Imaging
Koji Miki, Yoshiaki Kuramochi, Kazuaki Oride, Satoru Inoue, Hiroshi Harada, Masahiro Hiraoka and Kouichi Ohe
Bioconjugate Chemistry 2009 20 (3), 511-517
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Methanesulfonamide: a Cosolvent and a General Acid Catalyst in Sharpless Asymmetric Dihydroxylations
Mikko H. Junttila and Osmo O. E. Hormi
The Journal of Organic Chemistry 0 (proofing),
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Cleavage of Polarized P−P Bonds in N-Heterocyclic Diphosphines in Reactions with Metal Olefin Complexes
Sebastian Burck, Dietrich Gudat and Martin Nieger
Organometallics 2009 28 (5), 1447-1452
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Diastereoselective Room-Temperature Pd-Catalyzed α-Arylation and Vinylation of Arylmandelic Acid Derivatives
Lei Jiang, Stefan Weist and Susanna Jansat
Organic Letters 0 (proofing),
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Distortion, Interaction, and Conceptual DFT Perspectives of MO₄−Alkene (M = Os, Re, Tc, Mn) Cycloadditions
Daniel H. Ess
The Journal of Organic Chemistry 2009 74 (4), 1498-1508
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Synthesis of Tetrahydroquinolin-3-ols via CoCl₂-Catalyzed Reductive Cyclization of Nitro Cyclic Sulfites with NaBH₄
Arun R. Jagdale, R. Santhosh Reddy and Arumugam Sudalai
Organic Letters 2009 11 (4), 803-806
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Mitsunobu Approach to the Synthesis of Optically Active α,α-Disubstituted Amino Acids
Jonathan E. Green, David M. Bender, Stona Jackson, Martin J. O’Donnell and James R. McCarthy
Organic Letters 2009 11 (4), 807-810
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A Secondary Kinetic Isotope Effect Study of the 1-Deoxy-d-xylulose-5-phosphate Reductoisomerase-Catalyzed Reaction: Evidence for a Retroaldol-Aldol Rearrangement
Jeffrey W. Munos, Xiaotao Pu, Steven O. Mansoorabadi, Hak Joong Kim and Hung-wen Liu
Journal of the American Chemical Society 2009 131 (6), 2048-2049
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Diphosphination of Electron Poor Alkenes
Imre Hajdók, Falk Lissner, Martin Nieger, Sabine Strobel and Dietrich Gudat
Organometallics 0 (proofing),
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Ion Exchange Resins: Catalyst Recovery and Recycle
Pierluigi Barbaro and Francesca Liguori
Chemical Reviews 2009 109 (2), 515-529
Abstract | Full Text HTML | PDF | PDF w/ Links
Recyclable Stereoselective Catalysts
Alexandre F. Trindade, Pedro M. P. Gois and Carlos A. M. Afonso
Chemical Reviews 2009 109 (2), 418-514
Abstract | Full Text HTML | PDF | PDF w/ Links
Oxidative Cyclization Reactions of Trienes and Dienynes: Total Synthesis of Membrarollin
Claire L. Morris, Yulai Hu, Geoff D. Head, Lynda J. Brown, William G. Whittingham and Richard C. D. Brown
The Journal of Organic Chemistry 2009 74 (3), 981-988
Abstract | Full Text HTML | PDF | PDF w/ Links
Ring-Opening Metathesis Polymerization-Based Synthesis of ICG-Containing Amphiphilic Triblock Copolymers for in Vivo Tumor Imaging
Koji Miki, Yoshiaki Kuramochi, Kazuaki Oride, Satoru Inoue, Hiroshi Harada, Masahiro Hiraoka and Kouichi Ohe
Bioconjugate Chemistry 0 (proofing),
Abstract | Full Text HTML
Cleavage of Polarized P−P Bonds in N-Heterocyclic Diphosphines in Reactions with Metal Olefin Complexes
Sebastian Burck, Dietrich Gudat and Martin Nieger
Organometallics 0 (proofing),
Abstract | Full Text HTML
Asymmetric Synthesis of Tetrahydroquinolin-3-ols via CoCl₂-Catalyzed Reductive Cyclization of Nitro Cyclic Sulfites with NaBH₄
Arun R. Jagdale, R. Santhosh Reddy and Arumugam Sudalai
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Stereocontrolled Synthesis of d- and l-β-Rhamnopyranosides with 4-O-6-S-α-Cyanobenzylidene-Protected 6-Thiorhamnopyranosyl Thioglycosides
David Crich and Linfeng Li
The Journal of Organic Chemistry 2009 74 (2), 773-781
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Enantioselective Total Synthesis of (+)-Cassiol
Krastina V. Petrova, Justin T. Mohr and Brian M. Stoltz
Organic Letters 2009 11 (2), 293-295
Abstract | Full Text HTML | PDF | PDF w/ Links
Toward the Total Synthesis of the Brasilinolides: Stereocontrolled Assembly of a C1−C19 Polyol Segment
Ian Paterson, Friedrich A. Mühlthau, Christopher J. Cordier, Michael P. Housden, Paul M. Burton and Olivier Loiseleur
Organic Letters 2009 11 (2), 353-356
Abstract | Full Text HTML | PDF | PDF w/ Links
Recyclable Stereoselective Catalysts
Alexandre F. Trindade, Pedro M. P. Gois and Carlos A. M. Afonso
Chemical Reviews 0 (proofing),
Abstract | Full Text HTML
A Secondary Kinetic Isotope Effect Study of the 1-Deoxy-d-xylulose-5-phosphate Reductoisomerase-Catalyzed Reaction: Evidence for a Retroaldol-Aldol Rearrangement
Jeffrey W. Munos, Xiaotao Pu, Steven O. Mansoorabadi, Hak Joong Kim and Hung-wen Liu
Journal of the American Chemical Society 0 (proofing),
Abstract | Full Text HTML
Simple Chiral Derivatization Protocols for ¹H NMR and ¹⁹F NMR Spectroscopic Analysis of the Enantiopurity of Chiral Diols
Sonia Lozano Yeste, Magdalena E. Powell, Steven D. Bull and Tony D. James
The Journal of Organic Chemistry 2009 74 (1), 427-430
Abstract | Full Text HTML | PDF | PDF w/ Links
Distortion, Interaction, and Conceptual DFT Perspectives of MO₄−Alkene (M = Os, Re, Tc, Mn) Cycloadditions
Daniel H. Ess
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Homologation of Boronic Esters with Lithiated Epoxides for the Stereocontrolled Synthesis of 1,2- and 1,3-Diols and 1,2,4-Triols
Emeline Vedrenne, Olov A. Wallner, Maxime Vitale, Frank Schmidt and Varinder K. Aggarwal
Organic Letters 2009 11 (1), 165-168
Abstract | Full Text HTML | PDF | PDF w/ Links
An Efficient and General Enantioselective Synthesis of Sphingosine, Phythosphingosine, and 4-Substituted Derivatives
Josep Llaveria, Yolanda Díaz, M. Isabel Matheu and Sergio Castillón
Organic Letters 2009 11 (1), 205-208
Abstract | Full Text HTML | PDF | PDF w/ Links
Oxidative Cyclization Reactions of Trienes and Dienynes: Total Synthesis of Membrarollin
Claire L. Morris, Yulai Hu, Geoff D. Head, Lynda J. Brown, William G. Whittingham and Richard C. D. Brown
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Mitsunobu Approach to the Synthesis of Optically Active α,α-Disubstituted Amino Acids
Jonathan E. Green, David M. Bender, Stona Jackson, Martin J. O’Donnell and James R. McCarthy
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Enantioselective Synthesis of (+)-Cortistatin A, a Potent and Selective Inhibitor of Endothelial Cell Proliferation
Hong Myung Lee, Cristina Nieto-Oberhuber and Matthew D. Shair
Journal of the American Chemical Society 2008 130 (50), 16864-16866
Abstract | Full Text HTML | PDF | PDF w/ Links
Strategies for the Total Synthesis of C2−C11 Cyclized Cembranoids
J. Michael Ellis and Michael T. Crimmins
Chemical Reviews 2008 108 (12), 5278-5298
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of Pluraflavin A “Aglycone”
Benjamin J. D. Wright, John Hartung, Feng Peng, Ryan Van de Water, Haibo Liu, Quen-Hui Tan, Ting-Chao Chou and Samuel J. Danishefsky
Journal of the American Chemical Society 2008 130 (49), 16786-16790
Abstract | Full Text HTML | PDF | PDF w/ Links
Ion Exchange Resins: Catalyst Recovery and Recycle
Pierluigi Barbaro and Francesca Liguori
Chemical Reviews 0 (proofing),
Abstract | Full Text HTML
Toward the Total Synthesis of the Brasilinolides: Stereocontrolled Assembly of a C1−C19 Polyol Segment
Ian Paterson, Friedrich A. Mühlthau, Christopher J. Cordier, Michael P. Housden, Paul M. Burton and Olivier Loiseleur
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Homologation of Boronic Esters with Lithiated Epoxides for the Stereocontrolled Synthesis of 1,2- and 1,3-Diols and 1,2,4-Triols
Emeline Vedrenne, Olov A. Wallner, Maxime Vitale, Frank Schmidt and Varinder K. Aggarwal
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Enantioselective Total Synthesis of (+)-Cassiol
Krastina V. Petrova, Justin T. Mohr and Brian M. Stoltz
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Stereocontrolled Synthesis of d- and l-β-Rhamnopyranosides with 4-O-6-S-α-Cyanobenzylidene-Protected 6-Thiorhamnopyranosyl Thioglycosides
David Crich and Linfeng Li
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
An Efficient and General Enantioselective Synthesis of Sphingosine, Phythosphingosine, and 4-Substituted Derivatives
Josep Llaveria, Yolanda Díaz, M. Isabel Matheu and Sergio Castillón
Organic Letters 0 (proofing),
Abstract | Full Text HTML
Simple Chiral Derivatization Protocols for ¹H NMR and ¹⁹F NMR Spectroscopic Analysis of the Enantiopurity of Chiral Diols
Sonia Lozano Yeste, Magdalena E. Powell, Steven D. Bull and Tony D. James
The Journal of Organic Chemistry 0 (proofing),
Abstract | Full Text HTML
Synthesis of (+)-Didemniserinolipid B: Application of a 2-Allyl-4-fluorophenyl Auxiliary for Relay Ring-Closing Metathesis
Christopher C. Marvin, Eric A. Voight, Judy M. Suh, Christopher L. Paradise and Steven D. Burke
The Journal of Organic Chemistry 2008 73 (21), 8452-8457
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Syntheses of Racemic, Natural (−) and Unnatural (+) Glyceollin I
Rahul S. Khupse and Paul W. Erhardt
Organic Letters 2008 10 (21), 5007-5010
Abstract | Full Text HTML | PDF | PDF w/ Links
Spirastrellolide B: The Synthesis of Southern (C₉−C₂₅) Region
Srivari Chandrasekhar, Chegondi Rambabu and Annareddy Syamprasad Reddy
Organic Letters 2008 10 (19), 4355-4357
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthetic Studies Toward Pectenotoxin 2. Part II. Synthesis of the CDE and CDEF Ring Systems
Hannes Helmboldt, Jatta E. Aho and Petri M. Pihko
Organic Letters 2008 10 (19), 4183-4185
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Synthesis of the C10−C32 Core Structure of Spirangien A
Michael Lorenz and Markus Kalesse
Organic Letters 2008 10 (19), 4371-4374
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereospecific Synthesis of C₂ Symmetric Diamines from the Mother Diamine by Resonance-Assisted Hydrogen-Bond Directed Diaza-Cope Rearrangement
Hyunwoo Kim, Yen Nguyen, Cindy Pai-Hui Yen, Leonid Chagal, Alan J. Lough, B. Moon Kim and Jik Chin
Journal of the American Chemical Society 2008 130 (36), 12184-12191
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Synthesis of Tetrafluorinated Glucose and Galactose
Roxana S. Timofte and Bruno Linclau
Organic Letters 2008 10 (17), 3673-3676
Abstract | Full Text HTML | PDF | PDF w/ Links
Efficient and Selective Syntheses of (all-E)- and (6E,10Z)-2′-O-Methylmyxalamides D via Pd-Catalyzed Alkenylation−Carbonyl Olefination Synergy
Guangwei Wang, Zhihong Huang and Ei-ichi Negishi
Organic Letters 2008 10 (15), 3223-3226
Abstract | Full Text HTML | PDF | PDF w/ Links
Catalytic Enantioselective Allyl- and Crotylboration of Aldehydes Using Chiral Diol•SnCl₄ Complexes. Optimization, Substrate Scope and Mechanistic Investigations
Vivek Rauniyar, Huimin Zhai and Dennis G. Hall
Journal of the American Chemical Society 2008 130 (26), 8481-8490
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Contribution of Electrochemistry to Organometallic Catalysis
Anny Jutand,
Chemical Reviews 2008 108 (7), 2300-2347
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Total Synthesis of Leustroducsin B
Kazuyuki Miyashita, Tomoyuki Tsunemi, Takafumi Hosokawa, Masahiro Ikejiri and Takeshi Imanishi
The Journal of Organic Chemistry 2008 73 (14), 5360-5370
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A Chemical/Computational Approach to the Determination of Absolute Configuration of Flexible and Transparent Molecules: Aliphatic Diols As a Case Study
Sabina Tartaglia, Daniele Padula, Patrizia Scafato, Lucia Chiummiento and Carlo Rosini
The Journal of Organic Chemistry 2008 73 (13), 4865-4873
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Asymmetric Total Synthesis of (+)-Phoslactomycin B
Setsuya Shibahara, Masataka Fujino, Yasumasa Tashiro, Keisuke Takahashi, Jun Ishihara and Susumi Hatakeyama
Organic Letters 2008 10 (11), 2139-2142
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Stereocontrolled Synthesis of the Sterically Encumbered F Ring of Lancifodilactone G
Kwong Wah Lai and Leo A. Paquette
Organic Letters 2008 10 (11), 2115-2118
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Studies Directed toward the Total Synthesis of Lancifodilactone G: An Expeditious Route to the ABC Subunit
Leo A. Paquette and Kwong Wah Lai
Organic Letters 2008 10 (11), 2111-2113
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Preparation of Substituted Enol Derivatives From Terminal Alkynes and Their Synthetic Utility
John R. DeBergh, Kathleen M. Spivey and Joseph M. Ready
Journal of the American Chemical Society 2008 130 (25), 7828-7829
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The Carbohydrate−Sesquiterpene Interface. Directed Synthetic Routes to Both (+)- and (−)-Fomannosin from d-Glucose
Leo A. Paquette, Xiaowen Peng, Jiong Yang and Ho-Jung Kang
The Journal of Organic Chemistry 2008 73 (12), 4548-4558
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Lewis Base Activation of Lewis Acids: Catalytic, Enantioselective Addition of Glycolate-Derived Silyl Ketene Acetals to Aldehydes
Scott E. Denmark and Won-jin Chung
The Journal of Organic Chemistry 2008 73 (12), 4582-4595
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Synthesis of Homochiral Dihydroxy-4-nitroisoxazolines via One-Pot Asymmetric Dihydroxylation−Reduction
Mauro F. A. Adamo and Murali Nagabelli
Organic Letters 2008 10 (9), 1807-1810
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Epi-Cinchona Based Thiourea Organocatalyst Family as an Efficient Asymmetric Michael Addition Promoter: Enantioselective Conjugate Addition of Nitroalkanes to Chalcones and α,β-Unsaturated N-Acylpyrroles
Benedek Vakulya, Szilárd Varga and Tibor Soós
The Journal of Organic Chemistry 2008 73 (9), 3475-3480
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Synthetic Studies on Maitotoxin. 1. Stereoselective Synthesis of the C′D′E′F′-Ring System Having a Side Chain
Masayuki Morita, Seishi Ishiyama, Hiroyuki Koshino and Tadashi Nakata
Organic Letters 2008 10 (9), 1675-1678
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UnyLinker: An Efficient and Scaleable Synthesis of Oligonucleotides Utilizing a Universal Linker Molecule: A Novel Approach To Enhance the Purity of Drugs
Vasulinga T. Ravikumar, R. Krishna Kumar, Phil Olsen, Max N. Moore, Recaldo L. Carty, Mark Andrade, Dennis Gorman, Xuefeng Zhu, Isaiah Cedillo, Zhiwei Wang, Lucio Mendez, Anthony N. Scozzari, Gerardo Aguirre, Ratnasamy Somanathan and Sylvain Berneès
Organic Process Research & Development 2008 12 (3), 399-410
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Scalable Preparation of Both Enantiomers of 2-(1-Hydroxy-2-oxocyclohexyl)acetic Acid
Mitchell Vamos and Yoshihisa Kobayashi
The Journal of Organic Chemistry 2008 73 (10), 3938-3941
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De Novo Synthesis of a d-Galacturonic Acid Thioglycoside as Key to the Total Synthesis of a Glycosphingolipid from Sphingomonas yanoikuyae
Pierre Stallforth, Alexander Adibekian, and Peter H. Seeberger
Organic Letters 2008 10 (8), 1573-1576
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Synthesis of 7-Epi (+)-FR900482: An Epimer of Comparable Anti-Cancer Activity
Barry M. Trost and Brendan M. O'Boyle
Organic Letters 2008 10 (7), 1369-1372
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Formal Total Synthesis of Fostriecin via 1,4-Asymmetric Induction Using Cobalt-Alkyne Complex
Yujiro Hayashi, Hirofumi Yamaguchi, Maya Toyoshima, Kotaro Okado, Takumi Toyo, and Mitsuru Shoji
Organic Letters 2008 10 (7), 1405-1408
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Synthesis and Characterization of Poly(glyceryl glycerol) Block Copolymers
Frederik Wurm, Jörg Nieberle, and Holger Frey
Macromolecules 2008 41 (6), 1909-1911
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Enantioselective Total Synthesis of Peloruside A: A Potent Microtubule Stabilizer
Arun K. Ghosh, Xiaoming Xu, Jae-Hun Kim, and Chun-Xiao Xu
Organic Letters 2008 10 (5), 1001-1004
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Addition/Oxidative Rearrangement of 3-Furfurals and 3-Furyl Imines: New Approaches to Substituted Furans and Pyrroles
Ann Rowley Kelly, Michael H. Kerrigan, and Patrick J. Walsh
Journal of the American Chemical Society 2008 130 (12), 4097-4104
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Insect Growth Regulatory Effects of Linear Diterpenoids and Derivatives from Baccharis thymifolia
Virginia E. Juan Hikawczuk, J. Roberto Saad, Oscar S. Giordano, Celina García, Tomás Martín, Víctor S. Martín, Marta E. Sosa and Carlos E. Tonn
Journal of Natural Products 2008 71 (2), 190-194
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The Mechanism of Carbon Dioxide Catalysis in the Hydrogen Peroxide N-Oxidation of Amines
Bharathi Balagam and David E. Richardson
Inorganic Chemistry 2008 47 (3), 1173-1178
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Colorimetric Fluoride Ion Sensing by Polyborylated Ferrocenes: Structural Influences on Thermodynamics and Kinetics
Joanna K. Day, Christopher Bresner, Natalie D. Coombs, Ian A. Fallis, Li-Ling Ooi, and Simon Aldridge
Inorganic Chemistry 2008 47 (3), 793-804
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Alternative and Expedient Asymmetric Syntheses of l-(+)-Noviose
Stephen Hanessian and Luciana Auzzas
Organic Letters 2008 10 (2), 261-264
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Total Synthesis of (3R,9R,10R)-Panaxytriol via Tandem Metathesis and Metallotropic [1,3]-Shift as a Key Step
Eun Jin Cho and Daesung Lee
Organic Letters 2008 10 (2), 257-259
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Chiral Tertiary Diamines in Asymmetric Synthesis
Jean-Claude Kizirian
Chemical Reviews 2008 108 (1), 140-205
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Synthesis and Structural Variation of Iron, Rhodium, Palladium, and Silver Complexes of a Chiral N-Heterocyclic Carbene−Phenoxyimine Hybrid Ligand
Gavin Dyson, Jean-Cédric Frison, Stevan Simonovic, Adrian C. Whitwood and Richard E. Douthwaite
Organometallics 2008 27 (2), 281-288
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Asymmetric Enamine Catalysis
Santanu Mukherjee, Jung Woon Yang, Sebastian Hoffmann, and Benjamin List
Chemical Reviews 2007 107 (12), 5471-5569
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Stereoselective Anhydride Openings
Iuliana Atodiresei, Ingo Schiffers, and Carsten Bolm
Chemical Reviews 2007 107 (12), 5683-5712
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Recent Developments in the Use of Catalytic Asymmetric Ammonium Enolates in Chemical Synthesis
Matthew J. Gaunt and Carin C. C. Johansson
Chemical Reviews 2007 107 (12), 5596-5605
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Enantioselective Pinacol Coupling of Aryl Aldehydes Catalyzed by Chiral Salan−Mo(IV) Complexes
Hongwei Yang, Hongsong Wang, and Chengjian Zhu
The Journal of Organic Chemistry 2007 72 (26), 10029-10034
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Novel Non-PEG Derived Polyethers as Solid Supports. 2. Solid-Phase Synthesis Studies
Gabriel Cavalli, Andrew G. Shooter, David A. Pears, Donald A. Wellings, Saeed Gulzar and Joachim H. G. Steinke
Journal of Combinatorial Chemistry 2007 9 (6), 1012-1027
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New Efficient Route to an Advanced Precursor of the AB Spiroketal of Spongistatins
Sylvain Favre, Sandrine Gerber-Lemaire, and Pierre Vogel
Organic Letters 2007 9 (24), 5107-5110
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Synthesis of the C1−C52 Fragment of Amphidinol 3, Featuring a β-Alkoxy Alkyllithium Addition Reaction
John R. Huckins, Javier de Vicente, and Scott D. Rychnovsky
Organic Letters 2007 9 (23), 4757-4760
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Stereocontrolled Synthesis of Tetrasubstituted Olefins
Alison B. Flynn and William W. Ogilvie
Chemical Reviews 2007 107 (11), 4698-4745
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Importance of Counterion Reactivity on the Deactivation of Co−Salen Catalysts in the Hydrolytic Kinetic Resolution of Epichlorohydrin
Surbhi Jain, Xiaolai Zheng, Christopher W. Jones, Marcus Weck, and Robert J. Davis
Inorganic Chemistry 2007 46 (21), 8887-8896
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Total Syntheses of Schulzeines B and C
Mukund K. Gurjar, Chinmoy Pramanik, Debabrata Bhattasali, C. V. Ramana, and Debendra K. Mohapatra
The Journal of Organic Chemistry 2007 72 (17), 6591-6594
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A General Approach to the Synthesis of 1-Deoxy-l-iminosugars
Annalisa Guaragna, Stefano D'Errico, Daniele D'Alonzo, Silvana Pedatella, and Giovanni Palumbo
Organic Letters 2007 9 (17), 3473-3476
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Studies toward the Synthesis of Pinnatoxins: The B,C,D-Dispiroketal Fragment
Chong-Dao Lu and Armen Zakarian
Organic Letters 2007 9 (16), 3161-3163
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Mechanism of Cis-Dihydroxylation and Epoxidation of Alkenes by Highly H₂O₂ Efficient Dinuclear Manganese Catalysts
Johannes W. de Boer, Wesley R. Browne, Jelle Brinksma, Paul L. Alsters, Ronald Hage, and Ben L. Feringa
Inorganic Chemistry 2007 46 (16), 6353-6372
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Synthesis of DEFG Ring of Complestatin and Chloropeptin I: Highly Atropdiastereoselective Macrocyclization by Intramolecular Suzuki-Miyaura Reaction
Yanxing Jia, Michèle Bois-Choussy, and Jieping Zhu
Organic Letters 2007 9 (12), 2401-2404
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Oxidation of Tertiary Silanes by Osmium Tetroxide
Karine Valliant-Saunders, Erica Gunn, G. Robert Shelton, David A. Hrovat, Weston Thatcher Borden, and James M. Mayer
Inorganic Chemistry 2007 46 (13), 5212-5219
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Catalysis in Ionic Liquids
Vasile I. Pârvulescu and Christopher Hardacre
Chemical Reviews 2007 107 (6), 2615-2665
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On the Hydrolysis Step in Osmium Catalyzed Asymmetric Dihydroxylations
Mikko H. Junttila and Osmo E. O. Hormi
The Journal of Organic Chemistry 2007 72 (8), 2956-2961
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Practical Method for the Absolute Configuration Assignment of tert/tert 1,2-Diols Using Their Complexes with Mo₂(OAc)₄
Marcin Górecki, Ewa Jabłońska, Anna Kruszewska, Agata Suszczyńska, Zofia Urbańczyk-Lipkowska, Michael Gerards, Jacek W. Morzycki, Wojciech J. Szczepek, and Jadwiga Frelek
The Journal of Organic Chemistry 2007 72 (8), 2906-2916
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A Series of [3 + 2] Cycloaddition Products from the Reaction of Rhenium Oxo Complexes with Diphenyl Ketene
Michael Middleditch, James C. Anderson, Alexander J. Blake, and Clare Wilson
Inorganic Chemistry 2007 46 (7), 2797-2804
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Nickel-Catalyzed Coupling Producing (2Z)-2,4-Alkadien-1-ols, Conversion to (E)-3-Alkene-1,2,5-triol Derivatives, and Synthesis of Decarestrictine D
Yuichi Kobayashi, Shinya Yoshida, Moriteru Asano, Akira Takeuchi, and Hukum P. Acharya
The Journal of Organic Chemistry 2007 72 (5), 1707-1716
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Pectenotoxin-2 Synthetic Studies. 3. Assessment of the Capacity for Stereocontrolled Cyclization To Form the Entire C1−C26 Subunit Based upon the Double Bond Geometry Across C15-C16
Patrick D. O'Connor, Christopher K. Knight, Dirk Friedrich, Xiaowen Peng, and Leo A. Paquette
The Journal of Organic Chemistry 2007 72 (5), 1747-1754
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Aldehyde-Selective Wacker Oxidation in a Thiyl-Mediated Vinyl Group Transfer Route to Daunosamine
Gregory K. Friestad, Tao Jiang, and Alex K. Mathies
Organic Letters 2007 9 (5), 777-780
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Palladium-Catalyzed Aerobic Oxidative Amination of Alkenes: Development of Intra- and Intermolecular Aza-Wacker Reactions
Vasily Kotov, Christopher C. Scarborough, and Shannon S. Stahl
Inorganic Chemistry 2007 46 (6), 1910-1923
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Development of an Access Route to the C31−C52 Central Core of Amphidinol 3
Matthew W. Bedore, Shuh-Kuen Chang, and Leo A. Paquette
Organic Letters 2007 9 (3), 513-516
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Phosphine-Dependent Stereoselectivity in the Mitsunobu Cyclodehydration of 1,2-Diols: Stereodivergent Approach to Triaryl-Substituted Epoxides
Noemí García-Delgado, Antoni Riera, and Xavier Verdaguer
Organic Letters 2007 9 (4), 635-638
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Synthesis of the Pyrrolidinone Core of KSM-2690 B
Timothy J. Donohoe, Jessica Y. K. Chiu, and Rhian E. Thomas
Organic Letters 2007 9 (3), 421-424
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A Biosynthetically-Inspired Synthesis of the Tetrahydrofuran Core of Obtusallenes II and IV
D. Christopher Braddock, Roshni Bhuva, David S. Millan, Yolanda Pérez-Fuertes, Craig A. Roberts, Richard N. Sheppard, Savade Solanki, Elaine S. E. Stokes, and Andrew J. P. White
Organic Letters 2007 9 (3), 445-448
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Enantioselective Synthesis of α-Tertiary Hydroxyaldehydes by Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates
Barry M. Trost, Jiayi Xu, and Markus Reichle
Journal of the American Chemical Society 2007 129 (2), 282-283
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Preparation of Chiral α-Oxy-[²H₁]methyllithiums of 99% ee and Determination of Their Configurational Stability
Dagmar Kapeller, Roland Barth, Kurt Mereiter, and Friedrich Hammerschmidt
Journal of the American Chemical Society 2007 129 (4), 914-923
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Single Enantiomer Epoxides by Bromomandelation of Prochiral Alkenes
Douglass F. Taber and Jiang-lin Liang
The Journal of Organic Chemistry 2007 72 (2), 431-434
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Synthesis of Psymberin Analogues: Probing a Functional Correlation with the Pederin/Mycalamide Family of Natural Products
Xin Jiang, Noelle Williams, and Jef K. De Brabander
Organic Letters 2007 9 (2), 227-230
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Ultrafast and Ultraslow Oxygen Atom Transfer Reactions between Late Metal Centers
Kevin C. Fortner, David S. Laitar, John Muldoon, Lihung Pu, Sonja B. Braun-Sand, Olaf Wiest, and Seth N. Brown
Journal of the American Chemical Society 2007 129 (3), 588-600
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Where Is the Limit of Highly Fluorinated High-Oxidation-State Osmium Species?
