Superabsorbent Polymers: An Idea Whose Time Has Come

Fredric L. Buchholz
The Dow Chemical Company, 1603 Building, Midland, MI 48674
J. Chem. Educ., 1996, 73 (6), p 512
DOI: 10.1021/ed073p512
Publication Date (Web): June 1, 1996

Abstract

Superabsorbent polymers are cross-linked polyelectrolytes. Because of their ionic nature and interconnected structure, they absorb large quantities of water and other aqueous solutions without dissolving. This makes them ideally suited as absorbents of body fluids in many personal care products sold today, including baby diapers, adult incontinence products, and feminine napkins. Several emerging applications are also described. A simple laboratory preparation of partially neutralized, cross-linked poly(acrylic acid) is given along with test methods suitable for measuring the absorption capacity of the product. Experiments are described that demonstrate the ability of a swelling gel to perform work, and the ability of a gel to exclude macromolecular solutes from diffusing into its porous, cross-linked structure.

Keywords (Audience):

First-Year Undergraduate / General

Keywords (Domain):

Laboratory Instruction

Keywords (Feature):

Products of Chemistry

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Polymerization

Citing Articles

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This article has been cited by 6 ACS Journal articles (5 most recent appear below).

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      This activity explores an alternative use of a superabsorbent polymer known as a water absorbing material. A dilute solution of CuCl2 is treated with a small piece of unused disposable diaper containing superabsorbent sodium polyacrylates. The polymer is ...

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    Yueh-Huey Chen , Jing-Fun Yaung
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    • Coloring a Superabsorbent Polymer with Metal Ions. An Undergraduate Chemistry Experiment

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  • Received: August 03, 2009

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