Article
Photochemistry of Benzophenone in 2-Propanol: An Easy Experiment for Undergraduate Physical Chemistry Courses
Purchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
In this article we describe a laboratory experiment for undergraduate physical chemistry courses dealing with the photophysics and photochemistry of benzophenone in 2-propanol. This is an easy-to-perform experiment aimed to introduce the basic concepts of photochemistry which may help to achieve a systematic approach to the subject, incorporating related topics of chemical kinetics and molecular spectroscopy. This experiment provides quantitative data regarding the lifetime of short-lived excited states, which does not require expensive time resolved techniques.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Physical ChemistryKeywords (Pedagogy):
Hands-On Learning / ManipulativesKeywords (Subject):
PhotochemistryCiting Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 5 ACS Journal articles (5 most recent appear below).

Photochemical Size Reduction of CdSe and CdSe/ZnS Semiconductor Nanoparticles Assisted by nπ* Aromatic Ketones
Raquel E. Galian, Miguel de la Guardia and Julia Pérez-PrietoJournal of the American Chemical Society2009 131 (3), 892-893Photochemical Size Reduction of CdSe and CdSe/ZnS Semiconductor Nanoparticles Assisted by nπ* Aromatic Ketones
Raquel E. Galian, Miguel de la Guardia and Julia Pérez-PrietoJournal of the American Chemical Society2009 131 (3), 892-893A novel effect of nπ* aromatic ketones on the quantum dots optical properties is reported. By controlling experimental conditions such as time of irradiation, presence of air in the media, hydrogen donor capacity of the solvent, and irradiation wavelength,...

Modern Developments in the Physical Chemistry Laboratory
Samuel A. Abrash2007 973 (), 115-151Modern Developments in the Physical Chemistry Laboratory
Samuel A. Abrash2007 973 (), 115-151Developments in the physical chemistry laboratory since the publication of the germinal text by Schwenz and Moore (1) are categorized and reviewed. The categories examined include modern instrumentation, current topics in chemistry, integrated ...

Small Scale Reactor for Ultraviolet Photochemistry
James E. Gano , Andrew J. Gano , Patricia Garry and Padmanabhan SekherJournal of Chemical Education2002 79 (11), 1361Small Scale Reactor for Ultraviolet Photochemistry
James E. Gano , Andrew J. Gano , Patricia Garry and Padmanabhan SekherJournal of Chemical Education2002 79 (11), 1361A simple, versatile, inexpensive, synthetic photochemical reactor is described. A variety of wavelengths, such as 214 (Zn), 229 (Cd), and 254 nm (Hg), can be applied to gram quantities of material. It can be constructed using modest glassblowing skills.

Ultrasound Effects on the Photopinacolization of Benzophenone
Anton Gaplovsky, Martin Gaplovsky, Stefan Toma, and Jean-Louis LucheThe Journal of Organic Chemistry2000 65 (25), 8444-8447Ultrasound Effects on the Photopinacolization of Benzophenone
Anton Gaplovsky, Martin Gaplovsky, Stefan Toma, and Jean-Louis LucheThe Journal of Organic Chemistry2000 65 (25), 8444-8447Ultrasonic irradiation is able to modify the course of several photochemical reactions, especially bimolecular, proceeding via triplet states. These effects were illustrated in the study of benzophenone photopinacolization in ethanol. The rates and yields ...

Acetone-Photosensitized Reduction of Carbon Tetrachloride by 2-Propanol in Aqueous Solution
Eric A. Betterton, Nadia Hollan, Robert G. Arnold, Stefan Gogosha, Krista McKim, and Zhijie LiuEnvironmental Science & Technology2000 34 (7), 1229-1233Acetone-Photosensitized Reduction of Carbon Tetrachloride by 2-Propanol in Aqueous Solution
Eric A. Betterton, Nadia Hollan, Robert G. Arnold, Stefan Gogosha, Krista McKim, and Zhijie LiuEnvironmental Science & Technology2000 34 (7), 1229-1233Simple carbonyl chromophores can be used to facilitate the solar-promoted reductive dehalogenation of halo-organics. Here we describe the kinetics and mechanism of the reductive dehalogenation of carbon tetrachloride (CT) to chloroform (CF) in the ...
Tools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Received: August 03, 2009
Cart

ACS
Network