Sebastian Riedel and Martin Kaupp
Inorganic Chemistry 2006 45 (26), 10497-10502
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Concise Synthesis of Arnottin I and (−)-Arnottin II
Fujiko Konno, Tsutomu Ishikawa, Masatoshi Kawahata, and Kentaro Yamaguchi
The Journal of Organic Chemistry 2006 71 (26), 9818-9823
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Concise Strategy to the Core Structure of the Macrolide Queenslandon
Anton S. Khartulyari, Manmohan Kapur, and Martin E. Maier
Organic Letters 2006 8 (25), 5833-5836
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New Synthetic Routes toward Enantiopure Nitrogen Donor Ligands
Xavier Sala, Anna M. Rodríguez, Montserrat Rodríguez, Isabel Romero, Teodor Parella, Alexander von Zelewsky, Antoni Llobet, and Jordi Benet-Buchholz
The Journal of Organic Chemistry 2006 71 (25), 9283-9290
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Enantioselective Synthesis of N1999A2
Nan Ji, Hardwin O'Dowd, Brad M. Rosen, and Andrew G. Myers
Journal of the American Chemical Society 2006 128 (46), 14825-14827
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On the Biosynthetic Origin of Methoxymalonyl-Acyl Carrier Protein, the Substrate for Incorporation of “Glycolate” Units into Ansamitocin and Soraphen A
Silke C. Wenzel, Rachel M. Williamson, Christian Grünanger, Jun Xu, Klaus Gerth, Rodolfo A. Martinez, Steven J. Moss, Brian J. Carroll, Stephanie Grond, Clifford J. Unkefer, Rolf Müller, and Heinz G. Floss
Journal of the American Chemical Society 2006 128 (44), 14325-14336
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A Metal-Free Approach to the Synthesis of Indoline Derivatives by a Phenyliodine(III) Bis(trifluoroacetate)-Mediated Amidohydroxylation Reaction
Arkaitz Correa, Imanol Tellitu, Esther Domínguez, and Raul SanMartin
The Journal of Organic Chemistry 2006 71 (21), 8316-8319
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Osmium Catalyzed Dihydroxylation of 1,2-Dioxines: A New Entry for Stereoselective Sugar Synthesis
Tony V. Robinson, Dennis K. Taylor, and Edward R. T. Tiekink
The Journal of Organic Chemistry 2006 71 (19), 7236-7244
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Hydrazines and Azides via the Metal-Catalyzed Hydrohydrazination and Hydroazidation of Olefins
Jérôme Waser, Boris Gaspar, Hisanori Nambu, and Erick M. Carreira
Journal of the American Chemical Society 2006 128 (35), 11693-11712
Abstract | Full Text HTML | PDF | PDF w/ Links
De Novo Synthesis of 2-Substituted syn-1,3-Diols via an Iterative Asymmetric Hydration Strategy
Md. Moinuddin Ahmed, Matthew S. Mortensen, and George A. O'Doherty
The Journal of Organic Chemistry 2006 71 (20), 7741-7746
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Progressive−Convergent Elucidation of Stereochemistry in Complex Polyols. The Absolute Configuration of (−)-Sagittamide A
Sarah C. Lievens and Tadeusz F. Molinski
Journal of the American Chemical Society 2006 128 (36), 11764-11765
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Approach to the Synthesis of Cladiell-11-ene-3,6,7-triol
John M. Hutchison, Harriet A. Lindsay, Silvana S. Dormi, Gavin D. Jones, David A. Vicic, and Matthias C. McIntosh
Organic Letters 2006 8 (17), 3663-3665
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Convergent Synthesis of Pyragonicin
Shunya Takahashi, Yayoi Hongo, Narihito Ogawa, Hiroyuki Koshino, and Tadashi Nakata
The Journal of Organic Chemistry 2006 71 (16), 6305-6308
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Synthesis of Pentahydroxy Indolizidine Alkaloids Using Ring Closing Metathesis: Attempts To Find the Correct Structure of Uniflorine A
Narayan S. Karanjule, Shankar D. Markad, and Dilip D. Dhavale
The Journal of Organic Chemistry 2006 71 (16), 6273-6276
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An Outside-In Approach to Adjacent Bistetrahydrofuran Annonaceous Acetogenins with C₂ Core Symmetry. Total Synthesis of Asimicin and a C32 Analogue
James A. Marshall and Jesse J. Sabatini
Organic Letters 2006 8 (16), 3557-3560
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De Novo Asymmetric Syntheses of Muricatacin and Its Analogues via Dihydroxylation of Dienoates
Md. Moinuddin Ahmed, Hu Cui, and George A. O'Doherty
The Journal of Organic Chemistry 2006 71 (17), 6686-6689
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Total Synthesis and Biological Evaluation of Neodysiherbaine A and Analogues
Muneo Shoji, Nobuyuki Akiyama, Koichi Tsubone, L. Leanne Lash, James M. Sanders, Geoffrey T. Swanson, Ryuichi Sakai, Keiko Shimamoto, Masato Oikawa, and Makoto Sasaki
The Journal of Organic Chemistry 2006 71 (14), 5208-5220
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Asymmetric Synthesis of Active Pharmaceutical Ingredients
Vittorio Farina, Jonathan T. Reeves, Chris H. Senanayake, and Jinhua J. Song
Chemical Reviews 2006 106 (7), 2734-2793
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Total Synthesis of a 28-Member Stereoisomer Library of Murisolins
Dennis P. Curran, Qisheng Zhang, Cyrille Richard, Hejun Lu, Venugopal Gudipati, and Craig S. Wilcox
Journal of the American Chemical Society 2006 128 (29), 9561-9573
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Large-Scale Oxidations in the Pharmaceutical Industry
Stéphane Caron, Robert W. Dugger, Sally Gut Ruggeri, John A. Ragan, and David H. Brown Ripin
Chemical Reviews 2006 106 (7), 2943-2989
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Highly Regioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and Evidence for cis-Aminopalladation and S_N2 C−O Bond Formation
Guosheng Liu and Shannon S. Stahl
Journal of the American Chemical Society 2006 128 (22), 7179-7181
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Enantio- and Diastereocontrolled Total Synthesis of (+)-Boronolide
Pradeep Kumar and S. Vasudeva Naidu
The Journal of Organic Chemistry 2006 71 (10), 3935-3941
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Simple Protocol for NMR Analysis of the Enantiomeric Purity of Diols
Andrew M. Kelly, Yolanda Pérez-Fuertes, Susumu Arimori, Steven D. Bull, and Tony D. James
Organic Letters 2006 8 (10), 1971-1974
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Chemocatalysis and Biocatalysis (Biotransformation): Some Thoughts of a Chemist and of a Biotechnologist
James E. Leresche and Hans-Peter Meyer
Organic Process Research & Development 2006 10 (3), 572-580
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Stereoselective Synthesis of Protected 1,2-Diols and 1,2,3-Triols by a Tandem Hydroboration−Coupling Sequence
Manmohan Kapur, Anton Khartulyari, and Martin E. Maier
Organic Letters 2006 8 (8), 1629-1632
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Single-Isomer Tetrasubstituted Olefins from Regioselective and Stereospecific Palladium-Catalyzed Coupling of β-Chloro-α-iodo-α,β-unsaturated Esters
Alison B. Lemay, Katarina S. Vulic, and William W. Ogilvie
The Journal of Organic Chemistry 2006 71 (9), 3615-3618
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Asymmetric Synthesis of Four Isomers of 2-C-Trifluoromethylerythritol
Hua Wang, Xiaoming Zhao, Youhua Li, and Long Lu
The Journal of Organic Chemistry 2006 71 (8), 3278-3281
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Enantioselective Synthesis of Cyclic Enol Ethers and All-Carbon Quaternary Stereogenic Centers Through Catalytic Asymmetric Ring-Closing Metathesis
Ai-Lan Lee, Steven J. Malcolmson, Alessandra Puglisi, Richard R. Schrock, and Amir H. Hoveyda
Journal of the American Chemical Society 2006 128 (15), 5153-5157
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Catalytic Asymmetric Dihydroxylation of 1-Substituted-1-ferrocenylethenes: An Enantioselective Entry to Chiral Tertiary Ferrocenylcarbinols and Ferrocenylalkylamines
Rosa M. Moreno, Agustí Bueno, and Albert Moyano
The Journal of Organic Chemistry 2006 71 (6), 2528-2531
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Molecular Simplification in Bioactive Molecules: Formal Synthesis of (+)-Muconin
Fernando R. Pinacho Crisóstomo, Romen Carrillo, Leticia G. León, Tomás Martín, José M. Padrón, and Víctor S. Martín
The Journal of Organic Chemistry 2006 71 (6), 2339-2345
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A General, Convergent Strategy for the Construction of Indolizidine Alkaloids: Total Syntheses of (−)-Indolizidine 223AB and Alkaloid (−)-205B
Amos B. Smith, III and Dae-Shik Kim
The Journal of Organic Chemistry 2006 71 (7), 2547-2557
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Chemistry of Carbon Nanotubes
Dimitrios Tasis, Nikos Tagmatarchis, Alberto Bianco, and Maurizio Prato
Chemical Reviews 2006 106 (3), 1105-1136
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Synthesis of the Proposed Structure of Mucoxin via Regio- and Stereoselective Tetrahydrofuran Ring-Forming Strategies
Radha S. Narayan and Babak Borhan
The Journal of Organic Chemistry 2006 71 (4), 1416-1429
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S_N2 Reaction of Sulfur Nucleophiles with Hindered Sulfamidates: Enantioselective Synthesis of α-Methylisocysteine
Alberto Avenoza, Jesús H. Busto, Gonzalo Jiménez-Osés, and Jesús M. Peregrina
The Journal of Organic Chemistry 2006 71 (4), 1692-1695
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Total Synthesis and Revision of C6 Stereochemistry of (+)-Amphidinolide W
Arun K. Ghosh and Gangli Gong
The Journal of Organic Chemistry 2006 71 (3), 1085-1093
Abstract | Full Text HTML | PDF | PDF w/ Links
Functionalization of Metal-Protected Chiral Phosphines via Simple Organic Transformations
Wee-Chuan Yeo, Jagadese J. Vittal, Lip Lin Koh, Geok Kheng Tan, and Pak-Hing Leung
Organometallics 2006 25 (5), 1259-1269
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Synthesis of the Enediol Isofurans, Endogenous Oxidation Products of Arachidonic Acid
Douglass F. Taber and Zhe Zhang
The Journal of Organic Chemistry 2006 71 (3), 926-933
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Total Synthesis as a Resource in Drug Discovery: The First In Vivo Evaluation of Panaxytriol and Its Derivatives
Heedong Yun, Ting-Chao Chou, Huajin Dong, Yuan Tian, Yue-ming Li, and Samuel J. Danishefsky
The Journal of Organic Chemistry 2005 70 (25), 10375-10380
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Total Synthesis of Natural tert-Alkylamino Hydroxy Carboxylic Acids
Sung Ho Kang, Suk Youn Kang, Hee-Seung Lee, and Alan J. Buglass
Chemical Reviews 2005 105 (12), 4537-4558
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Asymmetric Total Synthesis of the 1-epi-Aglycon of the Cripowellins A and B
Dieter Enders, Achim Lenzen, Michael Backes, Carsten Janeck, Kelly Catlin, Marie-Isabelle Lannou, Jan Runsink, and Gerhard Raabe
The Journal of Organic Chemistry 2005 70 (25), 10538-10551
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Synthesis of the C6−C21 Segment of Amphidinolide E
James A. Marshall, Gregory Schaaf, and Andrew Nolting
Organic Letters 2005 7 (23), 5331-5333
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De Novo Asymmetric Synthesis of Anamarine and Its Analogues
Dong Gao and George A. O'Doherty
The Journal of Organic Chemistry 2005 70 (24), 9932-9939
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Synthesis of the C(43)−C(67) Fragment of Amphidinol 3
Jacqueline D. Hicks, Eric M. Flamme, and William R. Roush
Organic Letters 2005 7 (24), 5509-5512
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Synthesis of cis- and trans-2,5-Disubstituted Tetrahydrofurans by a Tandem Dihydroxylation-S_N2 Cyclization Sequence
James A. Marshall and Jesse J. Sabatini
Organic Letters 2005 7 (22), 4819-4822
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Alkene cis-Dihydroxylation by [(Me₃tacn)(CF₃CO₂)Ru^VIO₂]ClO₄ (Me₃tacn = 1,4,7-Trimethyl-1,4,7-triazacyclononane): Structural Characterization of [3 + 2] Cycloadducts and Kinetic Studies
Wing-Ping Yip, Wing-Yiu Yu, Nianyong Zhu, and Chi-Ming Che
Journal of the American Chemical Society 2005 127 (41), 14239-14249
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Curved Pi-Conjugation, Aromaticity, and the Related Chemistry of Small Fullerenes (<C₆₀) and Single-Walled Carbon Nanotubes
Xin Lu and Zhongfang Chen
Chemical Reviews 2005 105 (10), 3643-3696
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Total Synthesis of (+)-Amphidinolide A. Assembly of the Fragments
Barry M. Trost, Stephen T. Wrobleski, John D. Chisholm, Paul E. Harrington, and Michael Jung
Journal of the American Chemical Society 2005 127 (39), 13589-13597
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Toward the Synthesis of Spirastrellolide A: Construction of a Tetracyclic C₂₆−C₄₀ Subunit Containing the DEF-Bis-Spiroacetal
Ian Paterson, Edward A. Anderson, Stephen M. Dalby, and Olivier Loiseleur
Organic Letters 2005 7 (19), 4121-4124
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Enantioselective Synthesis of Apoptolidin Sugars
Michael T. Crimmins and Alan Long
Organic Letters 2005 7 (19), 4157-4160
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Synthesis of a New Chiral N,N,N-Tridentate Pyridinebisimidazoline Ligand Library and Its Application in Ru-Catalyzed Asymmetric Epoxidation
Santosh Bhor, Gopinathan Anilkumar, Man Kin Tse, Markus Klawonn, Christian Döbler, Bianca Bitterlich, Anne Grotevendt, and Matthias Beller
Organic Letters 2005 7 (16), 3393-3396
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Copper(II) Acetate Promoted Intramolecular Diamination of Unactivated Olefins
Thomas P. Zabawa, Dhanalakshmi Kasi, and Sherry R. Chemler
Journal of the American Chemical Society 2005 127 (32), 11250-11251
Abstract | Full Text HTML | PDF | PDF w/ Links
Extending Pummerer Reaction Chemistry. Development of a Strategy for the Regio- and Stereoselective Oxidative Cyclization of 3-(ω-Nucleophile)-Tethered Indoles
Ken S. Feldman, Daniela Boneva Vidulova, and Andrew G. Karatjas
The Journal of Organic Chemistry 2005 70 (16), 6429-6440
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Synthesis of the Branched C-Glycoside Substructure of Altromycin B
Bonsuk Koo and Frank E. McDonald
Organic Letters 2005 7 (17), 3621-3624
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Synthesis of the Aglycones of Altromycins and Kidamycin from a Common Intermediate
ZhongBo Fei and Frank E. McDonald
Organic Letters 2005 7 (17), 3617-3620
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Oxocarbenium Ion Cyclizations for C-Branched Cyclitols: Synthesis of a Relay Intermediate for Fumagillin Analogues
Fatoumata Camara, Johana Angarita, and David R. Mootoo
The Journal of Organic Chemistry 2005 70 (17), 6870-6875
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The Structure of a Trimolecular Liquid: tert-Butyl Alcohol:Cyclohexene:Water
D. T. Bowron and S. Díaz Moreno
The Journal of Physical Chemistry B 2005 109 (33), 16210-16218
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A Bidirectional Approach to the Synthesis of a Complete Library of Adjacent-Bis-THF Annonaceous Acetogenins
Sanjib Das, Lian-Sheng Li, Sunny Abraham, Zhiyong Chen, and Subhash C. Sinha
The Journal of Organic Chemistry 2005 70 (15), 5922-5931
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A Convenient Enantioselective Synthesis of (S)-α-Trifluoromethylisoserine
Alberto Avenoza, Jesús H. Busto, Gonzalo Jiménez-Osés, and Jesús M. Peregrina
The Journal of Organic Chemistry 2005 70 (14), 5721-5724
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anti-1,2-Diols via Ni-Catalyzed Reductive Coupling of Alkynes and α-Oxyaldehydes
Torsak Luanphaisarnnont, Chudi O. Ndubaku, and Timothy F. Jamison
Organic Letters 2005 7 (14), 2937-2940
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cis-Dihydroxylation and Epoxidation of Alkenes by [Mn₂O(RCO₂)₂(tmtacn)₂]: Tailoring the Selectivity of a Highly H₂O₂-Efficient Catalyst
Johannes W. de Boer, Jelle Brinksma, Wesley R. Browne, Auke Meetsma, Paul L. Alsters, Ronald Hage, and Ben L. Feringa
Journal of the American Chemical Society 2005 127 (22), 7990-7991
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Palladium-Catalyzed Ring-Forming Aminoacetoxylation of Alkenes
Erik J. Alexanian, Chulbom Lee, and Erik J. Sorensen
Journal of the American Chemical Society 2005 127 (21), 7690-7691
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One-Pot Regio- and Stereoselective Cyclization of 1,2,n-Triols
Tao Zheng, Radha S. Narayan, Jennifer M. Schomaker, and Babak Borhan
Journal of the American Chemical Society 2005 127 (19), 6946-6947
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Total Synthesis of Microcarpalide
Pradeep Kumar and S. Vasudeva Naidu
The Journal of Organic Chemistry 2005 70 (10), 4207-4210
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Transition State Studies on the Dioxirane-Mediated Asymmetric Epoxidation via Kinetic Resolution and Desymmetrization
Jon C. Lorenz, Michael Frohn, Xiaoming Zhou, Jian-Rong Zhang, Yong Tang, Christopher Burke, and Yian Shi
The Journal of Organic Chemistry 2005 70 (8), 2904-2911
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Pectenotoxin-2 Synthetic Studies. 2. Construction and Conjoining of ABC and DE Eastern Hemisphere Subtargets
Dmitriy Bondar, Jian Liu, Thomas Müller, and Leo A. Paquette
Organic Letters 2005 7 (9), 1813-1816
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Efficient Total Synthesis of Sapinofuranone B
Pradeep Kumar, S. Vasudeva Naidu, and Priti Gupta
The Journal of Organic Chemistry 2005 70 (7), 2843-2846
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Ligand-Catalyzed Asymmetric Alkynylboration of Enones: A New Paradigm for Asymmetric Synthesis Using Organoboranes
T. Robert Wu and J. Michael Chong
Journal of the American Chemical Society 2005 127 (10), 3244-3245
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Synthesis of the C(1)−C(25) Fragment of Amphidinol 3: Application of the Double-Allylboration Reaction for Synthesis of 1,5-Diols
Eric M. Flamme and William R. Roush
Organic Letters 2005 7 (7), 1411-1414
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Enantioselective Synthesis of 10-epi-Anamarine via an Iterative Dihydroxylation Sequence
Dong Gao and George A. O'Doherty
Organic Letters 2005 7 (6), 1069-1072
Abstract | Full Text HTML | PDF | PDF w/ Links
Ligand-Assisted Reduction of Osmium Tetroxide with Molecular Hydrogen via a [3+2] Mechanism
Ahmad Dehestani, Wai Han Lam, David A. Hrovat, Ernest R. Davidson, Weston Thatcher Borden, and James M. Mayer
Journal of the American Chemical Society 2005 127 (10), 3423-3432
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Total Synthesis and Elucidation of the Absolute Configuration of the Diterpene Tonantzitlolone
Christian Jasper, Rüdiger Wittenberg, Monika Quitschalle, Jasmin Jakupovic, and Andreas Kirschning
Organic Letters 2005 7 (3), 479-482
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Structure−Property Relationship in py-Hexahydrocinchonidine Diastereomers: Ab Initio and NMR Study
György Szöllösi, Abhijit Chatterjee, Péter Forgó, Mihály Bartók, and Fujio Mizukami
The Journal of Physical Chemistry A 2005 109 (5), 860-868
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Asymmetric Synthesis of Both the Enantiomers of trans-3-Hydroxypipecolic Acid
Pradeep Kumar and Mandar S. Bodas
The Journal of Organic Chemistry 2005 70 (1), 360-363
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Computational Study of Low-Coordinate Rhenium Diolates, Metallaoxetanes, Oxo Complexes, and Carbenes
Sanja Narancic and Peter Chen
Organometallics 2005 24 (1), 10-12
Abstract | Full Text HTML | PDF | PDF w/ Links
Diversity-Oriented Synthesis of Polyketide Natural Products via Iterative Chemo- and Stereoselective Functionalization of Polyenoates: Development of a Unified Approach for the C(1−19) Segments of Lituarines A−C
Amos B. Smith, III, Shawn P. Walsh, Michael Frohn, and Matthew O. Duffey
