Article
Past, Present, and Possible Future Applications of Supercritical Fluid Extraction Technology
Purchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
While the research and industrial communities are wholehartedly embracing the use of supercritical fluid extraction (SFE) technology, little has been written about it in undergraduate texts or in educational journals such as the Journal of Chemical Education . The supercritical phenomenon of fluids was first discovered in the early 1800's by the Frenchman Baron Charles Cagniard de la Tour, but the significance and practical application of his discovery have only recently been recognized and achieved. This article presents a general overview of the principles of SFE and describes the instrumentation necessary to carry out an extraction using a supercirtical fluid. The reader will also gain insight into the types of research currently being conducted using supercritical fluids as either processing solvents or as reaction constituents and matrices. Because carbon dioxide is the supercritical fluid of choice for many procedures, its use and modification for specific solutes is covered in some detail.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Public Understanding / OutreachKeywords (Subject):
Industrial ChemistryCiting Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 21 ACS Journal articles (5 most recent appear below).

Applying a Fiber Optic Reflectometer to Phase Measurements in Subcritical and Supercritical Water Mixtures
Alexander A. Novitskiy, Jie Ke, Victor N. Bagratashvili, and Martyn PoliakoffThe Journal of Physical Chemistry C2011 115 (4), 1143-1149Applying a Fiber Optic Reflectometer to Phase Measurements in Subcritical and Supercritical Water Mixtures
Alexander A. Novitskiy, Jie Ke, Victor N. Bagratashvili, and Martyn PoliakoffThe Journal of Physical Chemistry C2011 115 (4), 1143-1149A corrosion study of optic fibers in sub- and supercritical water has been carried out to find a suitable fiber for performing phase behavior studies with a fiber optic reflectometer on mixtures containing water at high pressures and temperatures. ...

Extraction of Lycopene from Tomato Skin with Supercritical Carbon Dioxide: Effect of Operating Conditions and Solubility Analysis
Ummihan Topal, Mitsuru Sasaki, Motonobu Goto, and Kiro HayakawaJournal of Agricultural and Food Chemistry2006 54 (15), 5604-5610Extraction of Lycopene from Tomato Skin with Supercritical Carbon Dioxide: Effect of Operating Conditions and Solubility Analysis
Ummihan Topal, Mitsuru Sasaki, Motonobu Goto, and Kiro HayakawaJournal of Agricultural and Food Chemistry2006 54 (15), 5604-5610Supercritical carbon dioxide (SCCO2) extraction of lycopene from waste tomato skins was investigated. The experiments were carried out at pressures and temperatures ranging from 20 to 50 MPa and 313 to 373 K, respectively, without any modifiers. The flow ...

Uranyl Extraction by β-Diketonate Ligands to SC−CO2: Theoretical Studies on the Effect of Ligand Fluorination and on the Synergistic Effect of TBP
Nicolas Galand and Georges WipffThe Journal of Physical Chemistry B2005 109 (1), 277-287Uranyl Extraction by β-Diketonate Ligands to SC−CO2: Theoretical Studies on the Effect of Ligand Fluorination and on the Synergistic Effect of TBP
Nicolas Galand and Georges WipffThe Journal of Physical Chemistry B2005 109 (1), 277-287We report theoretical investigations on the effect of H → F substitution in acetylacetonate ligands in order to understand why fluorination promotes the extraction of uranyl to supercritical CO2 with a marked synergistic effect of tri-n-butyl phosphate “...

Pressure-Assisted Chelating Extraction as a Teaching Tool in Instrumental Analysis
Omowunmi A. Sadik , Adam K. Wanekaya and Gelfand YevgenyJournal of Chemical Education2004 81 (8), 1177Pressure-Assisted Chelating Extraction as a Teaching Tool in Instrumental Analysis
Omowunmi A. Sadik , Adam K. Wanekaya and Gelfand YevgenyJournal of Chemical Education2004 81 (8), 1177This article describes a laboratory procedure designed for a junior-level instrumental analysis course using a pressure-assisted chelating extraction (PACE) technique to digest heavy metals from solid matrices. PACE can achieve the digestion of metals ...

Pressure−Density−Temperature Behavior of CO2/Acetone, CO2/Toluene, and CO2/Monochlorobenzene Mixtures in the Near-Critical Region
Jialong Wu, Qinmin Pan, and Garry L. RempelJournal of Chemical & Engineering Data2004 49 (4), 976-979Pressure−Density−Temperature Behavior of CO2/Acetone, CO2/Toluene, and CO2/Monochlorobenzene Mixtures in the Near-Critical Region
Jialong Wu, Qinmin Pan, and Garry L. RempelJournal of Chemical & Engineering Data2004 49 (4), 976-979An isochoric technique was used to perform P−ρ−T measurements of CO2/acetone, CO2/toluene, and CO2/monochlorobenzene mixtures where the mol fraction of CO2 is 0.9 at temperatures from 313.2 to 393.2 K, the density of mixtures varied from 2.91 to 15.77 mol/...
Tools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Received: August 03, 2009
Cart

ACS
Network






