Metal Complexes of EDTA: An Exercise in Data Interpretation

Philip C. H. Mitchell
University of Reading, Department of Chemistry, Reading RG6 2AD, UNITED KINGDOM
J. Chem. Educ., 1997, 74 (10), p 1235
DOI: 10.1021/ed074p1235
Publication Date (Web): October 1, 1997

Abstract

Stability constants of metal complexes of edta with main group and transition metals are correlated with properties of the elements and cations (ion charge, atomic and ionic radii, ionization energies and electronegativities) and interpreted with an ionic bonding model including a covalent contribution. Enthalpy and entropy contributions are discussed. It is shown how chemists recognize patterns in data with the help of a general theory and so develop a model.

Keywords (Audience):

Second-Year Undergraduate

Keywords (Domain):

Inorganic Chemistry

Keywords (Subject):

Metals

Citing Articles

View all 3 citing articles

Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.

This article has been cited by 3 ACS Journal articles (3 most recent appear below).

  • Cover Image

    Determination of Copper and Zinc in Brass: Two Basic Methods

    Paul-Louis Fabre and Olivier Reynes
    Journal of Chemical Education2010 87 (8), 836-837
    • Determination of Copper and Zinc in Brass: Two Basic Methods

      Paul-Louis Fabre and Olivier Reynes
      Journal of Chemical Education2010 87 (8), 836-837

      In this experiment, the concentrations of copper and zinc in brass are obtained by two methods. This experiment does not require advanced instrumentation, uses inexpensive chemicals, and can be easily carried out during a 3-h upper-level undergraduate ...

  • Cover Image

    Solubility of Alkali and Alkali Earth Salts of Dihydrogen Ethylenediaminetetraacetate in Aqueous Solutions

    Antonio R. Fiorucci, Leonardo R. de Paula, Eduardo A. Neves, and Éder T. G. Cavalheiro
    Journal of Chemical & Engineering Data2002 47 (6), 1510-1513
    • Solubility of Alkali and Alkali Earth Salts of Dihydrogen Ethylenediaminetetraacetate in Aqueous Solutions

      Antonio R. Fiorucci, Leonardo R. de Paula, Eduardo A. Neves, and Éder T. G. Cavalheiro
      Journal of Chemical & Engineering Data2002 47 (6), 1510-1513

      The solid metal−EDTA compounds K2H2Y·2H2O, MgH2Y·6H2O, CaH2Y·2H2O, SrH2Y·2H2O, and BaH2Y·3H2O (H2Y2- is dihydrogen ethylenediaminetetraacetate anion) prepared from aqueous media were characterized by elemental analysis, IR spectrometry, and ...

  • Cover Image

    pH and Ion-Triggered Volume Response of Anionic Hydrogel Microspheres

    Gary M. Eichenbaum, Patrick F. Kiser, Sidney A. Simon, and David Needham
    Macromolecules1998 31 (15), 5084-5093
    • pH and Ion-Triggered Volume Response of Anionic Hydrogel Microspheres

      Gary M. Eichenbaum, Patrick F. Kiser, Sidney A. Simon, and David Needham
      Macromolecules1998 31 (15), 5084-5093

      Micrometer-sized (47 m diameter) poly(methacrylic acid) (PMAA) hydrogel microspheres were synthesized by precipitation polymerization. Individual microspheres were held in a micropipet and visualized by interference contrast microscopy. They were ...

Tools

SciFinder Links

SciFinder subscribers:  Click to sign in | Not a SciFinder subscriber? Learn more at www.cas.org

Explore by:


History

  • Received: August 03, 2009

Recommend & Share

  • Share on ACS NetworkACS Network
  • Add to FacebookFacebook
  • Tweet ThisTweet This
  • Add to CiteULikeCiteULike
  • Add to NewsvineNewsvine
  • Digg ThisDigg This
  • Add to DeliciousDelicious

Related Content