Organic Letters 2005 7 (1), 139-142
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Total Synthesis of Ustiloxin D and Considerations on the Origin of Selectivity of the Asymmetric Allylic Alkylation
Andrew M. Sawayama, Hiroko Tanaka, and Thomas J. Wandless
The Journal of Organic Chemistry 2004 69 (25), 8810-8820
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A New Chiral Catalyst for the Enantioselective Strecker Synthesis of α-Amino Acids
Jinkun Huang and E. J. Corey
Organic Letters 2004 6 (26), 5027-5029
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A Synthesis Strategy Yielding Skeletally Diverse Small Molecules Combinatorially
Martin D. Burke, Eric M. Berger, and Stuart L. Schreiber
Journal of the American Chemical Society 2004 126 (43), 14095-14104
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Catalytic, Highly Enantio- and Diastereoselective Pinacol Coupling Reaction with a New Tethered Bis(8-quinolinolato) Ligand
Norito Takenaka, Guoyao Xia, and Hisashi Yamamoto
Journal of the American Chemical Society 2004 126 (41), 13198-13199
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Synthesis of (−)-Noviose from 2,3-O-Isopropylidene-d-erythronolactol
Xiao Ming Yu, Gang Shen, and Brian S. J. Blagg
The Journal of Organic Chemistry 2004 69 (21), 7375-7378
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Design, Synthesis, and Evaluation of Acyclic C-Nucleoside and N-Methylated Derivatives of the Ribitylaminopyrimidine Substrate of Lumazine Synthase as Potential Enzyme Inhibitors and Mechanistic Probes
Jinhua Chen, Thota Sambaiah, Boris Illarionov, Markus Fischer, Adelbert Bacher, and Mark Cushman
The Journal of Organic Chemistry 2004 69 (21), 6996-7003
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A Flexible Enantioselective Synthesis of the Isofurans
Douglass F. Taber, Yongchun Pan, and Xia Zhao
The Journal of Organic Chemistry 2004 69 (21), 7234-7240
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Structure−Reactivity Relationships in Oxidative Carbon−Carbon Bond Forming Reactions: A Mild and Efficient Approach to Stereoselective Syntheses of 2,6-Disubstituted Tetrahydropyrones
Lijun Wang, John R. Seiders, II, and Paul E. Floreancig
Journal of the American Chemical Society 2004 126 (39), 12596-12603
Abstract | Full Text HTML | PDF | PDF w/ Links
Access to Both Anomers of Pectenotoxin Spiroketals by Kinetic Spiroketalization
Petri M. Pihko and Jatta E. Aho
Organic Letters 2004 6 (21), 3849-3852
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Biomimetic Enantioselective Total Synthesis of (−)-Siccanin via the Pd-Catalyzed Asymmetric Allylic Alkylation (AAA) and Sequential Radical Cyclizations
Barry M. Trost, Hong C. Shen, and Jean-Philippe Surivet
Journal of the American Chemical Society 2004 126 (39), 12565-12579
Abstract | Full Text HTML | PDF | PDF w/ Links
Epoxide Hydrolase-Catalyzed Enantioselective Synthesis of Chiral 1,2-Diols via Desymmetrization of meso-Epoxides
Lishan Zhao, Bin Han, Zilin Huang, Mark Miller, Hongjun Huang, Dan S. Malashock, Zuolin Zhu, Aileen Milan, Dan E. Robertson, David P. Weiner, and Mark J. Burk
Journal of the American Chemical Society 2004 126 (36), 11156-11157
Abstract | Full Text HTML | PDF | PDF w/ Links
Efficient and Selective Synthesis of 6,7-Dehydrostipiamide via Zr-Catalyzed Asymmetric Carboalumination and Pd-Catalyzed Cross-Coupling of Organozincs
Xingzhong Zeng, Fanxing Zeng, and Ei-ichi Negishi
Organic Letters 2004 6 (19), 3245-3248
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Regioselective and Stereoselective Nucleophilic Ring Opening of Trifluoromethylated Cyclic Sulfates: Asymmetric Synthesis of Both Enantiomers of syn-(3-Trifluoromethyl)isoserine
Zhong-Xing Jiang and Feng-Ling Qing
The Journal of Organic Chemistry 2004 69 (16), 5486-5489
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Organic Catalysis with Modified Cinchona Alkaloids
Shi-Kai Tian, Yonggang Chen, Jianfeng Hang, Liang Tang, Paul McDaid, and Li Deng
Accounts of Chemical Research 2004 37 (8), 621-631
Abstract | Full Text HTML | PDF | PDF w/ Links
Studies toward Diazonamide A: Initial Synthetic Forays Directed toward the Originally Proposed Structure
K. C. Nicolaou, Scott A. Snyder, Xianhai Huang, Klaus B. Simonsen, Alexandros E. Koumbis, and Antony Bigot
Journal of the American Chemical Society 2004 126 (32), 10162-10173
Abstract | Full Text HTML | PDF | PDF w/ Links
Extending Pummerer Reaction Chemistry. Application to the Oxidative Cyclization of Tryptophan Derivatives
Ken S. Feldman and Andrew G. Karatjas
Organic Letters 2004 6 (17), 2849-2852
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Asymmetric Catalysis in Ionic Liquids: Easy Recycling of Catalyst and Improvement of Catalytic Performances
Choong Eui Song
2004, 145-160
Abstract | PDF | PDF w/ Links
Sodium Chlorite as an Efficient Oxidant and Hydroxy Ion Pump in Osmium-Catalyzed Asymmetric Dihydroxylation
Mikko H. Junttila and Osmo E. O. Hormi
The Journal of Organic Chemistry 2004 69 (14), 4816-4820
Abstract | Full Text HTML | PDF | PDF w/ Links
Convergent Highly Stereoselective Preparation of the C12−C24 Fragment of Macrolactin A
Carlo Bonini, Lucia Chiummiento, Maddalena Pullez, Guy Solladié, and Françoise Colobert
The Journal of Organic Chemistry 2004 69 (15), 5015-5022
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Mass Spectrometric Study of the Conversion of Rhenium Diolates to Metallaoxetanes and Carbenes. Coordination Number, Polar, and Steric Effects
Xiangyang Zhang, Xueyi Chen, and Peter Chen
Organometallics 2004 23 (14), 3437-3447
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Dihydroxylation of d-Glucose Derived α,β-Unsaturated Ester: Synthesis of Azepane and Nojirimycin Analogues
Dilip D. Dhavale, Shankar D. Markad, Narayan S. Karanjule, and J. PrakashaReddy
The Journal of Organic Chemistry 2004 69 (14), 4760-4766
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Anti-AIDS Agents. 60. Substituted 3‘R,4‘R-Di-O-(−)-camphanoyl-2‘,2‘-dimethyldihydropyrano[2,3-f]chromone (DCP) Analogues as Potent Anti-HIV Agents
Donglei Yu, Chin-Ho Chen, Arnold Brossi, and Kuo-Hsiung Lee
Journal of Medicinal Chemistry 2004 47 (16), 4072-4082
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An Ireland−Claisen Approach to Lignans: Synthesis of the Putative Structure of 5-epi-Eupomatilone-6
John M. Hutchison, Sang-phyo Hong, and Matthias C. McIntosh
The Journal of Organic Chemistry 2004 69 (12), 4185-4191
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Ionic Liquids as a Convenient New Medium for the Catalytic Asymmetric Dihydroxylation of Olefins Using a Recoverable and Reusable Osmium/Ligand
Luís C. Branco and Carlos A. M. Afonso
The Journal of Organic Chemistry 2004 69 (13), 4381-4389
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Stereoselective Synthesis of Polyhydroxyl Surfactants. Stereochemical Influence on Langmuir Monolayers
Kristina Neimert-Andersson, Eva Blomberg, and Peter Somfai
The Journal of Organic Chemistry 2004 69 (11), 3746-3752
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The First and Second Cinchona Rearrangement. Two Fundamental Transformations of Alkaloid Chemistry
M. Heiko Franz, Stefanie Röper, Rudolf Wartchow, and H. M. R. Hoffmann
The Journal of Organic Chemistry 2004 69 (9), 2983-2991
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Epoxide-Initiated Cationic Cyclization of Azides: A Novel Method for the Stereoselective Construction of 5-Hydroxymethyl Azabicyclic Compounds and Application in the Stereo- and Enantioselective Total Synthesis of (+)- and (−)-Indolizidine 167B and 209D
P. Ganapati Reddy and Sundarababu Baskaran
The Journal of Organic Chemistry 2004 69 (9), 3093-3101
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A New Stereoselective Synthesis of Ciguatoxin Right Wing Fragments
Masayuki Inoue, Shuji Yamashita, Atsushi Tatami, Keisuke Miyazaki, and Masahiro Hirama
The Journal of Organic Chemistry 2004 69 (8), 2797-2804
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Construction of a C(30−38) Dioxabicyclo[3.2.1]octane Subtarget for (+)-Sorangicin A, Exploiting a Regio- and Stereocontrolled Acid-Catalyzed Epoxide Ring Opening
Amos B. Smith, III and Richard J. Fox
Organic Letters 2004 6 (9), 1477-1480
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of a New Chiral Nonracemic C₂-Symmetric 2,2‘-Bipyridyl Ligand and Its Application in Copper(I)-Catalyzed Enantioselective Cyclopropanation Reactions
Michael P. A. Lyle and Peter D. Wilson
Organic Letters 2004 6 (5), 855-857
Abstract | Full Text HTML | PDF | PDF w/ Links
Enecarbamates as Selective Substrates in Oxidations: Chiral-Auxiliary-Controlled Mode Selectivity and Diastereoselectivity in the [2+2] Cycloaddition and Ene Reaction of Singlet Oxygen and in the Epoxidation by DMD and mCPBA
Waldemar Adam, Sara G. Bosio, Nicholas J. Turro, and Barbara T. Wolff
The Journal of Organic Chemistry 2004 69 (5), 1704-1715
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Total Synthesis and Structural Revision of (+)-Amphidinolide W
Arun K. Ghosh and Gangli Gong
Journal of the American Chemical Society 2004 126 (12), 3704-3705
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Reaction of α-Lithiated Dithioacetals Using Chiral Bis(oxazoline)s: New Chiral Formyl Anion Equivalents
Shuichi Nakamura, Yuji Ito, Libo Wang, and Takeshi Toru
The Journal of Organic Chemistry 2004 69 (5), 1581-1589
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A General and Nonempirical Approach to the Determination of the Absolute Configuration of 1-Aryl-1,2-diols
Stefano Superchi, Daniele Casarini, Carmela Summa, and Carlo Rosini
The Journal of Organic Chemistry 2004 69 (5), 1685-1694
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Highly Stereoselective Synthesis of Aristeromycin through Dihydroxylation of 4-Aryl-1-azido-2-cyclopentenes
Takauki Ainai, Yong-Gang Wang, Yuko Tokoro, and Yuichi Kobayashi
The Journal of Organic Chemistry 2004 69 (3), 655-659
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A Silicon Tether Approach for Addition of Functionalized Radicals to Chiral α-Hydroxyhydrazones: Diastereoselective Additions of Hydroxymethyl and Vinyl Synthons
Gregory K. Friestad and Sara E. Massari
The Journal of Organic Chemistry 2004 69 (3), 863-875
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Synthesis of the Putative Structure of Eupomatilone-6
Mukund K. Gurjar, Joseph Cherian, and C. V. Ramana
Organic Letters 2004 6 (3), 317-319
Abstract | Full Text HTML | PDF | PDF w/ Links
Fluorinated Carbonyl and Olefinic Compounds: Basic Character and Asymmetric Catalytic Reactions
Koichi Mikami, Yoshimitsu Itoh, and Masahiro Yamanaka
Chemical Reviews 2004 104 (1), 1-16
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Synthesis and Biological Activity of (3S,4R)- and (3S,4S)-3-Hydroxy-4-hydroxymethyl- 4-butanolides in Relation to PGE₂
Pedro O. Miranda, Francisco Estévez, José Quintana, Candelaria I. García, Ignacio Brouard, Juan I. Padrón, Juan P. Pivel, and Jaime Bermejo
Journal of Medicinal Chemistry 2004 47 (2), 292-295
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Total Synthesis of the Potent Antitumor Agent (−)-Mucocin Using a Temporary Silicon-Tethered Ring-Closing Metathesis Cross-Coupling Reaction
P. Andrew Evans, Jian Cui, Santosh J. Gharpure, Alexei Polosukhin, and Hai-Ren Zhang
Journal of the American Chemical Society 2003 125 (48), 14702-14703
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Total Synthesis of Apoptolidin: Construction of Enantiomerically Pure Fragments
K. C. Nicolaou, Konstantina C. Fylaktakidou, Holger Monenschein, Yiwei Li, Bernd Weyershausen, Helen J. Mitchell, Heng-xu Wei, Prasuna Guntupalli, David Hepworth, and Kazuyuki Sugita
Journal of the American Chemical Society 2003 125 (50), 15433-15442
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Total Synthesis of Apoptolidin: Completion of the Synthesis and Analogue Synthesis and Evaluation
K. C. Nicolaou, Yiwei Li, Kazuyuki Sugita, Holger Monenschein, Prasuna Guntupalli, Helen J. Mitchell, Konstantina C. Fylaktakidou, Dionisios Vourloumis, Paraskevi Giannakakou, and Aurora O'Brate
Journal of the American Chemical Society 2003 125 (50), 15443-15454
Abstract | Full Text HTML | PDF | PDF w/ Links
(S)-(+)-N-Acetylphenylglycineboronic Acid: A Chiral Derivatizing Agent for Ee Determination of 1,2-Diols
Emilia Caselli, Chiara Danieli, Stefania Morandi, Beatrice Bonfiglio, Arrigo Forni, and Fabio Prati
Organic Letters 2003 5 (25), 4863-4866
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Transient Absorption Studies of the Pacman Effect in Spring-Loaded Diiron(III) μ-Oxo Bisporphyrins
Justin M. Hodgkiss, Christopher J. Chang, Bradford J. Pistorio, and Daniel G. Nocera
Inorganic Chemistry 2003 42 (25), 8270-8277
Abstract | Full Text HTML | PDF | PDF w/ Links
Ferrocenoyl-Substituted Cinchona Alkaloids: Synthesis, Structure, and Application in Asymmetric Catalytic Oxidation
Kilian Muñiz and Martin Nieger
Organometallics 2003 22 (22), 4616-4619
Abstract | Full Text HTML | PDF | PDF w/ Links
Symmetry and Geometry Considerations of Atom Transfer: Deoxygenation of (silox)₃WNO and R₃PO (R = Me, Ph, ^tBu) by (silox)₃M (M = V, NbL (L = PMe₃, 4-Picoline), Ta; silox = ^tBu₃SiO)
Adam S. Veige, LeGrande M. Slaughter, Emil B. Lobkovsky, Peter T. Wolczanski, Nikita Matsunaga, Stephen A. Decker, and Thomas R. Cundari
Inorganic Chemistry 2003 42 (20), 6204-6224
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Asymmetric Synthesis of Cyclic Hydroxy Ketones Derived from Enol Ethers via Sharpless Asymmetric Dihydroxylation. A Study in the Correlation of the Enol Ether Chain Length and Enantioselectivity
Benjamin F. Marcune, Sandor Karady, Paul J. Reider, Ross A. Miller, Mirlinda Biba, Lisa DiMichele, and Robert A. Reamer
The Journal of Organic Chemistry 2003 68 (21), 8088-8091
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A Mechanistically Guided Design Leads to the Synthesis of an Efficient and Practical New Reagent for the Highly Enantioselective, Catalytic Dihydroxylation of Olefins
Jinkun Huang and E. J. Corey
Organic Letters 2003 5 (19), 3455-3458
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Synthesis of Both Enantiomers of anti-4,4,4-Trifluorothreonine and 2-Amino-4,4,4-trifluorobutanoic Acid
Zhong-Xing Jiang, Ying-Ying Qin, and Feng-Ling Qing
The Journal of Organic Chemistry 2003 68 (19), 7544-7547
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[3+2] versus [2+2] Addition of Metal Oxides Across CC Bonds. Reconciliation of Experiment and Theory
Dirk V. Deubel and Gernot Frenking
Accounts of Chemical Research 2003 36 (9), 645-651
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Synthesis of Nonadjacently Linked Tetrahydrofurans: An Iodoetherification and Olefin Metathesis Approach
Lei Zhu and David R. Mootoo
Organic Letters 2003 5 (19), 3475-3478
Abstract | Full Text HTML | PDF | PDF w/ Links
The Direct and Enantioselective Organocatalytic α-Oxidation of Aldehydes
Sean P. Brown, Michael P. Brochu, Christopher J. Sinz, and David W. C. MacMillan
Journal of the American Chemical Society 2003 125 (36), 10808-10809
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New Versatile Route to the Synthesis of Tetrahydro-β-carbolines and Tetrahydro-pyrano[3,4-b]indoles via an Intramolecular Michael Addition Catalyzed by InBr₃
Marianna Agnusdei, Marco Bandini, Alfonso Melloni, and Achille Umani-Ronchi
The Journal of Organic Chemistry 2003 68 (18), 7126-7129
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Asymmetric Alcoholysis of Cyclic Anhydrides
Yonggang Chen, Paul McDaid, and Li Deng
Chemical Reviews 2003 103 (8), 2965-2984
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Catalytic Enantioselective Strecker Reactions and Analogous Syntheses
Harald Gröger
Chemical Reviews 2003 103 (8), 2795-2828
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Process Research of (R)-Cyclohexyl Lactic Acid and Related Building Blocks: A Comparative Study
Thomas Storz and Peter Dittmar, Pierre François Fauquex and Philippe Marschal, Willy Urs Lottenbach and Heinz Steiner
Organic Process Research & Development 2003 7 (4), 559-570
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Asymmetric Schmidt Reaction of Hydroxyalkyl Azides with Ketones
Kiran Sahasrabudhe, Vijaya Gracias, Kelly Furness, Brenton T. Smith, Christopher E. Katz, D. Srinivasa Reddy, and Jeffrey Aubé
Journal of the American Chemical Society 2003 125 (26), 7914-7922
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Truly Catalytic and Enantioselective Pinacol Coupling of Aryl Aldehydes Mediated by Chiral Ti(III) Complexes^†
A. Chatterjee, T. H. Bennur, and N. N. Joshi
The Journal of Organic Chemistry 2003 68 (14), 5668-5671
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Total Synthesis of an Antitumor Antibiotic, Fostriecin (CI-920)
Kazuyuki Miyashita, Masahiro Ikejiri, Hitomi Kawasaki, Satoko Maemura, and Takeshi Imanishi
Journal of the American Chemical Society 2003 125 (27), 8238-8243
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Enantioselective Total Synthesis of Ustiloxin D
Hiroko Tanaka, Andrew M. Sawayama, and Thomas J. Wandless
Journal of the American Chemical Society 2003 125 (23), 6864-6865
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Preparation of Enantiopure 1-Azabicyclo[3.2.2]nonanes Functionalized at Carbon C3, from Cinchonine and Cinchonidine. Stereoselective Solvolysis and an Easily Enolizable Ketone
Stefanie Röper, M. Heiko Franz, Rudolf Wartchow, and H. Martin R. Hoffmann
The Journal of Organic Chemistry 2003 68 (12), 4944-4946
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Osmium Replica of Mesoporous Silicate MCM-48: Efficient and Reusable Catalyst for Oxidative Cleavage and Dihydroxylation Reactions
Kwangyeol Lee, Yong-Ho Kim, Soo Bong Han, Hongkyu Kang, Soyoung Park, Won Seok Seo, Joon T. Park, Bongsoo Kim, and Sukbok Chang
Journal of the American Chemical Society 2003 125 (23), 6844-6845
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Organosilanes in Synthesis: Application to an Enantioselective Synthesis of Methyl-l-callipeltose
Hongbing Huang and James S. Panek
Organic Letters 2003 5 (11), 1991-1993
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Straightforward Synthesis of Panaxytriol: An Active Component of Red Ginseng
Heedong Yun and Samuel J. Danishefsky
The Journal of Organic Chemistry 2003 68 (11), 4519-4522
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Total Synthesis of (+)-Asteltoxin
Khee Dong Eom, J. Venkat Raman, Heejin Kim, and Jin Kun Cha
Journal of the American Chemical Society 2003 125 (18), 5415-5421
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Platinum Group Metals in Catalysis: Fabrication of Catalysts and Catalyst Precursors
Peter B. Kettler
Organic Process Research & Development 2003 7 (3), 342-354
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Understanding the Unusual Regioselectivity in the Nucleophilic Ring-Opening Reactions of gem-Disubstituted Cyclic Sulfates. Experimental and Theoretical Studies
Alberto Avenoza, Jesús H. Busto, Francisco Corzana, José I. García, and Jesús M. Peregrina
The Journal of Organic Chemistry 2003 68 (11), 4506-4513
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Common-Intermediate Strategy for Synthesis of Conduritols and Inositols via β-Hydroxy Cyclohexenylsilanes
Jung-Nyoung Heo, Edward B. Holson, and William R. Roush
Organic Letters 2003 5 (10), 1697-1700
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Stereoselective Syntheses of 1,4-Dideoxy-1,4-imino-octitols and Novel Tetrahydroxyindolizidines
Ana T. Carmona, José Fuentes, and Inmaculada Robina, Eliazar Rodríguez García, Raynald Demange, and Pierre Vogel, Ana L. Winters
The Journal of Organic Chemistry 2003 68 (10), 3874-3883
