Bonding and Molecular Geometry without Orbitals - The Electron Domain Model

Ronald J. Gillespie
Department of Chemistry, McMaster University, Hamilton, ON L8S 4M1, Canada
James N. Spencer and Richard S. Moog
Department of Chemistry, Franklin and Marshall College, Lancaster, PA 17604-3003
J. Chem. Educ., 1996, 73 (7), p 622
DOI: 10.1021/ed073p622
Publication Date (Web): July 1, 1996

Abstract

An alternative to the conventional valence bond approach to bonding and geometry-the electron domain model-is presented. This approach avoids some of the problems with the standard approach and presents fewer difficulties for the student, while still providing a physical basis for the VSEPR model and a link to the valence bond model. The electron domain model also emphasizes the importance of the Pauli principle in understanding the chemical bond and molecular geometry.

Keywords (Audience):

First-Year Undergraduate / General

Keywords (Feature):

Demystifying Introductory Chemistry

Keywords (Subject):

Atomic Properties / Structure

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History

  • Received: August 03, 2009

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