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The Synthesis and Reactions of Nickel(III) Stabilized by a Nitrogen-Donor Macrocycle

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David E. Berry , Suzanne Girard and Alexander McAuley

University of Victoria, Victoria, BC, Canada, V8W 3P6

J. Chem. Educ., 1996, 73 (6), p 551

DOI: 10.1021/ed073p551

Publication Date (Web): June 1, 1996

Section:

History, Education, and Documentation

Abstract

This experiment describes the synthesis of 1,4,8,11-tetraazacyclotetradecane and its nickel(II and III) complexes avoiding the use of percholrate anion. The paramagnetic effects in solution and solid state are described for the nickel(III) dihalo derivatives along with a spectrophotometric study.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Inorganic Chemistry

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Magnetic Properties

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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

Zirconium Complexes of a Cross-Bridged Cyclam
Paul O'Connor, David J. Berg, and Brendan Twamley
Organometallics2005 24 (1), 28-36
- Zirconium Complexes of a Cross-Bridged Cyclam
  Paul O'Connor, David J. Berg, and Brendan Twamley
  Organometallics2005 24 (1), 28-36
  The rigid macrocycle incorporating an ethylene bridge across cyclam (cross-bridged cyclam, CBC) allows preparation of a wide variety of (CBC)ZrX2 species including the zirconacyclopentadiene (CBC)Zr(C4Ph4). Crystallographic studies show that the geometry ...
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