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A New Synthesis and Stereocontrolled Functionalization of Substituted Silacyclopent-3-enes
Yannick Landais, Cédrick Mahieux, Kurt Schenk, and Sheetal S. Surange
The Journal of Organic Chemistry 2003 68 (7), 2779-2789
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Scope and Limitations of the Double [4+3]-Cycloadditions of 2-Oxyallyl Cations to 2,2‘-Methylenedifuran and Derivatives
Kai Torsten Meilert, Marc-Etienne Schwenter, Yuli Shatz, Srinivas Reddy Dubbaka, and Pierre Vogel
The Journal of Organic Chemistry 2003 68 (7), 2964-2967
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Enantioselective Mercuriocyclization of γ-Hydroxy-cis-alkenes
Sung Ho Kang and Mihyong Kim
Journal of the American Chemical Society 2003 125 (16), 4684-4685
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Synthesis of Polyhydroxycyclohexanes and Relatives from (−)-Quinic Acid
Concepción González, Montserrat Carballido, and Luis Castedo
The Journal of Organic Chemistry 2003 68 (6), 2248-2255
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A Trifunctional Catalyst for One-Pot Synthesis of Chiral Diols via Heck Coupling−N-Oxidation−Asymmetric Dihydroxylation: Application for the Synthesis of Diltiazem and Taxol Side Chain
Boyapati M. Choudary, Naidu S. Chowdari, Sateesh Madhi, and Mannepalli L. Kantam
The Journal of Organic Chemistry 2003 68 (5), 1736-1746
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Toward the Synthesis of Peloruside A: Fragment Synthesis and Coupling Studies
Ian Paterson, M. Emilia Di Francesco, and Toralf Kühn
Organic Letters 2003 5 (4), 599-602
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Copper Ion-Induced Activation and Asymmetric Benzoylation of 1,2-Diols: Kinetic Chiral Molecular Recognition
Yoshihiro Matsumura, Toshihide Maki, Sachie Murakami, and Osamu Onomura
Journal of the American Chemical Society 2003 125 (8), 2052-2053
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Desymmetrization of a Centrosymmetric Diepoxide: Efficient Synthesis of a Key Intermediate in a Total Synthesis of Hemibrevetoxin B
Joanne M. Holland, Mark Lewis, and Adam Nelson
The Journal of Organic Chemistry 2003 68 (3), 747-753
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Stereochemistry of the Allylation and Crotylation Reactions of α-Methyl-β-hydroxy Aldehydes with Allyl- and Crotyltrifluorosilanes. Synthesis of anti,anti-Dipropionate Stereotriads and Stereodivergent Pathways for the Reactions with 2,3-anti- and 2,3-syn-α-Methyl-β-hydroxy Aldehydes
Sherry R. Chemler and William R. Roush
The Journal of Organic Chemistry 2003 68 (4), 1319-1333
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Direct Catalytic Asymmetric Aldol Reaction of Hydroxyketones: Asymmetric Zn Catalysis with a Et₂Zn/Linked-BINOL Complex
Naoya Kumagai, Shigeki Matsunaga, Tomofumi Kinoshita, Shinji Harada, Shigemitsu Okada, Shigeru Sakamoto, Kentaro Yamaguchi, and Masakatsu Shibasaki
Journal of the American Chemical Society 2003 125 (8), 2169-2178
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Bis(o-nitrophenyl)ethanediol: A Practical Photolabile Protecting Group for Ketones and Aldehydes
Aurélien Blanc and Christian G. Bochet
The Journal of Organic Chemistry 2003 68 (3), 1138-1141
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Determination of the In-Solution Molecular Structure of Reactive Osmium Compounds Involved in the Synthesis of Vicinal Diols
S. Díaz-Moreno, and D. T. Bowron
Organometallics 2003 22 (3), 390-394
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Highly Regioselective Friedländer Annulations with Unmodified Ketones Employing Novel Amine Catalysts: Syntheses of 2-Substituted Quinolines, 1,8-Naphthyridines, and Related Heterocycles
Peter G. Dormer, Kan K. Eng, Roger N. Farr, Guy R. Humphrey, J. Christopher McWilliams, P. J. Reider, Jess W. Sager, and R. P. Volante
The Journal of Organic Chemistry 2003 68 (2), 467-477
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Microencapsulation of Osmium Tetroxide in Polyurea
Steven V. Ley, Chandrashekar Ramarao, Ai-Lan Lee, Niels Østergaard, Stephen C. Smith, and Ian M. Shirley
Organic Letters 2003 5 (2), 185-187
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First Asymmetric Synthesis of 6-Hydroxy-4-Sphingenine-Containing Ceramides. Use of Chiral Propargylic Alcohols To Prepare a Lipid Found in Human Skin
Jiong Chun, Hoe-Sup Byun, and Robert Bittman
The Journal of Organic Chemistry 2003 68 (2), 348-354
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Regio- and Stereoselectivity of Diethylaluminum Azide Opening of Trisubstituted Epoxides and Conversion of the 3° Azidohydrin Adducts to Isoprenoid Aziridines
Chad E. Davis, Jessica L. Bailey, Jonathan W. Lockner, and Robert M. Coates
The Journal of Organic Chemistry 2003 68 (1), 75-82
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Asymmetric Synthesis of anti- and syn-β-Amino Alcohols by Reductive Cross-Coupling of Transition Metal-Coordinated Planar Chiral Arylaldehydes with Aldimines
Yoshie Tanaka, Nobukazu Taniguchi, Takayuki Kimura, and Motokazu Uemura
The Journal of Organic Chemistry 2002 67 (26), 9227-9237
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Osmium Tetroxide Anchored to Porous Resins Bearing Residual Vinyl Groups: A Highly Active and Recyclable Solid for Asymmetric Dihydroxylation of Olefins
Jung Woon Yang, Hogyu Han, Eun Joo Roh, Sang-gi Lee, and Choong Eui Song
Organic Letters 2002 4 (26), 4685-4688
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Chemoenzymatic Dynamic Kinetic Resolution of β-Halo Alcohols. An Efficient Route to Chiral Epoxides
Oscar Pàmies and Jan-E. Bäckvall
The Journal of Organic Chemistry 2002 67 (25), 9006-9010
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Enantioselective Syntheses of Colletodiol, Colletol, and Grahamimycin A
Thomas J. Hunter and George A. O'Doherty
Organic Letters 2002 4 (25), 4447-4450
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Total Synthesis of Desferrisalmycin B
Li Dong, John M. Roosenberg II, and Marvin J. Miller
Journal of the American Chemical Society 2002 124 (50), 15001-15005
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Novel Nucleophilic Trifluoromethylation of Vicinal Diol Cyclic Sulfates
Naoto Takechi, Samia Ait-Mohand, Maurice Medebielle, and William R. Dolbier, Jr.
Organic Letters 2002 4 (26), 4671-4672
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Structural Accommodation of Osmium Tetroxide in Tertiary Butanol Solution
S. Díaz Moreno and D. T. Bowron
The Journal of Physical Chemistry B 2002 106 (45), 11876-11886
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Directed Dihydroxylation of Cyclic Allylic Alcohols and Trichloroacetamides Using OsO₄/TMEDA
Timothy J. Donohoe, Kevin Blades, Peter R. Moore, Michael J. Waring, Jon J. G. Winter, Madeleine Helliwell, Nicholas J. Newcombe, and Geoffrey Stemp
The Journal of Organic Chemistry 2002 67 (23), 7946-7956
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Sidewall Oxidation and Complexation of Carbon Nanotubes by Base-Catalyzed Cycloaddition of Transition Metal Oxide: A Theoretical Prediction
Xin Lu, Feng Tian, Yabing Feng, Xin Xu, Nanqin Wang, and Qianer Zhang
Nano Letters 2002 2 (11), 1325-1327
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A Unique and Highly Efficient Method for Catalytic Olefin Aziridination
Kiran Guthikonda and J. Du Bois
Journal of the American Chemical Society 2002 124 (46), 13672-13673
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Chlorotrimethylsilane: A Suitable Reagent for the Synthesis of Chlorohydrin Esters
Jordi Eras, Jonh Jairo Méndez, Mercè Balcells, and Ramon Canela
The Journal of Organic Chemistry 2002 67 (24), 8631-8634
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Synthesis of Sialic Acids via Desymmetrization by Ring-Closing Metathesis
Eric A. Voight, Christian Rein, and Steven D. Burke
The Journal of Organic Chemistry 2002 67 (24), 8489-8499
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The Practical Synthesis of a Novel and Highly Potent Analogue of Bryostatin
Paul A. Wender, Jeremy L. Baryza, Chad E. Bennett, F. Christopher Bi, Stacey E. Brenner, Michael O. Clarke, Joshua C. Horan, Cindy Kan, Emmanuel Lacôte, Blaise Lippa, Peter G. Nell, and Tim M. Turner
Journal of the American Chemical Society 2002 124 (46), 13648-13649
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Synthesis of 2,6-Dideoxysugars via Ring-Closing Olefinic Metathesis
Peter R. Andreana, Jason S. McLellan, Yongchen Chen, and Peng George Wang
Organic Letters 2002 4 (22), 3875-3878
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Soluble Polymers as Scaffolds for Recoverable Catalysts and Reagents
Tobin J. Dickerson, Neal N. Reed, and Kim D. Janda
Chemical Reviews 2002 102 (10), 3325-3344
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Toward a Computational Tool Predicting the Stereochemical Outcome of Asymmetric Reactions. 1. Application to Sharpless Asymmetric Dihydroxylation
Nicolas Moitessier, Christophe Henry, Christophe Len, and Yves Chapleur
The Journal of Organic Chemistry 2002 67 (21), 7275-7282
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Supported Chiral Catalysts on Inorganic Materials
Choong Eui Song and Sang-gi Lee
Chemical Reviews 2002 102 (10), 3495-3524
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Ring-Closing Metathesis of Chiral Allylamines. Enantioselective Synthesis of (2S,3R,4S)-3,4-Dihydroxyproline
Rubén Martín, Montserrat Alcón, Miquel A. Pericàs, and Antoni Riera
The Journal of Organic Chemistry 2002 67 (20), 6896-6901
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Ruthenium-Catalyzed Alkene-Alkyne Coupling: Synthesis of the Proposed Structure of Amphidinolide A
Barry M. Trost, John D. Chisholm, Stephen T. Wrobleski, and Michael Jung
Journal of the American Chemical Society 2002 124 (42), 12420-12421
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Asymmetric Total Syntheses of (+)-Cheimonophyllon E and (+)-Cheimonophyllal
Ken-ichi Takao, Tomohiro Tsujita, Manabu Hara, and Kin-ichi Tadano
The Journal of Organic Chemistry 2002 67 (19), 6690-6698
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Process Development of a Dual MMP/TNF Inhibitor (SDZ 242-484)
Guido Koch, Georg Kottirsch, Bernhard Wietfeld, and Ernst Küsters
Organic Process Research & Development 2002 6 (5), 652-659
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Development of a Practical, Safe, and High-Yielding Process for the Preparation of Enantiomerically Pure trans-Cyclopropane Carboxylic Acid
Ambarish K. Singh, Meena N. Rao, James H. Simpson, Wen-Sen Li, John E. Thornton, Daniel E. Kuehner, and David J. Kacsur
Organic Process Research & Development 2002 6 (5), 618-620
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Kinetic Resolution of Atropisomeric Amides
Ramon Rios, Ciril Jimeno, Patrick J. Carroll, and Patrick J. Walsh
Journal of the American Chemical Society 2002 124 (35), 10272-10273
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Stereoselective Organic Reactions in Water
Ulf M. Lindström
Chemical Reviews 2002 102 (8), 2751-2772
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Progress toward a Peptidomimetic of Laminin-Derived Pentapeptide YIGSR: Synthesis of the Unique Tricyclic Core Structure
Félix Busqué, Stephanie A. Hopkins, and Joseph P. Konopelski
The Journal of Organic Chemistry 2002 67 (17), 6097-6103
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The First Total Synthesis of (±)-Ingenol
Jeffrey D. Winkler, Meagan B. Rouse, Michael F. Greaney, Sean J. Harrison, and Yoon T. Jeon
Journal of the American Chemical Society 2002 124 (33), 9726-9728
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Total Synthesis and Absolute Stereochemistry of Plakortone D
Patricia Y. Hayes and William Kitching
Journal of the American Chemical Society 2002 124 (33), 9718-9719
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Reactions of Dithiolate Ligands in Mononuclear Complexes of Rhenium(V)
J. A. Kanney, B. C. Noll, and M. Rakowski DuBois
Journal of the American Chemical Society 2002 124 (33), 9878-9886
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On the Verge of Axial Chirality: Atroposelective Synthesis of the AB-Biaryl Fragment of Vancomycin^,
Gerhard Bringmann, Dirk Menche, Jörg Mühlbacher, Matthias Reichert, Nozomi Saito, Steven S. Pfeiffer, and Bruce H. Lipshutz
Organic Letters 2002 4 (17), 2833-2836
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Oxiranyl Anion-Mediated Synthesis of Highly Enantiomerically Enriched Styrene Oxide Derivatives
Vito Capriati, Saverio Florio, Renzo Luisi, and Antonio Salomone
Organic Letters 2002 4 (14), 2445-2448
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Highly Enantioselective Copper−Bisoxazoline-Catalyzed Allylic Oxidation of Cyclic Olefins with tert-Butyl p-nitroperbenzoate
Merritt B. Andrus and Ziniu Zhou
Journal of the American Chemical Society 2002 124 (30), 8806-8807
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Synthesis of 4-Diphosphocytidyl-2-C-methyl-d-erythritol and 2-C-Methyl-d-erythritol-4-phosphate
Andrew T. Koppisch and C. Dale Poulter
The Journal of Organic Chemistry 2002 67 (15), 5416-5418
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Synthesis of [5‘-¹³C]Ribonucleosides and 2‘-Deoxy[5‘-¹³C]ribonucleosides
Etsuko Kawashima, Kaoru Umabe, and Takeshi Sekine
The Journal of Organic Chemistry 2002 67 (15), 5142-5151
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A New Approach to (−)-Swainsonine by Ruthenium-Catalyzed Ring Rearrangement
Nicole Buschmann, Anke Rückert, and Siegfried Blechert
The Journal of Organic Chemistry 2002 67 (12), 4325-4329
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Formation of Vinyl Halides via a Ruthenium-Catalyzed Three-Component Coupling
Barry M. Trost and Anthony B. Pinkerton
Journal of the American Chemical Society 2002 124 (25), 7376-7389
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OsO₄ in Ionic Liquid [Bmim]PF₆: A Recyclable and Reusable Catalyst System for Olefin Dihydroxylation. Remarkable Effect of DMAP
Qingwei Yao
Organic Letters 2002 4 (13), 2197-2199
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Magnitudes and Chemical Consequences of R₃N⁺−C−H···OC Hydrogen Bonding
Carina E. Cannizzaro and K. N. Houk
Journal of the American Chemical Society 2002 124 (24), 7163-7169
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Synthesis of the ABC Ring System of Azaspiracid. 2. A Systematic Study into the Effect of C₁₆ and C₁₇ Substitution on Bis-spirocyclization
Rich G. Carter, David E. Graves, Melissa A. Gronemeyer, and Gregory S. Tschumper
Organic Letters 2002 4 (13), 2181-2184
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Practical Asymmetric Synthesis of the Herbicide (S)-Indanofan via Lipase-Catalyzed Kinetic Resolution of a Diol and Stereoselective Acid-Catalyzed Hydrolysis of a Chiral Epoxide
Ken Tanaka, Kenji Yoshida, Chiduko Sasaki, and Yasuko T. Osano
The Journal of Organic Chemistry 2002 67 (9), 3131-3133
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A General Asymmetric Synthesis of syn- and anti-β-Substituted Cysteine and Serine Derivatives
Chiyi Xiong, Wei Wang, and Victor J. Hruby
The Journal of Organic Chemistry 2002 67 (10), 3514-3517
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Catalytic Asymmetric Dihydroxylation of Olefins with Reusable OsO₄²^- on Ion-Exchangers: The Scope and Reactivity Using Various Cooxidants
Boyapati M. Choudary, Naidu S. Chowdari, Karangula Jyothi, and Mannepalli L. Kantam
Journal of the American Chemical Society 2002 124 (19), 5341-5349
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The Nobel Prize in Chemistry for 2001
Addison Ault
Journal of Chemical Education 2002 79 (5), 572
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Catalytic Regioselective Sulfonylation of α-Chelatable Alcohols: Scope and Mechanistic Insight
Michael J. Martinelli, Rajappa Vaidyanathan, Joseph M. Pawlak, Naresh K. Nayyar, Ulhas P. Dhokte, Christopher W. Doecke, Lisa M. H. Zollars, Eric D. Moher, Vien Van Khau, and Berta Košmrlj
Journal of the American Chemical Society 2002 124 (14), 3578-3585
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Diastereo- and Enantioselective Direct Catalytic Aldol Reaction of 2-Hydroxyacetophenones with Aldehydes Promoted by a Heteropolymetallic Complex: Catalytic Asymmetric Synthesis of anti-1,2-Diols
Naoki Yoshikawa, Takeyuki Suzuki, and Masakatsu Shibasaki
The Journal of Organic Chemistry 2002 67 (8), 2556-2565
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Total Synthesis of Hectochlorin
Jeannie R. P. Cetusic, Frederick R. Green III, Paul R. Graupner, and M. Paige Oliver
Organic Letters 2002 4 (8), 1307-1310
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Kinetic Isotope Effects in Cycloreversion of Rhenium (V) Diolates
Kevin P. Gable and Fedor A. Zhuravlev
Journal of the American Chemical Society 2002 124 (15), 3970-3979
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Unusual Regioselection in the Mitsunobu Reactions of syn-2,3-Dihydroxy Esters: Synthesis of Statine and Its Diastereomer
Soo Y. Ko
The Journal of Organic Chemistry 2002 67 (8), 2689-2691
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Asymmetric Total Synthesis of (+)-Fostriecin
Y. Krishna Reddy and J. R. Falck
Organic Letters 2002 4 (6), 969-971
Abstract | Full Text HTML | PDF | PDF w/ Links
Iron(III)−Salen Complexes as Enzyme Models: Mechanistic Study of Oxo(salen)iron Complexes Oxygenation of Organic Sulfides
Veluchamy Kamaraj Sivasubramanian, Muniyandi Ganesan, Seenivasan Rajagopal, and Ramasamy Ramaraj
The Journal of Organic Chemistry 2002 67 (5), 1506-1514
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New Stereocontrolled Synthesis and Biological Evaluation of 5-(1‘-Hydroxyalkyl)-3-methylidenetetrahydro-2-furanones as Potential Cytotoxic Agents
Tomasz Janecki, Edyta Błaszczyk, Kazimierz Studzian, Marek Różalski, Urszula Krajewska, and Anna Janecka
Journal of Medicinal Chemistry 2002 45 (5), 1142-1145
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Asymmetric Synthesis of 1-Aryl-1,2-ethanediols from Arylacetylenes by Palladium-Catalyzed Asymmetric Hydrosilylation as a Key Step
Toyoshi Shimada, Kotaro Mukaide, Akihiro Shinohara, Jin Wook Han, and Tamio Hayashi
Journal of the American Chemical Society 2002 124 (8), 1584-1585
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Synthesis of an Optically Active, Bicyclic 2-Pyridone Dipeptide Mimetic
Peter S. Dragovich, Ru Zhou, and Thomas J. Prins
The Journal of Organic Chemistry 2002 67 (3), 741-746
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A Catalyst that Plays Multiple Roles: Asymmetric Synthesis of β-Substituted Aspartic Acid Derivatives through a Four-Stage, One-Pot Procedure
Travis Dudding, Ahmed M. Hafez, Andrew E. Taggi, Ty R. Wagerle, and Thomas Lectka
Organic Letters 2002 4 (3), 387-390
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Highly Selective Hydrolytic Kinetic Resolution of Terminal Epoxides Catalyzed by Chiral (salen)Co^III Complexes. Practical Synthesis of Enantioenriched Terminal Epoxides and 1,2-Diols
Scott E. Schaus, Bridget D. Brandes, Jay F. Larrow, Makoto Tokunaga, Karl B. Hansen, Alexandra E. Gould, Michael E. Furrow, and Eric N. Jacobsen
Journal of the American Chemical Society 2002 124 (7), 1307-1315
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A CD Exciton Chirality Method for Determination of the Absolute Configuration of threo-β-Aryl-β-hydroxy-α-amino Acid Derivatives
Lee-Chiang Lo, Chun-Tzu Yang, and Charng-Sheng Tsai
The Journal of Organic Chemistry 2002 67 (4), 1368-1371
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Combinatorial Synthesis of Natural Product-like Molecules Using a First-Generation Spiroketal Scaffold
Bheemashankar A. Kulkarni, Gregory P. Roth, Emil Lobkovsky, and John A. Porco, Jr.
