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Inorganic Photolithography: Interfacial Multicomponent Pattern Generation
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Abstract
Photolithography is one approach to the development of a "molecular architecture" of interfaces. To date, four different systems for creating high resolution inorganic microstructures through photolithography have been developed: Schanze and Meyer have used electrodes that have been chemically modified with an organometallic Ru polymer, Gafney has photolyzed metal carbonyls adsorbed into porous glass, and we have polymerized a multimetal, intervalent charge transfer complex onto ITO coated glass. Various features have been created, including Meyer's dots, Gafney's postage stamp sized periodic table, potential switchable grating of Schanze, and our potential switchable diffraction grating and reproduction of a full color American flag. Structures down to micron resolution have been demonstrated.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Inorganic ChemistryKeywords (Feature):
Symposium ReportKeywords (Subject):
Coordination CompoundsCiting Articles
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This article has been cited by 5 ACS Journal articles (5 most recent appear below).
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Photochemical Image Generation in a Cyanogel System Synthesized from Tetrachloropalladate(II) and the Trimetallic Mixed-Valence Complex [(NC)5FeII−CN−PtIV(NH3)4−NC−FeII(CN)5]4-: Consideration of Photochemical and Dark Mechanistic Pathways of Prussian Blue Formation
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David F. Watson, Jennifer L. Willson, and Andrew B. BocarslyInorganic Chemistry2002 41 (9), 2408-2416Aqueous tetrachloropallate(II) undergoes a solgel reaction with the mixed-valence complex [(NC)5FeIICNPtIV(NH3)4NCFeII(CN)5]4- to form a hydrogel polymer system in the cyanogel family. Once gelled, visible irradiation into the Fe(II) Pt(IV) IT band ...
Photolithographically-Patterned Electroactive Films and Electrochemically Modulated Diffraction Gratings
Kirk S. Schanze, Troy S. Bergstedt, Brain T. Hauser, and Carla S. P. CavalaheiroLangmuir2000 16 (2), 795-810Photolithographically-Patterned Electroactive Films and Electrochemically Modulated Diffraction Gratings
Kirk S. Schanze, Troy S. Bergstedt, Brain T. Hauser, and Carla S. P. CavalaheiroLangmuir2000 16 (2), 795-810This manuscript presents an overview of work directed toward the creation of arbitrary micron-scale patterns of electroactive polymer films by the application of photolithography. A brief overview of work by other groups in the field is followed by a ...
Redox Reactivity as the Controlling Element in Coordination Polymer Stereochemistry: Redox-Switched Growth Mechanism in the [FeII−CN−PtIV]n System
Clark Chang, David Ludwig, and Andrew BocarslyInorganic Chemistry1998 37 (21), 5467-5473Redox Reactivity as the Controlling Element in Coordination Polymer Stereochemistry: Redox-Switched Growth Mechanism in the [FeII−CN−PtIV]n System
Clark Chang, David Ludwig, and Andrew BocarslyInorganic Chemistry1998 37 (21), 5467-5473Coordination oligomers and polymers composed of [(CN)5FeIICNPtIV(NH3)4] units have been synthesized. The oligomer growth mechanism is based on the oxidation state of the iron centers which can be specified either chemically or electrochemically to allow ...
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- Received: August 03, 2009
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