Article
Electrospray Ionization Mass Spectrometry: Part III: Applications in Inorganic Chemistry and Synthetic Polymer Chemistry
Purchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
The introduction of electrospray ionization mass spectrometry (ESI-MS) in the mid-1980s started a new era in mass spectrometry and, currently, mass spectrometers of this type are present in virtually all pharmaceutical and biotechnology laboratories. Mass spectrometry has now become important for obtaining molecular weights as well as structural information for chemical substances including very large molecules, for example, biological substances such as proteins, carbohydrates, and oligonucleotides. This paper extends the applications of ESI-MS in this series to a variety of inorganic systems.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Inorganic ChemistryKeywords (Feature):
Topics in Chemical InstrumentationKeywords (Subject):
Instrumental MethodsCiting Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 9 ACS Journal articles (5 most recent appear below).

Using the Mini-Session Course Format To Train Students in the Practical Aspects of Modern Mass Spectrometry
Dale A. Rosado, Jr., Tina S. Masterson, and Douglas S. MastersonJournal of Chemical Education2011 88 (2), 178-183Using the Mini-Session Course Format To Train Students in the Practical Aspects of Modern Mass Spectrometry
Dale A. Rosado, Jr., Tina S. Masterson, and Douglas S. MastersonJournal of Chemical Education2011 88 (2), 178-183Mass spectrometry (MS) has been gaining in popularity in recent years owing in large part to the development of soft-ionization techniques such as matrix-assisted laser desorption ionization (MALDI) and electrospray ionization (ESI). These soft-ionization ...

Reactions of a Coordination Polymer Based on the Triangular Cluster [Cu3(μ3-OH)(μ-pz)3]2+ with Strong Acids. Crystal Structure and Supramolecular Assemblies of New Mono-, Tri-, and Hexanuclear Complexes and Coordination Polymers
Corrado Di Nicola, Federica Garau, Massimo Gazzano, Magda Monari, Luciano Pandolfo, Claudio Pettinari and Riccardo PettinariCrystal Growth & Design2010 10 (7), 3120-3131Reactions of a Coordination Polymer Based on the Triangular Cluster [Cu3(μ3-OH)(μ-pz)3]2+ with Strong Acids. Crystal Structure and Supramolecular Assemblies of New Mono-, Tri-, and Hexanuclear Complexes and Coordination Polymers
Corrado Di Nicola, Federica Garau, Massimo Gazzano, Magda Monari, Luciano Pandolfo, Claudio Pettinari and Riccardo PettinariCrystal Growth & Design2010 10 (7), 3120-3131A series of mono-, tri-, hexanuclear compounds, and coordination polymers were obtained from the reaction of [Cu3(μ3-OH)(μ-pz)3(MeCOO)2(Hpz)], 1, (Hpz = pyrazole) with H2SO4, H3PO4, HClO4, HNO3, CF3COOH, and CF3SO3H. The trinuclear [Cu3(μ3-OH)(μ-pz)3(SO4)(...

Illustrating the Concepts of Isotopes and Mass Spectrometry in Introductory Courses: A MALDI-TOF Mass Spectrometry Laboratory Experiment
Nancy Carter Dopke and Timothy Neal LovettJournal of Chemical Education2007 84 (12), 1968Illustrating the Concepts of Isotopes and Mass Spectrometry in Introductory Courses: A MALDI-TOF Mass Spectrometry Laboratory Experiment
Nancy Carter Dopke and Timothy Neal LovettJournal of Chemical Education2007 84 (12), 1968Mass spectrometry is a widely used and versatile tool for scientists in many different fields. Soft ionization techniques such as matrix-assisted laser desorption/ionization (MALDI) allow for the analysis of biomolecules, polymers, and clusters. This ...

Variable Coordination Modes of NO2- in a Series of Ag(I) Complexes Containing Triorganophosphines, -arsines, and -stibines. Syntheses, Spectroscopic Characterization (IR, 1H and 31P NMR, Electrospray Ionization Mass), and Structures of [AgNO2(R3E)x] Adducts (E = P, As, Sb, x = 1−3)
Augusto Cingolani, Effendy, Maura Pellei, Claudio Pettinari, Carlo Santini, Brian W. Skelton, and Allan H. WhiteInorganic Chemistry2002 41 (25), 6633-6645Variable Coordination Modes of NO2- in a Series of Ag(I) Complexes Containing Triorganophosphines, -arsines, and -stibines. Syntheses, Spectroscopic Characterization (IR, 1H and 31P NMR, Electrospray Ionization Mass), and Structures of [AgNO2(R3E)x] Adducts (E = P, As, Sb, x = 1−3)
Augusto Cingolani, Effendy, Maura Pellei, Claudio Pettinari, Carlo Santini, Brian W. Skelton, and Allan H. WhiteInorganic Chemistry2002 41 (25), 6633-6645Adducts of triorganophosphine, triphenylarsine, and triphenylstibine with silver(I) nitrite have been synthesized and characterized both in solution (1H, 31P NMR) and in the solid state (IR, single-crystal X-ray structure analysis). In addition aggregates ...

Gold(III) Complexes as Potential Antitumor Agents: Solution Chemistry and Cytotoxic Properties of Some Selected Gold(III) Compounds
Luigi Messori, Francesco Abbate, Giordana Marcon, Pierluigi Orioli, Marco Fontani, Enrico Mini, Teresita Mazzei, Stefania Carotti, Tim O'Connell, and Piero ZanelloJournal of Medicinal Chemistry2000 43 (19), 3541-3548Gold(III) Complexes as Potential Antitumor Agents: Solution Chemistry and Cytotoxic Properties of Some Selected Gold(III) Compounds
Luigi Messori, Francesco Abbate, Giordana Marcon, Pierluigi Orioli, Marco Fontani, Enrico Mini, Teresita Mazzei, Stefania Carotti, Tim O'Connell, and Piero ZanelloJournal of Medicinal Chemistry2000 43 (19), 3541-3548Gold(III) complexes generally exhibit interesting cytotoxic and antitumor properties, but until now, their development has been heavily hampered by their poor stability under physiological conditions. To enhance the stability of the gold(III) center, we ...
Tools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Received: August 03, 2009
Cart

ACS
Network