Journal of Combinatorial Chemistry 2002 4 (1), 56-72
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Diastereoselective Synthesis of 2H,5H-Dihydrofurans by Cobalt-Mediated Cycloisomerization of Allyl Propargyl Ethers. Application to Poly-THF Molecules
Alain Ajamian and James L. Gleason
Organic Letters 2001 3 (26), 4161-4164
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gem-Diacetates as Carbonyl Surrogates for Asymmetric Synthesis. Total Syntheses of Sphingofungins E and F
Barry M. Trost and Chulbom Lee
Journal of the American Chemical Society 2001 123 (49), 12191-12201
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Dual Enantioselective Control in Asymmetric Synthesis
Yong Hae Kim
Accounts of Chemical Research 2001 34 (12), 955-962
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Sharpless Asymmetric Dihydroxylation of trans-Propenylphosphonate by Using a Modified AD-mix-α and the Synthesis of Fosfomycin
Yuichi Kobayashi, Anthony D. William, and Yuko Tokoro
The Journal of Organic Chemistry 2001 66 (23), 7903-7906
Abstract | Full Text HTML | PDF | PDF w/ Links
From 2,2‘-Methylenedifuran to All Stereomeric Pentadecane-1,3,5,7,9,11,13,15-octols
Marc-Etienne Schwenter and Pierre Vogel
The Journal of Organic Chemistry 2001 66 (23), 7869-7872
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Synthesis of N-Cbz-Protected 6-Amino-6-deoxymannose, -talose, and -gulose
Michael H. Haukaas and George A. O'Doherty
Organic Letters 2001 3 (24), 3899-3902
Abstract | Full Text HTML | PDF | PDF w/ Links
Osmium-Catalyzed Asymmetric Dihydroxylation of Olefins by H₂O₂; Dual Role of the Cinchona Alkaloid Ligand
Sandra Y. Jonsson, Hans Adolfsson, and Jan-E. Bäckvall
Organic Letters 2001 3 (22), 3463-3466
Abstract | Full Text HTML | PDF | PDF w/ Links
Metal−Ligand Bifunctional Catalysis: A Nonclassical Mechanism for Asymmetric Hydrogen Transfer between Alcohols and Carbonyl Compounds
Ryoji Noyori, Masashi Yamakawa, and Shohei Hashiguchi
The Journal of Organic Chemistry 2001 66 (24), 7931-7944
Abstract | Full Text HTML | PDF | PDF w/ Links
Preparation of 5-Substituted 1H-Tetrazoles from Nitriles in Water
Zachary P. Demko and K. Barry Sharpless
The Journal of Organic Chemistry 2001 66 (24), 7945-7950
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Highly Effective Transition Structure Designed Catalyst for the Enantio- and Position-Selective Dihydroxylation of Polyisoprenoids
E. J. Corey and Junhu Zhang
Organic Letters 2001 3 (20), 3211-3214
Abstract | Full Text HTML | PDF | PDF w/ Links
Orthogonally Protected, Enantiopure syn-2-Amino-1,3,4-butanetriol: A General Building Block for syn-Amino Alcohols
Soon Ji Kwon and Soo Y. Ko
The Journal of Organic Chemistry 2001 66 (20), 6833-6835
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Synthesis of Kaitocephalin, the First Naturally Occurring AMPA/KA Receptor Antagonist
Dawei Ma and Jiade Yang
Journal of the American Chemical Society 2001 123 (39), 9706-9707
Abstract | Full Text HTML | PDF | PDF w/ Links
A Novel Reactivity of SeO₂ with 1,3-Dienes: Formation of syn 1,2- and 1,4-Diols via a Facile C−Se Bond Oxidation
Truc M. Nguyen and Daesung Lee
Organic Letters 2001 3 (20), 3161-3163
Abstract | Full Text HTML | PDF | PDF w/ Links
Opening the [4 + 2 + 2] Cycloadducts of Bicyclo[2.2.1]hepta-2,5-dienes (Norbornadienes) to Cis-Fused Bicyclo[5.3.0]decanes¹
Yan Chen and John K. Snyder
The Journal of Organic Chemistry 2001 66 (21), 6943-6957
Abstract | Full Text HTML | PDF | PDF w/ Links
Catalytic Asymmetric Dihydroxylation of Olefins with New Catalysts: The First Example of Heterogenization of OsO₄²^- by Ion-Exchange Technique
Boyapati M. Choudary, Naidu S. Chowdari, Mannepalli L. Kantam, and Kondapuram V. Raghavan
Journal of the American Chemical Society 2001 123 (37), 9220-9221
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereoselective 1,2-Additions of α-Alkoxymethyllithiums to Aldehydes
Robert P. Smyj and J. Michael Chong
Organic Letters 2001 3 (18), 2903-2906
Abstract | Full Text HTML | PDF | PDF w/ Links
Catalytic Asymmetric Dihydroxylation Using Phenoxyethoxymethyl-polystyrene (PEM)-Based Novel Microencapsulated Osmium Tetroxide (PEM-MC OsO₄)
Shū Kobayashi, Tasuku Ishida, and Ryo Akiyama
Organic Letters 2001 3 (17), 2649-2652
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereoselective Synthesis of Styrene Oxides via a Mitsunobu Cyclodehydration
Steven A. Weissman, Kai Rossen, and Paul J. Reider
Organic Letters 2001 3 (16), 2513-2515
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Determination of Absolute Configuration of Acyclic 1,2-Diols with Mo₂(OAc)₄. 1. Snatzke's Method Revisited
Lorenzo Di Bari, Gennaro Pescitelli, Carmela Pratelli, Dario Pini, and Piero Salvadori*
The Journal of Organic Chemistry 2001 66 (14), 4819-4825
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Modeling Rieske Dioxygenases: The First Example of Iron-Catalyzed Asymmetric cis-Dihydroxylation of Olefins
Miquel Costas, Adrianne K. Tipton, Kui Chen, Du-Hwan Jo, and Lawrence Que, Jr.
Journal of the American Chemical Society 2001 123 (27), 6722-6723
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Dihydroxylation of Olefins Using Cinchona Alkaloids on Highly Ordered Inorganic Supports
Irina Motorina and Cathleen M. Crudden
Organic Letters 2001 3 (15), 2325-2328
Abstract | Full Text HTML | PDF | PDF w/ Links
Deoxygenations of (silox)₃WNO and R₃PO by (silox)₃M (M = V, Ta) and (silox)₃NbL (silox = ^tBu₃SiO): Consequences of Electronic Effects
Adam S. Veige, Lee M. Slaughter, Peter T. Wolczanski, Nikita Matsunaga, Stephen A. Decker, and Thomas R. Cundari
Journal of the American Chemical Society 2001 123 (26), 6419-6420
Abstract | Full Text HTML | PDF | PDF w/ Links
Kinetic Resolution of Acyclic Secondary Allylic Silyl Ethers Catalyzed by Chiral Ketones
Dan Yang, Guan-Sheng Jiao, Yiu-Chung Yip, Tsz-Hin Lai, and Man-Kin Wong
The Journal of Organic Chemistry 2001 66 (13), 4619-4624
Abstract | Full Text HTML | PDF | PDF w/ Links
A Convenient Route to Higher Sugars by Two-Carbon Chain Elongation Using Wittig/Dihydroxylation Reactions
Morten Jørgensen, Erik H. Iversen, and Robert Madsen
The Journal of Organic Chemistry 2001 66 (13), 4625-4629
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of (+)-1-Epiaustraline
Scott E. Denmark and Jeromy J. Cottell
The Journal of Organic Chemistry 2001 66 (12), 4276-4284
Abstract | Full Text HTML | PDF | PDF w/ Links
Dynamic Kinetic Resolution of β-Azido Alcohols. An Efficient Route to Chiral Aziridines and β-Amino Alcohols
Oscar Pàmies and Jan-E. Bäckvall
The Journal of Organic Chemistry 2001 66 (11), 4022-4025
Abstract | Full Text HTML | PDF | PDF w/ Links
Determination of Absolute Configuration Using Vibrational Circular Dichroism Spectroscopy: The Chiral Sulfoxide 1-(2-methylnaphthyl) Methyl Sulfoxide
P. J. Stephens, A. Aamouche, and F. J. Devlin, S. Superchi, M. I. Donnoli, and C. Rosini
The Journal of Organic Chemistry 2001 66 (11), 3671-3677
Abstract | Full Text HTML | PDF | PDF w/ Links
Unexpected Catalyzed CC Bond Cleavage by Molecular Oxygen Promoted by a Thiyl Radical
Xavier Baucherel, Jacques Uziel, and Sylvain Jugé
The Journal of Organic Chemistry 2001 66 (13), 4504-4510
Abstract | Full Text HTML | PDF | PDF w/ Links
A β-Lactam-Based Stereoselective Access to β,γ-Dihydroxy α-Amino Acid-Derived Peptides with Either α,β-Like or Unlike Configurations
Claudio Palomo, Mikel Oiarbide, Aitor Landa, Aitor Esnal, and Anthony Linden
The Journal of Organic Chemistry 2001 66 (12), 4180-4186
Abstract | Full Text HTML | PDF | PDF w/ Links
Teubrevin G and Teubrevin H: The First Total Syntheses of Rearranged neo-Clerodanes Including Solutions to the Problems of Chirality Merger and Furan Ring Assembly
Leo A. Paquette and Ivan Efremov
Journal of the American Chemical Society 2001 123 (19), 4492-4501
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Synthesis of the AB-Ring System of the Antitumor Antibiotic Tetrazomine
Peter Wipf and Corey R. Hopkins
The Journal of Organic Chemistry 2001 66 (9), 3133-3139
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Total Synthesis of Fostriecin (CI-920)
Dale L. Boger, Satoshi Ichikawa, and Wenge Zhong
Journal of the American Chemical Society 2001 123 (18), 4161-4167
Abstract | Full Text HTML | PDF | PDF w/ Links
Photochemical Reactivity of Group 9 Metal Pinacolate Complexes
Andrew W. Holland, David S. Glueck, and Robert G. Bergman
Organometallics 2001 20 (11), 2250-2261
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereochemical Aspects in the 4-Vinylcyclohexene Biotransformation with Rat Liver Microsomes and Purified P450s. Monoepoxides and Diols
Cinzia Chiappe, Antonietta De Rubertis, Massimiliano De Carlo, Giada Amato, and Pier Giovanni Gervasi
Chemical Research in Toxicology 2001 14 (5), 492-499
Abstract | Full Text HTML | PDF | PDF w/ Links
Direct Catalytic Enantio- and Diastereoselective Aldol Reaction Using a Zn−Zn-Linked-BINOL Complex: A Practical Synthesis of syn-1,2-Diols
Naoya Kumagai, Shigeki Matsunaga, Naoki Yoshikawa, Takashi Ohshima, and Masakatsu Shibasaki
Organic Letters 2001 3 (10), 1539-1542
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis and NMR-Driven Conformational Analysis of Taxol Analogues Conformationally Constrained on the C13 Side Chain
Luciano Barboni and Catia Lambertucci, Giovanni Appendino, David G. Vander Velde and Richard H. Himes, Ezio Bombardelli, Minmin Wang and James P. Snyder
Journal of Medicinal Chemistry 2001 44 (10), 1576-1587
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Aldol Reaction via a Dinuclear Zinc Catalyst: α-Hydroxyketones as Donors
Barry M. Trost, Hisanaka Ito, and Elliad R. Silcoff
Journal of the American Chemical Society 2001 123 (14), 3367-3368
Abstract | Full Text HTML | PDF | PDF w/ Links
Geminal Dicarboxylates as Carbonyl Surrogates for Asymmetric Synthesis. Part II. Scope and Applications
Barry M. Trost and Chul Bom Lee
Journal of the American Chemical Society 2001 123 (16), 3687-3696
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthetic Studies toward the C5−C20 Domain of the Azaspiracids
Amy B. Dounay and Craig J. Forsyth
Organic Letters 2001 3 (7), 975-978
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The First Total Synthesis of Concanamycin F (Concanolide A)
Kazunobu Toshima, Takaaki Jyojima, Naoki Miyamoto, Masataka Katohno, Masaya Nakata, and Shuichi Matsumura
The Journal of Organic Chemistry 2001 66 (5), 1708-1715
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Synthesis of Epigallocatechin-3-gallate (EGCG), the Active Polyphenol Component from Green Tea
Lianhai Li and Tak Hang Chan
Organic Letters 2001 3 (5), 739-741
Abstract | Full Text HTML | PDF | PDF w/ Links
Direct Catalytic Asymmetric Aldol Reaction: Synthesis of Either syn- or anti-α,β-Dihydroxy Ketones
Naoki Yoshikawa, Naoya Kumagai, Shigeki Matsunaga, Guido Moll, Takashi Ohshima, Takeyuki Suzuki, and Masakatsu Shibasaki
Journal of the American Chemical Society 2001 123 (10), 2466-2467
Abstract | Full Text HTML | PDF | PDF w/ Links
Furan Ring Oxidation Strategy for the Synthesis of Macrosphelides A and B
Yuichi Kobayashi, G. Biju Kumar, Tomoaki Kurachi, Hukum P. Acharya, Takashi Yamazaki, and Tomoya Kitazume
The Journal of Organic Chemistry 2001 66 (6), 2011-2018
Abstract | Full Text HTML | PDF | PDF w/ Links
Five-Membered Ring Analogues of Shikimic Acid
Ming An, Tab Toochinda, and Paul A. Bartlett
The Journal of Organic Chemistry 2001 66 (4), 1326-1333
Abstract | Full Text HTML | PDF | PDF w/ Links
β-Hydroxy-γ-lactones as Chiral Building Blocks for the Enantioselective Synthesis of Marine Natural Products
Celina García, Tomás Martín, and Víctor S. Martín
The Journal of Organic Chemistry 2001 66 (4), 1420-1428
Abstract | Full Text HTML | PDF | PDF w/ Links
Entropy-Controlled Selectivity in the Vinylation of a Cyclic Chiral Nitrone. An Efficient Route to Enantiopure Polyhydroxylated Pyrrolidines
Marco Lombardo, Serena Fabbroni, and Claudio Trombini
The Journal of Organic Chemistry 2001 66 (4), 1264-1268
Abstract | Full Text HTML | PDF | PDF w/ Links
Osmium-Catalyzed Asymmetric Dihydroxylation of Olefins by H₂O₂ Using a Biomimetic Flavin-Based Coupled Catalytic System
Sandra Y. Jonsson, Katarina Färnegårdh, and Jan-E. Bäckvall
Journal of the American Chemical Society 2001 123 (7), 1365-1371
Abstract | Full Text HTML | PDF | PDF w/ Links
Chemoselective Elaboration of O-Linked Glycopeptide Mimetics by Alkylation of 3-ThioGalNAc
Lisa A. Marcaurelle and Carolyn R. Bertozzi
Journal of the American Chemical Society 2001 123 (8), 1587-1595
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Synthesis of (−)-Heliannuol E
Kenji Sato, Tomoyuki Yoshimura, Mitsuru Shindo, and Kozo Shishido
The Journal of Organic Chemistry 2001 66 (1), 309-314
Abstract | Full Text HTML | PDF | PDF w/ Links
Microbiological Transformations. 47. A Step toward a Green Chemistry Preparation of Enantiopure (S)-2-, -3-, and -4-Pyridyloxirane via an Epoxide Hydrolase Catalyzed Kinetic Resolution
Yvonne Genzel, Alain Archelas, Q. B. Broxterman, Birgit Schulze, and Roland Furstoss
The Journal of Organic Chemistry 2001 66 (2), 538-543
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Formal Synthesis of (+)-3-Deoxy-d- glycero-d-galacto-2-nonulosonic Acid (KDN) via Desymmetrization by Ring-Closing Metathesis
Steven D. Burke and Eric A. Voight
Organic Letters 2001 3 (2), 237-240
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of the Left-Hand Portion of Geldanamycin Using an Anti Glycolate Aldol Reaction
Merritt B. Andrus, Erik L. Meredith, and B. B. V. Soma Sekhar
Organic Letters 2001 3 (2), 259-262
Abstract | Full Text HTML | PDF | PDF w/ Links
[2+3] Cycloaddition of Ethylene to Transition Metal Oxo Compounds. Analysis of Density Functional Results by Marcus Theory
Philip Gisdakis and Notker Rösch
Journal of the American Chemical Society 2001 123 (4), 697-701
Abstract | Full Text HTML | PDF | PDF w/ Links
P-Nitrosophosphate Compounds: New N−O Heterodienophiles and Nitroxyl Delivery Agents
Roy W. Ware, Jr. and S. Bruce King
The Journal of Organic Chemistry 2000 65 (25), 8725-8729
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of the C(29)−C(45) Bis-pyran Subunit (E−F) of Spongistatin 1 (Altohyrtin A)
Glenn C. Micalizio, Anatoly N. Pinchuk, and William R. Roush
The Journal of Organic Chemistry 2000 65 (25), 8730-8736
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Synthesis of the Papulacandin Ring System: Conversion of the Mannose Diastereoisomer into a Glucose Stereoisomer
Devan Balachari and George A. O'Doherty
Organic Letters 2000 2 (25), 4033-4036
Abstract | Full Text HTML | PDF | PDF w/ Links
Studies Directed toward the Total Synthesis of Azaspiracid: Stereoselective Construction of C₁−C₁₂, C₁₃−C₁₉, and C₂₁−C₂₅ Fragments
Rich G. Carter and David J. Weldon
Organic Letters 2000 2 (24), 3913-3916
Abstract | Full Text HTML | PDF | PDF w/ Links
Process Development of the Sharpless Catalytic Asymmetric Dihydroxylation Reaction To Prepare Methyl (2R,3S)-2,3-Dihydroxy-3-phenylpropionate
Xinbo Lu, Zhunle Xu, and Guojun Yang
Organic Process Research & Development 2000 4 (6), 575-576
Abstract | Full Text HTML | PDF | PDF w/ Links
Alkyne Oxidations by cis-Dioxoruthenium(VI) Complexes. A Formal [3 + 2] Cycloaddition Reaction of Alkynes with cis-[(Cn*)(CF₃CO₂)Ru^VIO₂]ClO₄ (Cn* = 1,4,7-Trimethyl-1,4,7-triazacyclononane)
Chi-Ming Che, Wing-Yiu Yu, Pui-Ming Chan, Wing-Chi Cheng, Shie-Ming Peng, Kai-Chung Lau, and Wai-Kee Li
Journal of the American Chemical Society 2000 122 (46), 11380-11392
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereoselective Preparation of Ceramide and Its Skeleton Backbone Modified Analogues via Cyclic Thionocarbonate Intermediates Derived by Catalytic Asymmetric Dihydroxylation of α,β-Unsaturated Ester Precursors
Linli He, Hoe-Sup Byun, and Robert Bittman
The Journal of Organic Chemistry 2000 65 (22), 7627-7633
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A Stereocontrolled, Efficient Synthetic Route to Bioactive Sphingolipids: Synthesis of Phytosphingosine and Phytoceramides from Unsaturated Ester Precursors via Cyclic Sulfate Intermediates
Linli He, Hoe-Sup Byun, and Robert Bittman
The Journal of Organic Chemistry 2000 65 (22), 7618-7626
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Stereoselective Synthesis of Optically Active α-Hydroxy Ketones and anti-1,2-Diols via Asymmetric Transfer Hydrogenation of Unsymmetrically Substituted 1,2-Diketones
Takashi Koike, Kunihiko Murata, and Takao Ikariya
Organic Letters 2000 2 (24), 3833-3836
Abstract | Full Text HTML | PDF | PDF w/ Links
Osmium-Catalyzed Dihydroxylation of Olefins Using Dioxygen or Air as the Terminal Oxidant
Christian Döbler, Gerald M. Mehltretter, Uta Sundermeier, and Matthias Beller
Journal of the American Chemical Society 2000 122 (42), 10289-10297
Abstract | Full Text HTML | PDF | PDF w/ Links
A Highly Enantioselective Catalytic Desymmetrization of Cyclic Anhydrides with Modified Cinchona Alkaloids
Yonggang Chen, Shi-Kai Tian, and Li Deng
Journal of the American Chemical Society 2000 122 (39), 9542-9543
Abstract | Full Text HTML | PDF | PDF w/ Links
Application of Complex Aldol Reactions to the Total Synthesis of Phorboxazole B
David A. Evans, Duke M. Fitch, Thomas E. Smith, and Victor J. Cee
Journal of the American Chemical Society 2000 122 (41), 10033-10046
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Synthesis of (+)-Zaragozic Acid C
Alan Armstrong, Paul A. Barsanti, Lyn H. Jones, and Ghafoor Ahmed
The Journal of Organic Chemistry 2000 65 (21), 7020-7032
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A Symmetry-Based Formal Synthesis of Zaragozic Acid A
Kevin D. Freeman-Cook and Randall L. Halcomb
The Journal of Organic Chemistry 2000 65 (19), 6153-6159
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Enantioselective Syntheses of Isoaltholactone, 3-epi-Altholactone, and 5-Hydroxygoniothalamin
Joel M. Harris and George A. O'Doherty
Organic Letters 2000 2 (19), 2983-2986
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Syntheses of (−)-8-epi-Swainsonine Triacetate and (+)-1,2-Di-epi-swainsonine. Carbonyl Addition Thwarted by an Unprecedented Aza-Pinacol Rearrangement
Hossein Razavi and Robin Polt
The Journal of Organic Chemistry 2000 65 (18), 5693-5706
Abstract | Full Text HTML | PDF | PDF w/ Links
Anti-Selective Glycolate Aldol Additions with an Oxapyrone Boron Enolate
Merritt B. Andrus, B. B. V. Soma Sekhar, Erik L. Meredith, and N. Kent Dalley
Organic Letters 2000 2 (19), 3035-3037
Abstract | Full Text HTML | PDF | PDF w/ Links
Evolution of a Gram-Scale Synthesis of (+)-Discodermolide
Amos B. Smith III, Thomas J. Beauchamp, Matthew J. LaMarche, Michael D. Kaufman, Yuping Qiu, Hirokazu Arimoto, David R. Jones, and Kaoru Kobayashi
Journal of the American Chemical Society 2000 122 (36), 8654-8664
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Synthesis of Asimicin and Bullatacin
Hovsep Avedissian, Santosh C. Sinha, Ahmad Yazbak, Anjana Sinha, Partha Neogi, Subhash C. Sinha, and Ehud Keinan
The Journal of Organic Chemistry 2000 65 (19), 6035-6051
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereochemical Course of the Biotransformation of Isoprene Monoepoxides and of the Corresponding Diols with Liver Microsomes from Control and Induced Rats
Cinzia Chiappe, Antonietta De Rubertis, Viola Tinagli, Giada Amato, and Pier Giovanni Gervasi
Chemical Research in Toxicology 2000 13 (9), 831-838
