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Enyne Metathesis (Enyne Bond Reorganization)
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Section:- 1. Introduction and Scope
- 2. Mechanism Families
- 2.1. Metal Salt-Catalyzed Enyne Bond Reorganization
- 2.2. Metal Carbene-Mediated Enyne Metathesis2.2.1. Fischer Carbene Complex-Catalyzed Enyne Metathesis
- 2.2.2. Enyne Metathesis with Ruthenium Carbenes
- 3. Synthetic Applications
- 3.1. Intramolecular Metathesis of Enynes3.1.1. Synthesis of Carbocycles and Various Heterocycles (O, N, P, Si) with Ring-Closing Enyne Metathesis
- 3.1.2. β-Lactams through Ring-Closing Enyne Metathesis
- 3.1.3. Unnatural Amino Acids Obtained through Ring-Closing Enyne Metathesis
- 3.1.4. Carbohydrates in Ring-Closing Enyne Metathesis
- 3.1.5. Medium- and Macro-Ring-Closing Enyne Metathesis
- 3.1.6. Ring-Closing Enyne Metathesis with Element-Substituted Alkynes
- 3.1.7. Natural Product Synthesis Employing Enyne Metathesis
- 3.2. Intermolecular Enyne Cross Metathesis
- 3.2.1 Reaction with Ethylene
- 3.2.2. Cross Metathesis with Higher Alkenes
- 3.2.3. Influence of Ethylene on Cross Metatheses
- 3.3. Tandem Metathesis and Domino Metathesis
- 4. Conclusion and Outlook
- 5. Acknowledgments
- 6. References
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- Published In Issue March 10, 2004
- Received June 5, 2003
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