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Template Synthesis of Macrocyclic Complexes: A Laboratory Project for Advanced Undergraduate Students
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Abstract
A family of tetraazamacrocyclic complexes of nickel(II) forms the basis of a convenient synthetic experiment for advanced undergraduates, highlighting the utility of the coordination template effect in promoting macrocyclic synthesis.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Inorganic ChemistryKeywords (Pedagogy):
Hands-On Learning / ManipulativesKeywords (Subject):
SynthesisCiting Articles
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This article has been cited by 4 ACS Journal articles (4 most recent appear below).
Nickel(II) Cyclidenes with Appended Ethylpyridine Receptor Centers as Molecular Tweezers for Dicarboxylic Acids
Jeremy S. Disch, Richard J. Staples, Thomas E. Concolino, Terry E. Haas, and Elena V. Rybak-AkimovaInorganic Chemistry2003 42 (21), 6749-6763Nickel(II) Cyclidenes with Appended Ethylpyridine Receptor Centers as Molecular Tweezers for Dicarboxylic Acids
Jeremy S. Disch, Richard J. Staples, Thomas E. Concolino, Terry E. Haas, and Elena V. Rybak-AkimovaInorganic Chemistry2003 42 (21), 6749-6763(2-Pyridyl)ethylamino-appended cyclidenes with varied platform sizes (I, x, y = 0; II, x = 0, y = 1; III, x, y = 1) were crystallography characterized and display planar, Z-configuration, and saddle shapes, respectively. Cyclidenes IIII were evaluated ...
Synthesis, Kinetics, and Thermodynamics: An Advanced Laboratory Investigation of the Cis-Trans Isomerization of Mo(CO)4(PR3)2
Kim E. Mooney , Ashfaq A. BengaliJournal of Chemical Education2003 80 (9), 1044Synthesis, Kinetics, and Thermodynamics: An Advanced Laboratory Investigation of the Cis-Trans Isomerization of Mo(CO)4(PR3)2
Kim E. Mooney , Ashfaq A. BengaliJournal of Chemical Education2003 80 (9), 1044An advanced laboratory experiment that requires students to thoroughly investigate the kinetics, thermodynamics, and the mechanism of the cis–trans isomerization of Mo(CO)4(PR3)2 (R = Et, n-butyl) is presented. The students synthesize the cis complex and ...
Ruthenium(II)-dppm Coordination Chemistry. An Advanced Inorganic Miniproject
Simon J. HigginsJournal of Chemical Education2001 78 (5), 663Ruthenium(II)-dppm Coordination Chemistry. An Advanced Inorganic Miniproject
Simon J. HigginsJournal of Chemical Education2001 78 (5), 663A guided miniproject involving aspects of Ru(II)-diphosphine complex synthesis and characterization, suitable for advanced undergraduate students, has been devised. It combines teaching of new synthetic and characterization techniques with the opportunity ...
Determination of the Regiochemistry of Disubstituted Arenes Generated by Addition of a Carbanion to the (η6-Anisole)Cr(CO)3 Complex
Ashfaq A. Bengali , Cindy Samet and Samantha B. CharltonJournal of Chemical Education2001 78 (1), 68Determination of the Regiochemistry of Disubstituted Arenes Generated by Addition of a Carbanion to the (η6-Anisole)Cr(CO)3 Complex
Ashfaq A. Bengali , Cindy Samet and Samantha B. CharltonJournal of Chemical Education2001 78 (1), 68It has become increasingly important to demonstrate to undergraduates that chemistry is not many separate subfields, but rather a set of interconnected concepts. We describe a laboratory activity that integrates fundamental concepts of organic and ...
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- Received: August 03, 2009
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