Abstract | Full Text HTML | PDF | PDF w/ Links
The Synthesis and Evaluation of a Solution Phase Indexed Combinatorial Library of Non-Natural Polyenes for Reversal of P-Glycoprotein Mediated Multidrug Resistance
Merritt B. Andrus,* Timothy M. Turner, Zuben E. Sauna, and Suresh V. Ambudkar
The Journal of Organic Chemistry 2000 65 (16), 4973-4983
Abstract | Full Text HTML | PDF | PDF w/ Links
Catalytic, Asymmetric Synthesis of β-Lactams
Andrew E. Taggi, Ahmed M. Hafez, Harald Wack, Brandon Young, William J. Drury, III, and Thomas Lectka
Journal of the American Chemical Society 2000 122 (32), 7831-7832
Abstract | Full Text HTML | PDF | PDF w/ Links
Application of the Silicon-Tether Strategy for Controlling the Regioselectivity and Diastereoselectivity of Intramolecular Nitrone Cycloadditions for Aminopolyol Synthesis
Teruhiko Ishikawa, Takayuki Kudo, Kazunori Shigemori, and Seiki Saito
Journal of the American Chemical Society 2000 122 (32), 7633-7637
Abstract | Full Text HTML | PDF | PDF w/ Links
Concentration Dependence of the Sharpless Asymmetric Amidohydroxylation of Isopropyl Cinnamate
Peter G. M. Wuts, Andrew M. Anderson, Michael P. Goble, Sarah E. Mancini, and Ronald J. VanderRoest
Organic Letters 2000 2 (17), 2667-2669
Abstract | Full Text HTML | PDF | PDF w/ Links
Antineoplastic Agents 440. Asymmetric Synthesis and Evaluation of the Combretastatin A-1 SAR Probes (1S,2S)- and (1R,2R)-1,2-Dihydroxy- 1-(2‘,3‘-dihydroxy-4‘-methoxyphenyl)-2-(3‘ ‘,4‘ ‘,5‘ ‘-trimethoxyphenyl)-ethane
George R. Pettit, John W. Lippert III, Delbert L. Herald, Ernest Hamel, and Robin K. Pettit
Journal of Natural Products 2000 63 (7), 969-974
Abstract | Full Text HTML | PDF | PDF w/ Links
Diastereoselective Alkylations of Oxazolidinone Glycolates: A Useful Extension of the Evans Asymmetric Alkylation
Michael T. Crimmins, Kyle A. Emmitte, and Jason D. Katz
Organic Letters 2000 2 (14), 2165-2167
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereoselective Synthesis of (1R,2S,3R)-Camphordiamine
Carl A. Busacca, Scot Campbell, Yong Dong, Danja Grossbach, Mike Ridges, Lana Smith, and Earl Spinelli
The Journal of Organic Chemistry 2000 65 (15), 4753-4755
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A Stereoselective Synthesis of the C-10 to C-18 (Right-Half) Fragment of Mycalamides Employing Lewis Acid Promoted Intermolecular Aldol Reaction
Masahiro Toyota, Masako Hirota, Hitomi Hirano, and Masataka Ihara
Organic Letters 2000 2 (14), 2031-2034
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Unusual Diastereoselectivity in Intramolecular Diels−Alder Reactions of Substituted 3,5-Hexadienyl Acrylates. Preference for a Boatlike Structure of the Six-Atom Tether Due to Ester Overlap
Michael E. Jung, Adrian Huang, and Ted W. Johnson
Organic Letters 2000 2 (13), 1835-1837
Abstract | Full Text HTML | PDF | PDF w/ Links
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis
Fabienne Fache, Emmanuelle Schulz, M. Lorraine Tommasino, and Marc Lemaire
Chemical Reviews 2000 100 (6), 2159-2232
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Different Enantioselective Interaction Pathways Induced by Derivatized Quinines
Gloria Uccello-Barretta, Federica Balzano, Cristiana Quintavalli, and Piero Salvadori
The Journal of Organic Chemistry 2000 65 (12), 3596-3602
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Synthesis of a C₂₉−C₅₁ Subunit of Spongistatin 1 (Altohyrtin A) Starting from (R)-3-Benzyloxy-2-methylpropan-1-ol
Sandrine Lemaire-Audoire and Pierre Vogel
The Journal of Organic Chemistry 2000 65 (11), 3346-3356
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of Enantiopure 3-Quinuclidinone Analogues with Three Stereogenic Centers: (1S,2R,4S)- and (1S,2S,4S)-2-(Hydroxymethyl)-1-azabicyclo[2.2.2]octan-5-one and Stereocontrol of Nucleophilic Addition to the Carbonyl Group
Jens Frackenpohl and H. M. R. Hoffmann
The Journal of Organic Chemistry 2000 65 (13), 3982-3996
Abstract | Full Text HTML | PDF | PDF w/ Links
Combinatorial de Novo Synthesis of Catalysts: How Much of a Hit-Structure Is Needed for Activity?
Albrecht Berkessel and Rainer Riedl
Journal of Combinatorial Chemistry 2000 2 (3), 215-219
Abstract | Full Text HTML | PDF | PDF w/ Links
Additions of Enantiopure α-Sulfinyl Carbanions to (S)-N-Sulfinimines: Asymmetric Synthesis of β-Amino Sulfoxides and β-Αmino Alcohols
José L. García Ruano, Ana Alcudia, Miriam del Prado, David Barros, M. Carmen Maestro, and Inmaculada Fernández
The Journal of Organic Chemistry 2000 65 (10), 2856-2862
Abstract | Full Text HTML | PDF | PDF w/ Links
A Rapid Synthesis of Hydroxymethylacylfulvene (HMAF) Using the Allenic Pauson−Khand Reaction. A Synthetic Approach to Either Enantiomer of This Illudane Structure
Kay M. Brummond, Jianliang Lu, and Jeffrey Petersen
Journal of the American Chemical Society 2000 122 (20), 4915-4920
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of Cryptophycin 52 Using the Sharpless Asymmetric Dihydroxylation: Diol to Epoxide Transformation Optimized for a Base-Sensitive Substrate
Jian Liang, Eric D. Moher, Richard E. Moore, and David W. Hoard
The Journal of Organic Chemistry 2000 65 (10), 3143-3147
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Enantioselective Synthesis of 2-Substituted Cyclobutanones
Sung Yun Cho and Jin Kun Cha
Organic Letters 2000 2 (9), 1337-1339
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Total Synthesis of (−)-Taxol
Hiroyuki Kusama, Ryoma Hara, Shigeru Kawahara, Toshiyuki Nishimori, Hajime Kashima, Nobuhito Nakamura, Koichiro Morihira, and Isao Kuwajima
Journal of the American Chemical Society 2000 122 (16), 3811-3820
Abstract | Full Text HTML | PDF | PDF w/ Links
Further Studies on the Synthesis of 24(S),25-Epoxycholesterol. A New, Efficient Preparation of Desmosterol
Thomas A. Spencer, Dansu Li, and Jonathon S. Russel, Nicholas C. O. Tomkinson and Timothy M. Willson
The Journal of Organic Chemistry 2000 65 (7), 1919-1923
Abstract | Full Text HTML | PDF | PDF w/ Links
Interactions between Divalent Metal Ions and an Octacoordinate Macrocyclic Ligand
Haiyang He, Arthur E. Martell, Ramunas J. Motekaitis, and Joseph H. Reibenspies
Inorganic Chemistry 2000 39 (7), 1586-1592
Abstract | Full Text HTML | PDF | PDF w/ Links
Stereoselective Dihapto-Binding of Prochiral Aromatic Compounds by {TpRe(CO)(PMe₃)}: Synthesis, Characterization, Stability, and Enantiofacial Discrimination (Tp = Hydrido(tris)pyrazolylborate)
T. Brent Gunnoe, Michal Sabat, and W. Dean Harman
Organometallics 2000 19 (5), 728-740
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Sharpless Asymmetric Dihydroxylation of 5-Aryl-2-vinylfurans: Application to the Synthesis of the Spiroketal Moiety of Papulacandin D
Devan Balachari and George A. O'Doherty
Organic Letters 2000 2 (6), 863-866
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Catalytic Enantioselective meso-Epoxide Ring Opening Reaction with Phenolic Oxygen Nucleophile Promoted by Gallium Heterobimetallic Multifunctional Complexes
Shigeki Matsunaga, Jagattaran Das, Jochen Roels, Erasmus M. Vogl, Noriyoshi Yamamoto, Takehiko Iida, Kentaro Yamaguchi, and Masakatsu Shibasaki
Journal of the American Chemical Society 2000 122 (10), 2252-2260
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The Metal−Ligand Bifunctional Catalysis: A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds
Masashi Yamakawa, Hisashi Ito, and Ryoji Noyori
Journal of the American Chemical Society 2000 122 (7), 1466-1478
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Synthesis of 2-C-Methyl-d-erythritol 4-Phosphate: The First Pathway-Specific Intermediate in the Methylerythritol Phosphate Route to Isoprenoids
Andrew T. Koppisch, Brian S. J. Blagg, and C. Dale Poulter
Organic Letters 2000 2 (2), 215-217
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A Strategy for the Asymmetric Aminohomologation of α,β-Dihydroxy Aldehydes: Application to the Synthesis of the Southwest Tripeptide Segment of Echinocandin B
Claudio Palomo, Mikel Oiarbide, and Aitor Landa
The Journal of Organic Chemistry 2000 65 (1), 41-46
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Asymmetric Synthesis of 4-Deoxyverrucarol via Two Types of Ring Expansion Reactions
Junji Miyata, Hideo Nemoto, and Masataka Ihara
The Journal of Organic Chemistry 2000 65 (2), 504-512
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Determination of the Absolute Configuration of 1-Arylethane-1,2-diols by a Nonempirical Analysis of the CD Spectra of Their 4-Biphenylboronates
Stefano Superchi, Maria Irene Donnoli, and Carlo Rosini
Organic Letters 1999 1 (13), 2093-2096
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An Asymmetric Dihydroxylation Route to (3R,5E)-2,6-Dimethyl-2,3-epoxyocta-5,7-diene: The Major Volatile Component from Male Fruit-Spotting Bugs
Christopher J. Moore, Sven Possner, Patricia Hayes, Gregory C. Paddon-Jones, and William Kitching
The Journal of Organic Chemistry 1999 64 (26), 9742-9744
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Catalytic Asymmetric Dihydroxylation of Olefins Using a Recoverable and Reusable Polymer-Supported Osmium Catalyst
Shū Kobayashi, Masahiro Endo, and Satoshi Nagayama
Journal of the American Chemical Society 1999 121 (48), 11229-11230
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Desymmetrization of Cyclohexadienylsilanes. Regio-, Diastereo-, and Enantioselective Access to Sugar Mimics
Rémy Angelaud, Odile Babot, Trevor Charvat, and Yannick Landais
The Journal of Organic Chemistry 1999 64 (26), 9613-9624
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Synthesis of Unsymmetrical Diolate, Oxametallacyclopentene, Amido-Alkoxide and Thiolato-Alkoxide Complexes Using Dialkyl and Diaryl Titanium Aminotroponiminate Complexes: A Route to Unsymmetrical Vicinal Diols
Dietrich P. Steinhuebel and Stephen J. Lippard
Journal of the American Chemical Society 1999 121 (50), 11762-11772
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Assembly and Binding Properties of Osmate Ester-Bridged Binuclear Macrocycles
Kyu-Sung Jeong, Young Lag Cho, Sung-Youn Chang, Tae-Yoon Park, and Jung Uk Song
The Journal of Organic Chemistry 1999 64 (26), 9459-9466
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A New Coupled Catalytic System for Dihydroxylation of Olefins by H₂O₂
Katarina Bergstad, Sandra Y. Jonsson, and Jan-E. Bäckvall
Journal of the American Chemical Society 1999 121 (44), 10424-10425
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A New Synthesis of All Four Stereoisomers of 2-(2,3-Dihydroxypropyl)piperidine via Iterative Asymmetric Dihydroxylation To Cause Enantiomeric Enhancement. Application to Asymmetric Synthesis of Naturally Occurring Piperidine-Related Alkaloids
Hiroki Takahata, Minoru Kubota, and Nobuo Ikota
The Journal of Organic Chemistry 1999 64 (23), 8594-8601
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Expanding Synthetic Utilities of Asymmetric Dihydroxylation Reaction: Conversion of syn-Diols to syn-Amino Alcohols
Gae Y. Cho and Soo Y. Ko
The Journal of Organic Chemistry 1999 64 (23), 8745-8747
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Total Synthesis of Clavepictines A and B. Diastereoselective Cyclization of δ-Aminoallenes
Jae Du Ha and Jin Kun Cha
Journal of the American Chemical Society 1999 121 (43), 10012-10020
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A Novel and Efficient Synthesis of a Highly Active Analogue of clasto-Lactacystin β-Lactone
François Soucy, Louis Grenier, Mark L. Behnke, Antonia T. Destree, Teresa A. McCormack, Julian Adams, and Louis Plamondon
Journal of the American Chemical Society 1999 121 (43), 9967-9976
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Rationalizing the Stereoselectivity of Osmium Tetroxide Asymmetric Dihydroxylations with Transition State Modeling Using Quantum Mechanics-Guided Molecular Mechanics
Per-Ola Norrby, Torben Rasmussen, Jan Haller, Thomas Strassner, and K. N. Houk
Journal of the American Chemical Society 1999 121 (43), 10186-10192
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Consecutive Double Nucleophilic Attacks on an Olefin Promoted by a Platinum(III) Dimeric Complex
Yong-Shou Lin, Shintaro Takeda, and Kazuko Matsumoto
Organometallics 1999 18 (24), 4897-4899
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Total Synthesis of (+)-Calyculin A and (−)-Calyculin B: Asymmetric Synthesis of the C(9−25) Spiroketal Dipropionate Subunit
Amos B. Smith, III, Gregory K. Friestad, Joseph Barbosa, Emmanuel Bertounesque, Kenneth G. Hull, Makoto Iwashima, Yuping Qiu, Brian A. Salvatore, P. Grant Spoors, and James J.-W. Duan
Journal of the American Chemical Society 1999 121 (45), 10468-10477
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Metal Complexes with Cis α Topology from Stereoselective Quadridentate Ligands with Amine, Pyridine, and Quinoline Donor Groups
Christina Ng, Michal Sabat, and Cassandra L. Fraser
Inorganic Chemistry 1999 38 (24), 5545-5556
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A Practical Stereoselective Synthesis of Chiral Hydrobenzoins via Asymmetric Transfer Hydrogenation of Benzils
Kunihiko Murata, Kazuya Okano, Miwa Miyagi, Hiroshi Iwane, Ryoji Noyori, and Takao Ikariya
Organic Letters 1999 1 (7), 1119-1121
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Novel Dialkyl Aluminum Bis(iminophosphorano) Methanide and Methanediide Complexes
Kasani Aparna, Robert McDonald, Michael Ferguson, and Ronald G. Cavell
Organometallics 1999 18 (21), 4241-4243
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Total Synthesis of C-Glycosylangucycline, Urdamycinone B, Using an Unprotected Sugar
Goh Matsuo, Yuko Miki, Masaya Nakata, Shuichi Matsumura, and Kazunobu Toshima
The Journal of Organic Chemistry 1999 64 (19), 7101-7106
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Total Synthesis of Squamotacin
Santosh C. Sinha, Subhash C. Sinha, and Ehud Keinan
The Journal of Organic Chemistry 1999 64 (19), 7067-7073
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Glycosidase Inhibitors: Synthesis of Enantiomerically Pure Aza-Sugars from Schiff Base Amino Esters via Tandem Reduction-Alkenylation and Osmylation
Robin Polt, Dalibor Sames, and Jason Chruma
The Journal of Organic Chemistry 1999 64 (17), 6147-6158
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Dibutyltin Oxide Catalyzed Selective Sulfonylation of α-Chelatable Primary Alcohols
Michael J. Martinelli, Naresh K. Nayyar, Eric D. Moher, Ulhas P. Dhokte, Joseph M. Pawlak, and Rajappa Vaidyanathan
Organic Letters 1999 1 (3), 447-450
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Kinetic Resolution of Racemic Cyclic Olefins via Chiral Dioxirane
Michael Frohn, Xiaoming Zhou, Jian-Rong Zhang, Yong Tang, and Yian Shi
Journal of the American Chemical Society 1999 121 (33), 7718-7719
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Regioselective and Stereospecific Azidation of 1,2- and 1,3-Diols by Azidotrimethylsilane via a Mitsunobu Reaction
Linli He, Meni Wanunu, Hoe-Sup Byun, and Robert Bittman
The Journal of Organic Chemistry 1999 64 (16), 6049-6055
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Total Synthesis of Bryostatin 2
David A. Evans, Percy H. Carter, Erick M. Carreira, André B. Charette, Joëlle A. Prunet, and Mark Lautens
Journal of the American Chemical Society 1999 121 (33), 7540-7552
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Transition Metal-Catalyzed Regioselective and Stereoselective Aminochlorination of Cinnamic Esters
Guigen Li, Han-Xun Wei, Sun Hee Kim, and Margret Neighbors
Organic Letters 1999 1 (3), 395-398
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Microbiological Transformations 43. Epoxide Hydrolases as Tools for the Synthesis of Enantiopure α-Methylstyrene Oxides: A New and Efficient Synthesis of (S)-Ibuprofen
M. Cleij, A. Archelas, and R. Furstoss
The Journal of Organic Chemistry 1999 64 (14), 5029-5035
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Enantioselective Ti(IV) Sulfoxidation Catalysts Bearing C₃-Symmetric Trialkanolamine Ligands: Solution Speciation by ¹H NMR and ESI-MS Analysis
Marcella Bonchio, Giulia Licini, Giorgio Modena, Olga Bortolini, Stefano Moro, and William A. Nugent
Journal of the American Chemical Society 1999 121 (26), 6258-6268
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Catalytic Asymmetric Dihydroxylation by Gold Colloids Functionalized with Self-Assembled Monolayers
Hui Li, Yan-Yeung Luk, and Milan Mrksich
Langmuir 1999 15 (15), 4957-4959
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Total Synthesis of 3-Deoxy-d-manno-2-octulosonic Acid (KDO) and 2-Deoxy-β-KDO
Steven D. Burke and Geoffrey M. Sametz
Organic Letters 1999 1 (1), 71-74
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N,O-Bis(trifluoroacetyl)hydroxylamine as a Useful Electrophilic Nitrogen Source: Catalytic Synthesis of N-(Trifluoroacetyl)sulfilimines
C. S. Tomooka, D. D. LeCloux, H. Sasaki, and E. M. Carreira
Organic Letters 1999 1 (1), 149-152
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Binding of Alkenes to ReS₄^-
Jonathan T. Goodman and Thomas B. Rauchfuss
Journal of the American Chemical Society 1999 121 (21), 5017-5022
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Induction of Cholesteric Mesophases by Simple Cyclic Derivatives of p,p‘-Disubstituted 1,2-Diphenylethane-1,2-diols: Importance of Shape and Polarizability Effects
Stefano Superchi, Maria Irene Donnoli, Gloria Proni, Gian Piero Spada, and Carlo Rosini
The Journal of Organic Chemistry 1999 64 (13), 4762-4767
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Asymmetric Formation of α-Amino Acid Esters through Dynamic Kinetic Resolution: A Cyclic Carbonate as an Optically Active CO₂ Synthon
Jon A. Tunge, Daniel A. Gately, and Jack R. Norton
Journal of the American Chemical Society 1999 121 (18), 4520-4521
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Synthesis of Novel (P,S) Ligands Based on Chiral Nonracemic Episulfides. Use in Asymmetric Hydrogenation
Elisabeth Hauptman, Paul J. Fagan, and William Marshall
Organometallics 1999 18 (11), 2061-2073
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Diastereocontrol of [4 + 3] Cyclic Oxyallyl Cycloadditions by Alkoxy Substituents
Sung Yun Cho, Jae Chol Lee, and Jin Kun Cha
The Journal of Organic Chemistry 1999 64 (10), 3394-3395
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Total Synthesis of (−)-Hennoxazole A
David R. Williams, Dawn A. Brooks, and Martin A. Berliner
Journal of the American Chemical Society 1999 121 (20), 4924-4925
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Sharpless Asymmetric Dihydroxylation: Effect of Alkene Structure on Rates and Selectivity
Alan C. Spivey , R. Hanson , N. Scorah and S. J. Thorpe
Journal of Chemical Education 1999 76 (5), 655
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Syntheses of d- and l-Mannose, Gulose, and Talose via Diastereoselective and Enantioselective Dihydroxylation Reactions
Joel M. Harris, Mark D. Keranen, and George A. O'Doherty
The Journal of Organic Chemistry 1999 64 (9), 2982-2983
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In Situ Generation of NMO in the Osmium-Catalyzed Dihydroxylation of Olefins. Stereoselective Oxidation of Olefins to Cis Diols by m-CPBA
Katarina Bergstad, Joeri J. N. Piet, and Jan-E. Bäckvall
The Journal of Organic Chemistry 1999 64 (7), 2545-2548
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Directed Dihydroxylation of Allylic Trichloroacetamides
