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The Phase-Transfer Catalyzed Preparation of Mo(CO)4(dphos): An Intermediate-Level Organometallic-Inorganic Experiment
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Abstract
Mo(CO)4(diphos) may be prepared by the phase transfer catalysed substitution of Mo(CO)6 with diphos in the presence of Bu4NI. The complex may be characterised by infrared and 1H and 13C NMR spectroscopy.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Inorganic ChemistryKeywords (Pedagogy):
Hands-On Learning / ManipulativesKeywords (Subject):
OrganometallicsCiting Articles
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This article has been cited by 3 ACS Journal articles (3 most recent appear below).
Synthesis of Bis(1,2-dimethylimidazole)copper(I) Hexafluorophosphate: An Experiment Using a Glove Box
J. H. Niewahner and Keith A. WaltersJournal of Chemical Education2007 84 (4), 702Synthesis of Bis(1,2-dimethylimidazole)copper(I) Hexafluorophosphate: An Experiment Using a Glove Box
J. H. Niewahner and Keith A. WaltersJournal of Chemical Education2007 84 (4), 702Laboratory instructions for a glove box experiment involving the synthesis of the compound bis(1,2-dimethylimidazole)copper(I) hexafluorophosphate are given. This synthesis (modified from a previous literature article) can be completed in a four-hour lab ...
Microwave-Assisted Reflux in Organometallic Chemistry: Synthesis and Structural Determination of Molybdenum Carbonyl Complexes. An Intermediate-Level Organometallic-Inorganic Experiment
Michael Ardon , Philip D. Hayes and Graeme HogarthJournal of Chemical Education2002 79 (10), 1249Microwave-Assisted Reflux in Organometallic Chemistry: Synthesis and Structural Determination of Molybdenum Carbonyl Complexes. An Intermediate-Level Organometallic-Inorganic Experiment
Michael Ardon , Philip D. Hayes and Graeme HogarthJournal of Chemical Education2002 79 (10), 1249Simple modification of a household microwave oven leads to the acceleration of chemical reactions as a result of microwave-assisted reflux. This acceleration is illustrated in the reactions of metal–carbonyls where the M–CO bond is notoriously inert. ...
Synthesis and Reactivity of the Metallaborane Complex [Mo(CO)4B3H8]- and the Formation of Mo(CO)4(dppe)
Craig M. Davis and Megan F. KleinJournal of Chemical Education2001 78 (7), 952Synthesis and Reactivity of the Metallaborane Complex [Mo(CO)4B3H8]- and the Formation of Mo(CO)4(dppe)
Craig M. Davis and Megan F. KleinJournal of Chemical Education2001 78 (7), 952In this laboratory exercise the octahydrotriborate anion ([B3H8]-) is synthesized from sodium borohydride (NaBH4) and iodine in diglyme under a nitrogen atmosphere, and the sodium salt is converted to the tetrabutylammonium salt by a simple metathesis. ...
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- Received: August 03, 2009
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