Timothy J. Donohoe, Kevin Blades, Madeleine Helliwell, Peter R. Moore, and Jonathan J. G. Winter, Geoffrey Stemp
The Journal of Organic Chemistry 1999 64 (9), 2980-2981
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The Synthesis and Evaluation of a Solution-Phase Indexed Combinatorial Library of Non-natural Polyenes for Multidrug Resistance Reversal
Merritt B. Andrus, Timothy M. Turner, Davoud Asgari, and Wenke Li
The Journal of Organic Chemistry 1999 64 (9), 2978-2979
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Total Synthesis of Trilobin
Anjana Sinha, Santosh C. Sinha, Subhash C. Sinha, and Ehud Keinan
The Journal of Organic Chemistry 1999 64 (7), 2381-2386
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Enantioselective Synthesis of a Novel Trans Double Bond Ceramide Analogue via Catalytic Asymmetric Dihydroxylation of an Enyne. The Role of the Trans Double Bond of Ceramide in the Fusion of Semliki Forest Virus with Target Membranes
LinLi He, Hoe-Sup Byun, Jolanda Smit, Jan Wilschut, and Robert Bittman
Journal of the American Chemical Society 1999 121 (16), 3897-3903
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Total Syntheses of (+)-Castanospermine, (+)-6-Epicastanospermine, (+)-Australine, and (+)-3-Epiaustraline
Scott E. Denmark and Esther A. Martinborough
Journal of the American Chemical Society 1999 121 (13), 3046-3056
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Asymmetric Aminohydroxylation of Vinylfuran
Mark L. Bushey, Michael H. Haukaas, and George A. O'Doherty
The Journal of Organic Chemistry 1999 64 (9), 2984-2985
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Synthesis of the South Unit of Cephalostatin. 7. Total Syntheses of (+)-Cephalostatin 7, (+)-Cephalostatin 12, and (+)-Ritterazine K¹
Jae Uk Jeong, Chuangxing Guo, and P. L. Fuchs
Journal of the American Chemical Society 1999 121 (10), 2071-2084
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Theoretical Study on the Origin of Enantioselectivity in the Bis(dihydroquinidine)-3,6-pyridazine·Osmium Tetroxide-Catalyzed Dihydroxylation of Styrene
Gregori Ujaque, Feliu Maseras, and Agustí Lledós
Journal of the American Chemical Society 1999 121 (6), 1317-1323
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The First Chiral Zirconium(IV) Catalyst for Highly Stereoselective Sulfoxidation
Marcella Bonchio, Giulia Licini, Fulvio Di Furia, Silvia Mantovani, Giorgio Modena, and William A. Nugent
The Journal of Organic Chemistry 1999 64 (4), 1326-1330
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Total Synthesis of the Cytotoxic Threo, Trans, Erythro, Cis, Threo Annonaceous Acetogenin Trilobin
James A. Marshall and Hongjian Jiang
The Journal of Organic Chemistry 1999 64 (3), 971-975
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Zeolite β Induced Rearrangement of Allyl Benzyl Ethers. 6. Variation of the Aromatic Part and Synthesis of Dihydronaphthalene Derivatives
Johan Wennerberg, Fredrik Ek, Anna Hansson, and Torbjörn Frejd
The Journal of Organic Chemistry 1999 64 (1), 54-59
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The Nitro-Mannich Reaction and Its Application to the Stereoselective Synthesis of 1,2-Diamines
Harry Adams, James C. Anderson, Simon Peace, and Andrew M. K. Pennell
The Journal of Organic Chemistry 1998 63 (26), 9932-9934
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Efficient, Stereoselective Synthesis of 24(S),25-Epoxycholesterol
Nicholas C. O. Tomkinson and Timothy M. Willson, Jonathon S. Russel and Thomas A. Spencer
The Journal of Organic Chemistry 1998 63 (26), 9919-9923
Abstract | Full Text HTML | PDF | PDF w/ Links
“Nonbiomimetic” Oxidations of Dihydropyridines
Rodolfo Lavilla, Xavier Barón, Oscar Coll, Francisco Gullón, Carme Masdeu, and Joan Bosch
The Journal of Organic Chemistry 1998 63 (26), 10001-10005
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Catalytic Asymmetric Oxidation of Aryl Sulfides with a Ti/H₂O/(R,R)-Diphenylethane-1,2-diol Complex: a Versatile and Highly Enantioselective Oxidation Protocol
Maria Irene Donnoli, Stefano Superchi, and Carlo Rosini
The Journal of Organic Chemistry 1998 63 (25), 9392-9395
Abstract | Full Text HTML | PDF | PDF w/ Links
Mono(pentamethylcyclopentadienyl)titanium and -zirconium Complexes Supported by Chiral Diolate Ligands. X-ray Crystal Structures of [(η-C₅Me₅)TiCl(μ-η¹,η¹-2-CF₃-dpbd)]₂ and [HNEt₃][(η-C₅Me₅)₂Zr₂Cl₂(μ-Cl)(μ-η¹,η²-3,5-Me₂-dpbd)₂]
David L. Clark, Damon R. Click, Steven K. Grumbine, Brian L. Scott, and John G. Watkin
Inorganic Chemistry 1998 37 (24), 6237-6243
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Total Synthesis of Mucocin
Partha Neogi, Thomas Doundoulakis, Ahmad Yazbak, Santosh C. Sinha, Subhash C. Sinha, and Ehud Keinan
Journal of the American Chemical Society 1998 120 (44), 11279-11284
Abstract | Full Text HTML | PDF | PDF w/ Links
An Expeditious Synthesis of the C(38)−C(54) Halichondrin B Subunit
Steven D. Burke, Brian C. Austad, and Amy C. Hart
The Journal of Organic Chemistry 1998 63 (20), 6770-6771
Abstract | Full Text HTML | PDF | PDF w/ Links
Efficient Conditions for Conversion of 2-Substituted Furans into 4-Oxygenated 2-Enoic Acids and Its Application to Synthesis of (+)-Aspicilin, (+)-Patulolide A, and (−)-Pyrenophorin
Yuichi Kobayashi, Miwa Nakano, G. Biju Kumar, and Kiyonobu Kishihara
The Journal of Organic Chemistry 1998 63 (21), 7505-7515
Abstract | Full Text HTML | PDF | PDF w/ Links
Dihydroxylation of Polyenes Using Narasaka's Modification of the Upjohn Procedure
Andreas Gypser, Dominique Michel, David S. Nirschl, and K. Barry Sharpless
The Journal of Organic Chemistry 1998 63 (21), 7322-7327
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Total Synthesis of Clerocidin via a Novel, Enantioselective Homoallenylboration Methodology
Alan X. Xiang, Donald A. Watson, Taotao Ling, and Emmanuel A. Theodorakis
The Journal of Organic Chemistry 1998 63 (20), 6774-6775
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Microencapsulated Osmium Tetraoxide. A New Recoverable and Reusable Polymer-Supported Osmium Catalyst for Dihydroxylation of Olefins
Satoshi Nagayama, Masahiro Endo, and Shū Kobayashi
The Journal of Organic Chemistry 1998 63 (18), 6094-6095
Abstract | Full Text HTML | PDF | PDF w/ Links
Oxidation of Alkenes in Supercritical Carbon Dioxide Catalyzed by Molybdenum Hexacarbonyl
Geoffrey R. Haas and Joseph W. Kolis
Organometallics 1998 17 (20), 4454-4460
Abstract | Full Text HTML | PDF | PDF w/ Links
Ruthenium-Catalyzed Alder Ene Type Reactions. A Formal Synthesis of Alternaric Acid
Barry M. Trost, Gary D. Probst, and Andreas Schoop
Journal of the American Chemical Society 1998 120 (36), 9228-9236
Abstract | Full Text HTML | PDF | PDF w/ Links
Inhibition of HIV-1 Protease by a Subunit of Didemnaketal A
Xiaodong Fan, George R. Flentke, and Daniel H. Rich
Journal of the American Chemical Society 1998 120 (34), 8893-8894
Abstract | Full Text HTML | PDF | PDF w/ Links
Methyl- and (Trifluoromethyl)alkene Peptide Isosteres: Synthesis and Evaluation of Their Potential as β-Turn Promoters and Peptide Mimetics
Peter Wipf, Todd C. Henninger, and Steven J. Geib
The Journal of Organic Chemistry 1998 63 (18), 6088-6089
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Synthesis of Acyclic Precursors to (3S,4S)-4-Hydroxy-2,3,4,5-tetrahydropyridazine-3-carboxylic Acid and Incorporation into a Luzopeptin/Quinoxapeptin Dipeptide
Dale L. Boger and Gunter Schüle
The Journal of Organic Chemistry 1998 63 (18), 6421-6424
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Probing the Scope of the Asymmetric Dihydroxylation of Polymer-Bound Olefins. Monitoring by HRMAS NMR Allows for Reaction Control and On-Bead Measurement of Enantiomeric Excess
Rainer Riedl, Robert Tappe, and Albrecht Berkessel
Journal of the American Chemical Society 1998 120 (35), 8994-9000
Abstract | Full Text HTML | PDF | PDF w/ Links
Novel Oxidative Transformation of Indenoisoquinolines to Isoquinoline-3-spiro-3‘-phthalides in the Presence of Osmium Tetraoxide and 4-Methylmorpholine N-Oxide
Muthusamy Jayaraman, Phillip E. Fanwick, and Mark Cushman
The Journal of Organic Chemistry 1998 63 (17), 5736-5737
Abstract | Full Text HTML | PDF | PDF w/ Links
Chemoenzymatic Synthesis of d-N-Boc-3,5- dihydroxy-4-methoxyphenylglycine
Michèle Bois-Choussy and Jieping Zhu
The Journal of Organic Chemistry 1998 63 (16), 5662-5665
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Total Synthesis of Uvaricin
Ahmad Yazbak, Subhash C. Sinha, and Ehud Keinan
The Journal of Organic Chemistry 1998 63 (17), 5863-5868
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Neutral and Cationic Tetracoordinated Aluminum Complexes Featuring Tridentate Nitrogen Donors: Synthesis, Structure, and Catalytic Activity for the Ring-Opening Polymerization of Propylene Oxide and (d,l)-Lactide
Norbert Emig, Hanh Nguyen, Harald Krautscheid, Régis Réau, Jean-Bernard Cazaux, and Guy Bertrand
Organometallics 1998 17 (16), 3599-3608
Abstract | Full Text HTML | PDF | PDF w/ Links
A New Synthetic Route to Chiral Glycerolipid Precursors Using a Cyclic Sulfate Synthon: Preparation of 1-O-Hexadecyl-3-O-(4‘-methoxyphenyl)- sn-glycerol and Its 1-Thio and 1-Aza Analogues
Linli He, Hoe-Sup Byun, and Robert Bittman
The Journal of Organic Chemistry 1998 63 (16), 5696-5699
Abstract | Full Text HTML | PDF | PDF w/ Links
Novel Enantioselective Synthesis of α-Methylthreonines and α,β-Dimethylcysteines
Hui Shao, Jaimie K. Rueter, and Murray Goodman
The Journal of Organic Chemistry 1998 63 (15), 5240-5244
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Formation of Columnar and Cubic Mesophases by Calamitic Molecules: Novel Amphotropic Biphenyl Derivatives
Niels Lindner, Marius Kölbel, Christiane Sauer, Siegmar Diele, Jani Jokiranta, and Carsten Tschierske
The Journal of Physical Chemistry B 1998 102 (27), 5261-5273
Abstract | Full Text HTML | PDF | PDF w/ Links
Facile Synthesis of Terminal 1,2-Diols with High Optical Purity via Oxazaborolidine-Catalyzed Asymmetric Borane Reduction
Byung Tae Cho and Yu Sung Chun
The Journal of Organic Chemistry 1998 63 (15), 5280-5282
Abstract | Full Text HTML | PDF | PDF w/ Links
A New Strategy for the Synthesis of Sphingosine Analogues. Sphingofungin F
Barry M. Trost and Chul Bom Lee
Journal of the American Chemical Society 1998 120 (27), 6818-6819
Abstract | Full Text HTML | PDF | PDF w/ Links
LReO₃ Epoxidizes, cis-Dihydroxylates, and Cleaves Alkenes as Well as Alkenylates Aldehydes: Toward an Understanding of Why
M. A. Pietsch, T. V. Russo, R. B. Murphy, R. L. Martin, and A. K. Rappé
Organometallics 1998 17 (13), 2716-2719
Abstract | Full Text HTML | PDF | PDF w/ Links
Design and Synthesis of Chiral Ketones for Catalytic Asymmetric Epoxidation of Unfunctionalized Olefins
Dan Yang, Man-Kin Wong, Yiu-Chung Yip, Xue-Chao Wang, Man-Wai Tang, Jian-Hua Zheng, and Kung-Kai Cheung
Journal of the American Chemical Society 1998 120 (24), 5943-5952
Abstract | Full Text HTML | PDF | PDF w/ Links
Highly Regio- and Enantioselective Monoepoxidation of Conjugated Dienes
Michael Frohn, Molly Dalkiewicz, Yong Tu, Zhi-Xian Wang, and Yian Shi
The Journal of Organic Chemistry 1998 63 (9), 2948-2953
Abstract | Full Text HTML | PDF | PDF w/ Links
Rh−DuPHOS-Catalyzed Enantioselective Hydrogenation of Enol Esters. Application to the Synthesis of Highly Enantioenriched α-Hydroxy Esters and 1,2-Diols
Mark J. Burk, Christopher S. Kalberg, and Antonio Pizzano
Journal of the American Chemical Society 1998 120 (18), 4345-4353
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Synthesis of 3-Deoxy-(R)-sphingomyelin from (S)-1-(4‘-Methoxyphenyl)glycerol
Hoe-Sup Byun, Jason A. Sadlofsky, and Robert Bittman
The Journal of Organic Chemistry 1998 63 (8), 2560-2563
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Synthesis of Goniocin and Cyclogoniodenin T. Unique Biosynthetic Implications
Santosh C. Sinha, Anjana Sinha, Subhash C. Sinha, and Ehud Keinan
Journal of the American Chemical Society 1998 120 (16), 4017-4018
Abstract | Full Text HTML | PDF | PDF w/ Links
Aldolase Antibodies of Remarkable Scope
Torsten Hoffmann, Guofu Zhong, Benjamin List, Doron Shabat, James Anderson, Svetlana Gramatikova, Richard A. Lerner, and Carlos F. Barbas III
Journal of the American Chemical Society 1998 120 (12), 2768-2779
Abstract | Full Text HTML | PDF | PDF w/ Links
Palladium-Catalyzed 1,4-Acetoxy-Trifluoroacetoxylation and 1,4-Alkoxy-Trifluoroacetoxylation of Cyclic 1,3-Dienes. Scope and Mechanism
Attila Aranyos, Kálmán J. Szabó, and Jan-E. Bäckvall
The Journal of Organic Chemistry 1998 63 (8), 2523-2529
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Symmetry-Assisted Synthesis of C₂-Symmetric trans-α,α‘-Bis(hydroxymethyl)pyrrolidine and -piperidine Derivatives via Double Sharpless Asymmetric Dihydroxylation of α,ω-Terminal Dienes
Hiroki Takahata, Seiki Takahashi, Shin-ichi Kouno, and Takefumi Momose
The Journal of Organic Chemistry 1998 63 (7), 2224-2231
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Mechanistic Course of the Asymmetric Methoxyselenenylation Reaction
Thomas Wirth, Gianfranco Fragale, and Martin Spichty
Journal of the American Chemical Society 1998 120 (14), 3376-3381
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Energetics of Metal−Ligand Multiple Bonds. A Combined Solution Thermochemical and ab Initio Quantum Chemical Study of MO Bonding in Group 6 Metallocene Oxo Complexes
Lubin Luo, Giuseppe Lanza, Ignazio L. Fragalà, Charlotte L. Stern, and Tobin J. Marks
Journal of the American Chemical Society 1998 120 (13), 3111-3122
Abstract | Full Text HTML | PDF | PDF w/ Links
Macrocycles Derived from Cinchona Alkaloids: A Thermodynamic vs Kinetic Study
Stuart J. Rowan and Jeremy K. M. Sanders
The Journal of Organic Chemistry 1998 63 (5), 1536-1546
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Diastereoselective Synthesis of γ-Hydroxy-β-amino Alcohols and (2S,3S)-β-Hydroxyleucine from Chiral d-(N,N-Dibenzylamino)serine (TBDMS) Aldehyde
Taoues Laïb, Jacqueline Chastanet, and Jieping Zhu
The Journal of Organic Chemistry 1998 63 (5), 1709-1713
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Enantiocontrolled Construction of Functionalized Tetrahydrofurans: Total Synthesis of (6S,7S,9R,10R)-6,9-Epoxynonadec-18-ene-7,10-diol, a Marine Natural Product
Zhi-Min Wang and Ming Shen
The Journal of Organic Chemistry 1998 63 (5), 1414-1418
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Constitution, Configuration, and the Optical Activity of Chiral Dendrimers
James R. McElhanon and Dominic V. McGrath
Journal of the American Chemical Society 1998 120 (8), 1647-1656
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Asymmetric Dihydroxylation−Haloetherification Strategy for the Synthesis of Tetrahydrofuran-Containing Acetogenins
Huiping Zhang, Mohindra Seepersaud, Sheila Seepersaud, and David R. Mootoo
The Journal of Organic Chemistry 1998 63 (6), 2049-2052
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The Mechanistic Basis for Electronic Effects on Enantioselectivity in the (salen)Mn(III)-Catalyzed Epoxidation Reaction
Michael Palucki, Nathaniel S. Finney, Paul J. Pospisil, Mehmet L. Güler, Toyohisa Ishida, and Eric N. Jacobsen
Journal of the American Chemical Society 1998 120 (5), 948-954
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From Styrenes to Enantiopure α-Arylglycines in Two Steps
K. Laxma Reddy and K. Barry Sharpless
Journal of the American Chemical Society 1998 120 (6), 1207-1217
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Application of Newly Developed Anti-Selective Aldol Methodology: Synthesis of C6−C13 and C19−C28 Fragments of Miyakolide
Takehiko Yoshimitsu, Jinhua J. Song, Guo-Qiang Wang and Satoru Masamune
The Journal of Organic Chemistry 1997 62 (26), 8978-8979
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trans-1,2-Diaminocyclohexane Derivatives as Chiral Reagents, Scaffolds, and Ligands for Catalysis: Applications in Asymmetric Synthesis and Molecular Recognition
Youssef L. Bennani and Stephen Hanessian
Chemical Reviews 1997 97 (8), 3161-3196
Abstract | Full Text HTML | PDF | PDF w/ Links
Tandem Oxidative Cyclization with Rhenium Oxide. Total Synthesis of 17,18-bisepi-Goniocin
Subhash C. Sinha, Anjana Sinha, Santosh C. Sinha, and Ehud Keinan
Journal of the American Chemical Society 1997 119 (49), 12014-12015
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Enzymatic Synthesis of β-Hydroxy-α-amino Acids Based on Recombinant d- and l-Threonine Aldolases
Teiji Kimura, Vassil P. Vassilev, Gwo-Jenn Shen, and Chi-Huey Wong
Journal of the American Chemical Society 1997 119 (49), 11734-11742
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Total Synthesis of Stipiamide and Designed Polyenes as New Agents for the Reversal of Multidrug Resistance
Merritt B. Andrus, Salvatore D. Lepore, and Timothy M. Turner
Journal of the American Chemical Society 1997 119 (50), 12159-12169
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A New and Versatile Allylic Alcohol Anion and Acyl β-Anion Equivalent for Three-Carbon Homologations
Romualdo Caputo, Annalisa Guaragna, Giovanni Palumbo, and Silvana Pedatella
The Journal of Organic Chemistry 1997 62 (26), 9369-9371
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Process Research and Development for the Production of Intermediates for the Synthesis of Carbocyclic Nucleosides
Robin Bannister, Chris Hanson, Neil Henderson, Ray McCague, and Graham Ruecroft
Organic Process Research & Development 1997 1 (6), 415-419
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Sharpless Asymmetric Dihydroxylation on an Industrial Scale
Leif Ahrgren and Lori Sutin
Organic Process Research & Development 1997 1 (6), 425-427
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Preparation and Use of Aziridino Alcohols as Promoters for the Enantioselective Addition of Dialkylzinc Reagents to N-(Diphenylphosphinoyl) Imines
Pher G. Andersson, David Guijarro, and David Tanner
The Journal of Organic Chemistry 1997 62 (21), 7364-7375
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Experimental and Theoretical Kinetic Isotope Effects for Asymmetric Dihydroxylation. Evidence Supporting a Rate-Limiting “(3 + 2)” Cycloaddition
Albert J. DelMonte, Jan Haller, K. N. Houk, K. Barry Sharpless, Daniel A. Singleton, Thomas Strassner, and Allen A. Thomas
Journal of the American Chemical Society 1997 119 (41), 9907-9908
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Applications of Zr-Catalyzed Carbomagnesation and Mo-Catalyzed Macrocyclic Ring Closing Metathesis in Asymmetric Synthesis. Enantioselective Total Synthesis of Sch 38516 (Fluvirucin B₁)
Zhongmin Xu, Charles W. Johannes, Ahmad F. Houri, Daniel S. La, Derek A. Cogan, Gloria E. Hofilena, and Amir H. Hoveyda
Journal of the American Chemical Society 1997 119 (43), 10302-10316
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Theoretical Characterization of an Intermediate for the [3 + 2] Cycloaddition Mechanism in the Bis(dihydroxy- quinidine)−3,6-Pyridazine·Osmium Tetroxide-Catalyzed Dihydroxylation of Styrene
Gregori Ujaque, Feliu Maseras, and Agustí Lledós
The Journal of Organic Chemistry 1997 62 (22), 7892-7894
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A Simple Enantioselective Synthesis of the Biologically Active Tetracyclic Marine Sesterterpene Scalarenedial
E. J. Corey, Guanglin Luo, and Linus Shouzhong Lin
Journal of the American Chemical Society 1997 119 (41), 9927-9928
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Nonracemic α-Fluoro Aldehydes: Asymmetric Synthesis of 4-Deoxy-4-fluoro-d-arabinopyranose
Franklin A. Davis, Parimala V. N. Kasu, Gajendran Sundarababu, and Hongyan Qi
The Journal of Organic Chemistry 1997 62 (22), 7546-7547
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Nitridomanganese(V) Complexes: Design, Preparation, and Use as Nitrogen Atom-Transfer Reagents
J. Du Bois, Craig S. Tomooka, Jason Hong, and Erick M. Carreira
Accounts of Chemical Research 1997 30 (9), 364-372
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Synthesis of 12 Stereochemically and Structurally Diverse C-Trisaccharides
Daniel P. Sutherlin and Robert W. Armstrong
The Journal of Organic Chemistry 1997 62 (16), 5267-5283
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Total Synthesis of the Annonaceous Acetogenin (+)-Asimicin. Development of a New Bidirectional Strategy
James A. Marshall and Kevin W. Hinkle
The Journal of Organic Chemistry 1997 62 (17), 5989-5995
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Syntheses of Epothilones A and B via a Macrolactonization-Based Strategy
K. C. Nicolaou, S. Ninkovic, F. Sarabia, D. Vourloumis, Y. He, H. Vallberg, M. R. V. Finlay, and Z. Yang
Journal of the American Chemical Society 1997 119 (34), 7974-7991
Abstract | Full Text HTML | PDF | PDF w/ Links
Models for Stereoselective Additions to Chiral Allylic Ethers: Osmium Tetroxide Bis-hydroxylations
Jan Haller, Thomas Strassner, and K. N. Houk
Journal of the American Chemical Society 1997 119 (34), 8031-8034
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In Defense of the Catalytic Asymmetric Cis Dihydroxylation of Olefins Utilizing Insoluble Polymeric Ligands
Piero Salvadori, Dario Pini, and Antonella Petri
Journal of the American Chemical Society 1997 119 (29), 6929-6930
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Total Synthesis of Clavepictines A and B. Cross-Coupling of an Acylenamino Triflate and Cyclization of a δ-Aminoallene
Jae Du Ha, Dongha Lee, and Jin Kun Cha
The Journal of Organic Chemistry 1997 62 (14), 4550-4551
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Evidence for a Ring-Opening Preequilibrium in the Exchange Reactions of Diosmacyclobutanes
Bruce R. Bender, David L. Ramage, Jack R. Norton, Dawn C. Wiser, and Anthony K. Rappé
Journal of the American Chemical Society 1997 119 (24), 5628-5637
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Kinetics of Diosmacyclobutane Exchange Reactions
David L. Ramage, Dawn C. Wiser, and Jack R. Norton
Journal of the American Chemical Society 1997 119 (24), 5618-5627
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Applications of Cyclic Sulfates of vic-Diols: Synthesis of Episulfides, Olefins, and Thio Sugars
Francisco G. Calvo-Flores, Pilar García-Mendoza, Fernando Hernández-Mateo, Joaquín Isac-García, and Francisco Santoyo-González
The Journal of Organic Chemistry 1997 62 (12), 3944-3961
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Preparation of Optically Active Tertiary Alcohols by Enzymatic Methods. Application to the Synthesis of Drugs and Natural Products
Same-Ting Chen and Jim-Min Fang
The Journal of Organic Chemistry 1997 62 (13), 4349-4357
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Proton-Decoupled Carbon-13 NMR Spectroscopy in a Lyotropic Chiral Nematic Solvent as an Analytical Tool for the Measurement of the Enantiomeric Excess
A. Meddour, P. Berdague, A. Hedli, J. Courtieu, and P. Lesot
Journal of the American Chemical Society 1997 119 (19), 4502-4508
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Synthesis of l-Daunosamine Derivatives on the Basis of the Asymmetric Dihydroxylation of 3-((E)-1-Propenyl)-4,5-dihydroisoxazole
Peter A. Wade, Stephen G. D'Ambrosio, Jetla Appa Rao, Sharmila Shah-Patel, Damien T. Cole, James K. Murray, Jr., and Patrick J. Carroll
The Journal of Organic Chemistry 1997 62 (11), 3671-3677
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CC-1065 and the Duocarmycins: Synthetic Studies
Dale L. Boger, Christopher W. Boyce, Robert M. Garbaccio, and Joel A. Goldberg
Chemical Reviews 1997 97 (3), 787-828
Abstract | Full Text HTML | PDF | PDF w/ Links
Prins Desymmetrization of a C₂-Symmetric Diol: Application to the Synthesis of 17-Deoxyroflamycoin
Scott D. Rychnovsky, Guang Yang, Yueqing Hu, and Uday R. Khire
The Journal of Organic Chemistry 1997 62 (10), 3022-3023
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An Easy Approach to the Synthesis of Optically Active vic-Diols: A New Single-Enzyme System
Olga Bortolini, Giancarlo Fantin, Marco Fogagnolo, Pier Paolo Giovannini, Alessandra Guerrini, and Alessandro Medici
The Journal of Organic Chemistry 1997 62 (6), 1854-1856
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Synthesis of Stipiamide and a New Multidrug Resistance Reversal Agent, 6,7-Dehydrostipiamide
Merritt B. Andrus and Salvatore D. Lepore
Journal of the American Chemical Society 1997 119 (9), 2327-2328
Abstract | Full Text HTML | PDF | PDF w/ Links
Determination of the Relative and Absolute Stereochemistry of Fostriecin (CI-920)
Dale L. Boger, Masataka Hikota, and Bryan M. Lewis
The Journal of Organic Chemistry 1997 62 (6), 1748-1753
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Toward an Understanding of the High Enantioselectivity in the Osmium-Catalyzed Asymmetric Dihydroxylation. 4. Electronic Effects in Amine-Accelerated Osmylations
Derek W. Nelson, Andreas Gypser, Pui Tong Ho, Hartmuth C. Kolb, Teruyuki Kondo, Hoi-Lun Kwong, Dominic V. McGrath, A. Erik Rubin, Per-Ola Norrby, Kevin P. Gable, and K. Barry Sharpless
Journal of the American Chemical Society 1997 119 (8), 1840-1858
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Highly Diastereoselective Synthesis of Pederic Acid Derivatives
William R. Roush, Thomas G. Marron, and Lance A. Pfeifer
The Journal of Organic Chemistry 1997 62 (3), 474-478
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Asymmetric Synthesis of a Series of Chiral AB₂ Monomers for Dendrimer Construction
James R. McElhanon, Mu-Jen Wu, Maya Escobar, Umer Chaudhry, Chun-Ling Hu, and Dominic V. McGrath
The Journal of Organic Chemistry 1997 62 (4), 908-915
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Total Synthesis of (+)-Aspicilin. The Naked Carbon Skeleton Strategy vs the Bioorganic Approach
Subhash C. Sinha and Ehud Keinan
The Journal of Organic Chemistry 1997 62 (2), 377-386
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Total Synthesis of (+)-Duocarmycin A, epi-(+)-Duocarmycin A and Their Unnatural Enantiomers: Assessment of Chemical and Biological Properties
Dale L. Boger, Jeffrey A. McKie, Takahide Nishi, and Tsuyoshi Ogiku
Journal of the American Chemical Society 1997 119 (2), 311-325
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Synthesis of Trimegestone: The First Industrial Application of Bakers' Yeast Mediated Reduction of a Ketone
Véronique Crocq, Christian Masson, Jacques Winter, Christian Richard, Guy Lemaitre, Jacques Lenay, Michel Vivat, Jean Buendia, and Denis Prat
Organic Process Research & Development 1997 1 (1), 2-13
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Conformational Analysis of Some trans-4,5-Diaryl-1,3-dioxolanes by CD Spectroscopy and Induction of Cholesteric Mesophases in Nematic Solvents: A Correlation between Twisting Power and Structure of the Dopant
Carlo Rosini, Gian Piero Spada, Gloria Proni, Stefano Masiero, and Simone Scamuzzi
Journal of the American Chemical Society 1997 119 (3), 506-512
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Ligand-Dependent Reversal of Facial Selectivity in the Asymmetric Dihydroxylation
Koen P. M. Vanhessche and K. Barry Sharpless
The Journal of Organic Chemistry 1996 61 (23), 7978-7979
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Recent Advances in the Chemoenzymatic Synthesis of Carbohydrates and Carbohydrate Mimetics
Harrie J. M. Gijsen, Lei Qiao, Wolfgang Fitz, and Chi-Huey Wong
Chemical Reviews 1996 96 (1), 443-474
Abstract | Full Text HTML | PDF | PDF w/ Links
Aciculitins A−C: Cytotoxic and Antifungal Cyclic Peptides from the Lithistid Sponge Aciculites orientalis
Carole A. Bewley, Haiyin He, David H. Williams, and D. John Faulkner
Journal of the American Chemical Society 1996 118 (18), 4314-4321
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Hydroxyl-Directed Reductive Cleavage of 3-Oxetanols as an Entry to Diastereomerically Pure 1,2-Diols
Thorsten Bach and Kristian Kather
The Journal of Organic Chemistry 1996 61 (11), 3900-3901
Abstract | Full Text HTML | PDF | PDF w/ Links
Facile Syntheses of Valiolamine and Its Diastereomers from (−)-Quinic Acid.¹ Nucleophilic Substitution Reactions of 5-(Hydroxymethyl)cyclohexane-1,2,3,4,5-pentol
Tony K. M. Shing and Leong H. Wan
The Journal of Organic Chemistry 1996 61 (24), 8468-8479
Abstract | Full Text HTML | PDF | PDF w/ Links
Desymmetrization of a Silyl-2,5-cyclohexadiene. Synthesis of (+)-Conduritol E and (−)-2-Deoxy-allo-inositol
Rémy Angelaud and Yannick Landais
The Journal of Organic Chemistry 1996 61 (16), 5202-5203
Abstract | Full Text HTML | PDF | PDF w/ Links
Addition of Alkynes and Alkenes to ReS₄^-: Reactivity Akin to OsO₄
Jonathan T. Goodman, Shinji Inomata, and Thomas B. Rauchfuss
Journal of the American Chemical Society 1996 118 (46), 11674-11675
Abstract | Full Text HTML | PDF | PDF w/ Links
Toward Chemical Libraries of Annonaceous Acetogenins. Total Synthesis of Trilobacin
Subhash C. Sinha, Anjana Sinha, Ahmad Yazbak, and Ehud Keinan
The Journal of Organic Chemistry 1996 61 (22), 7640-7641
Abstract | Full Text HTML | PDF | PDF w/ Links
An Olefin Metathesis Based Strategy for the Construction of the JKL, OPQ, and UVW Ring Systems of Maitotoxin
K. C. Nicolaou, M. H. D. Postema, E. W. Yue, and A. Nadin
Journal of the American Chemical Society 1996 118 (42), 10335-10336
Abstract | Full Text HTML | PDF | PDF w/ Links
Kinetic Investigations Provide Additional Evidence That an Enzyme-like Binding Pocket Is Crucial for High Enantioselectivity in the Bis-Cinchona Alkaloid Catalyzed Asymmetric Dihydroxylation of Olefins
E. J. Corey and Mark C. Noe
Journal of the American Chemical Society 1996 118 (2), 319-329
Abstract | Full Text HTML | PDF | PDF w/ Links
Efficient Stereospecific Synthesis of Diamide Analogs of Phosphatidylcholine Starting from 1-(4‘-Methoxyphenyl)-sn-glycerol
Hoe-Sup Byun and Robert Bittman
The Journal of Organic Chemistry 1996 61 (24), 8706-8708
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of (R)-(4-Methoxy-3,5-dihydroxyphenyl)glycine Derivatives: The Central Amino Acid of Vancomycin and Related Agents
Dale L. Boger, Robert M. Borzilleri, and Seiji Nukui
The Journal of Organic Chemistry 1996 61 (10), 3561-3565
Abstract | Full Text HTML | PDF | PDF w/ Links
Kinetic Resolution of Terminal Epoxides via Highly Regioselective and Enantioselective Ring Opening with TMSN₃. An Efficient, Catalytic Route to 1,2-Amino Alcohols
Jay F. Larrow, Scott E. Schaus, and Eric N. Jacobsen
Journal of the American Chemical Society 1996 118 (31), 7420-7421
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Total Synthesis of (+)-Duocarmycin A, epi-(+)-Duocarmycin A, and Their Unnatural Enantiomers
Dale L. Boger, Jeffrey A. McKie, Takahide Nishi, and Tsuyoshi Ogiku
Journal of the American Chemical Society 1996 118 (9), 2301-2302
Abstract | Full Text HTML | PDF | PDF w/ Links
On the Question of Asymmetric Induction with Acyclic Allylic Substrates. An Asymmetric Synthesis of (+)-Polyoxamic Acid
Barry M. Trost, A. Chris Krueger, Richard C. Bunt, and Jorge Zambrano
Journal of the American Chemical Society 1996 118 (27), 6520-6521
Abstract | Full Text HTML | PDF | PDF w/ Links
Highly threo-Selective Pinacol Coupling of Tricarbonylchromium Complexes of Benzaldehyde with Samarium(II) Diiodide
Nobukazu Taniguchi, Naotake Kaneta, and Motokazu Uemura
The Journal of Organic Chemistry 1996 61 (18), 6088-6089
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Molar Scale Synthesis of Enantiopure Stilbene Oxide
Han-Ting Chang and K. Barry Sharpless
The Journal of Organic Chemistry 1996 61 (18), 6456-6457
Abstract | Full Text HTML | PDF | PDF w/ Links
Highly Enantioselective Synthesis of Natural Phyllodulcin
Alessio Ramacciotti, Rita Fiaschi, and Elio Napolitano
The Journal of Organic Chemistry 1996 61 (16), 5371-5374
Abstract | Full Text HTML | PDF | PDF w/ Links
Acidic, Selective Monoacylation of vic-Diols
Masato Oikawa, Akira Wada, Fumiaki Okazaki, and Shoichi Kusumoto
The Journal of Organic Chemistry 1996 61 (13), 4469-4471
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An Enantiomeric Synthesis of allo-Threonines and β-Hydroxyvalines
Hui Shao and Murray Goodman
The Journal of Organic Chemistry 1996 61 (8), 2582-2583
Abstract | Full Text HTML | PDF | PDF w/ Links
Toward Chiral Dendrimers with Highly Functionalized Interiors. Dendrons from Synthetic AB₂ Monomers
James R. McElhanon, Mu-Jen Wu, Maya Escobar, and Dominic V. McGrath
Macromolecules 1996 29 (27), 8979-8982
Abstract | Full Text HTML | PDF | PDF w/ Links
Theory Does Not Support an Osmaoxetane Intermediate in the Osmium-Catalyzed Dihydroxylation of Olefins
Stefan Dapprich, Gregori Ujaque, Feliu Maseras, Agustí Lledós, Djamaladdin G. Musaev, and Keiji Morokuma
Journal of the American Chemical Society 1996 118 (46), 11660-11661
Abstract | Full Text HTML | PDF | PDF w/ Links
The Synthesis of C-Trisaccharides Exploiting the Stereochemical Diversity of a Central Sugar
Daniel P. Sutherlin and Robert W. Armstrong
Journal of the American Chemical Society 1996 118 (40), 9802-9803
Abstract | Full Text HTML | PDF | PDF w/ Links
Evaluation of Furan Photooxygenation as a Device for Construction of the Zaragozic Acid (Squalestatin) Core
Naoyoshi Maezaki, Harrie J. M. Gijsen, Li-Qiang Sun, and Leo A. Paquette
The Journal of Organic Chemistry 1996 61 (19), 6685-6692
Abstract | Full Text HTML | PDF | PDF w/ Links
Toward an Understanding of the High Enantioselectivity in the Osmium-Catalyzed Asymmetric Dihydroxylation. 3. New Insights into Isomeric Forms of the Putative Osmaoxetane Intermediate
Per-Ola Norrby, Heinrich Becker, and K. Barry Sharpless
Journal of the American Chemical Society 1996 118 (1), 35-42
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of [4,5-Bis(hydroxymethyl)-1,3-dithiolan-2-yl]nucleosides as Potential Inhibitors of HIV¹
Jonas Brånalt and Ingemar Kvarnström, Björn Classon and Bertil Samuelsson
The Journal of Organic Chemistry 1996 61 (11), 3611-3615
Abstract | Full Text HTML | PDF | PDF w/ Links
X-ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2-Diamine−OsO₄ Complex, Formally a 20-Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2-Diamine-Accelerated Dihydroxylation of Olefins by OsO₄
E. J. Corey, Sepehr Sarshar, Mihai D. Azimioara, Ronald C. Newbold, and Mark C. Noe
Journal of the American Chemical Society 1996 118 (33), 7851-7852
Abstract | Full Text HTML | PDF | PDF w/ Links
Anomalous Face-Selectivity in Sharpless Asymmetric Dihydroxylation of o-Allylbenzamides
Piero Salvadori, Stefano Superchi, and Filippo Minutolo
The Journal of Organic Chemistry 1996 61 (13), 4190-4191
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Synthesis of the Dihydroisocoumarin Moiety of AI-77-B via Copper-Mediated Cross-Coupling and Sharpless Asymmetric Dihydroxylation
Stefano Superchi, Filippo Minutolo, Dario Pini, and Piero Salvadori
The Journal of Organic Chemistry 1996 61 (9), 3183-3186
Abstract | Full Text HTML | PDF | PDF w/ Links
Soluble Polymer-Bound Ligand-Accelerated Catalysis: Asymmetric Dihydroxylation
Hyunsoo Han and Kim D. Janda
Journal of the American Chemical Society 1996 118 (32), 7632-7633
Abstract | Full Text HTML | PDF | PDF w/ Links
A Critical Analysis of the Mechanistic Basis of Enantioselectivity in the Bis-Cinchona Alkaloid Catalyzed Dihydroxylation of Olefins
E. J. Corey and Mark C. Noe
Journal of the American Chemical Society 1996 118 (45), 11038-11053
Abstract | Full Text HTML | PDF | PDF w/ Links
Chemical and Electrochemical Asymmetric Dihydroxylation of Olefins in I₂−K₂CO₃−K₂OsO₂(OH)₄ and I₂−K₃PO₄/K₂HPO₄−K₂OsO₂(OH)₄ Systems with Sharpless' Ligand
Sigeru Torii, Ping Liu, Narayanaswamy Bhuvaneswari, Christian Amatore, and Anny Jutand
The Journal of Organic Chemistry 1996 61 (9), 3055-3060
Abstract | Full Text HTML | PDF | PDF w/ Links
Complete Relative Stereochemistry of Maitotoxin
Wanjun Zheng, John A. DeMattei, Jiang-Ping Wu, James J.-W. Duan, Laura R. Cook, Hitoshi Oinuma, and Yoshito Kishi
Journal of the American Chemical Society 1996 118 (34), 7946-7968
Abstract | Full Text HTML | PDF | PDF w/ Links
Filipin III: Configuration Assignment and Confirmation by Synthetic Correlation
Timothy I. Richardson and Scott D. Rychnovsky
The Journal of Organic Chemistry 1996 61 (13), 4219-4231
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of Optically Pure Cyclic Lipoidal Ammonium Salts and Evaluation of Inhibition of Protein Kinase C
M. Patricia Hubieki, Richard D. Gandour, and Curtis L. Ashendel
The Journal of Organic Chemistry 1996 61 (26), 9379-9384
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis and Growth Inhibitory Properties of Glycosides of 1-O-Hexadecyl-2-O-methyl-sn-glycerol, Analogs of the Antitumor Ether Lipid ET-18-OCH₃ (Edelfosine)
José R. Marino-Albernas, Robert Bittman, Andrew Peters, and Eric Mayhew
Journal of Medicinal Chemistry 1996 39 (17), 3241-3247
Abstract | Full Text HTML | PDF | PDF w/ Links
Asymmetric Transition Metal-Catalyzed Allylic Alkylations
Barry M. Trost, David L. Van Vranken
Chemical Reviews 1996 96 (1), 395-422
Abstract | Full Text HTML | PDF | PDF w/ Links
Total Synthesis of (±)-Dihydrokawain-5-ol. Regioselective Monoprotection of Vicinal Syn-Diols Derived from the Iodocyclofunctionalization of α-Allenic Alcohols
Richard W. Friesen and Christopher Vanderwal
The Journal of Organic Chemistry 1996 61 (26), 9103-9110
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantioselective Syntheses of Syributin 1 and Novel C-Glycosidic Elicitors Syringolides 1 and 2
Toshio Honda, Hirotake Mizutani, and Kazuo Kanai
The Journal of Organic Chemistry 1996 61 (26), 9374-9378
Abstract | Full Text HTML | PDF | PDF w/ Links
Synthesis of Tuckolide, a New Cholesterol Biosynthesis Inhibitor
Merritt B. Andrus and Tzenge-Lien Shih
The Journal of Organic Chemistry 1996 61 (25), 8780-8785
Abstract | Full Text HTML | PDF | PDF w/ Links
Enantiocontrolled Synthesis of (+)-Boronolide
Toshio Honda, Satomi Horiuchi, Hirotake Mizutani, and Kazuo Kanai
The Journal of Organic Chemistry 1996 61 (15), 4944-4948
Abstract | Full Text HTML | PDF | PDF w/ Links
The application of a mechanistic model leads to the extension of the Sharpless asymmetric dihydroxylation to allylic 4-methoxybenzoates and conformationally related amine and homoallylic alcohol derivatives.
E. J. Corey, Angel Guzman-Perez, Mark C. Noe
Journal of the American Chemical Society 1995 117 (44), 10805-10816
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Kinetic Resolution by Enantioselective Dihydroxylation of Secondary Allylic 4-Methoxybenzoate Esters Using a Mechanistically Designed Cinchona Alkaloid Catalyst
E. J. Corey, Mark C. Noe, Angel Guzman-Perez
Journal of the American Chemical Society 1995 117 (44), 10817-10824
Abstract | PDF | PDF w/ Links

Article

Catalytic Asymmetric Dihydroxylation