Cart
Report
Applications of Luminescent Transition Metal Complexes to Sensor Technology and Molecular Probes
Hi-Res PDFPurchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
An overview of the applications of luminescent transition metal complexes to sensor technology is presented. In addition to general considerations, a number of specific systems are discussed including oxygen, pH, carbon dioxide, temperature, and immunoassay sensors. Applications of the complexes to molecular probes are also covered including chirality and conformational proves, water exposure sensors, and dynamic probes. Problem areas such as photostability, excitability, immobilization chemistry, the existence multiple responses in the same molecule, and substrate-support interactions are discussed. Also covered is the very difficulty problem of unambiguously interpreting the complex kinetic and chemical behavior of real sensor systems.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Inorganic ChemistryKeywords (Feature):
Symposium ReportKeywords (Subject):
Materials ScienceCiting Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 32 ACS Journal articles (5 most recent appear below).
Cu(II), Co(II), and Mn(II) Complexes of Rhodamine C and Rhodamine 640 Perchlorate: Synthesis, Spectroscopic, Thermal, Fluorescence, and Photostability Studies
Moamen S. Refat, Hamada M.A. Killa, Asmaa F. Mansour, Mohamed Y. Ibrahim, and Hammad FetoohJournal of Chemical & Engineering Data2011 Article ASAPCu(II), Co(II), and Mn(II) Complexes of Rhodamine C and Rhodamine 640 Perchlorate: Synthesis, Spectroscopic, Thermal, Fluorescence, and Photostability Studies
Moamen S. Refat, Hamada M.A. Killa, Asmaa F. Mansour, Mohamed Y. Ibrahim, and Hammad FetoohJournal of Chemical & Engineering Data2011 Article ASAPA goal of our work was to design and synthesize novel Mn(II), Co(II), and Cu(II) complexes with rhodamine C (RHC) and rhodamine 640 perchlorate (RHP) to obtain knowledge about the thermal stability of rhodamine itself compared with its complexes. The ...
Synthesis and Characterization of Luminescent Bis-Cyclometalated PlatinumIV Complexes
Dustin M. Jenkins and Stefan BernhardInorganic Chemistry2010 49 (24), 11297-11308Synthesis and Characterization of Luminescent Bis-Cyclometalated PlatinumIV Complexes
Dustin M. Jenkins and Stefan BernhardInorganic Chemistry2010 49 (24), 11297-11308Presented is the synthesis and characterization of a series of luminescent heteroleptic bis-cyclometalated platinumIV complexes. An oxidation-facilitated cyclometalation is employed to convert platinumII pendant species into bis-cyclometalated platinumIV ...
Can Luminescent Ru(II) Polypyridyl Dyes Measure pH Directly?
Laura Tormo, Nelia Bustamante, Gonzalo Colmenarejo and Guillermo OrellanaAnalytical Chemistry2010 82 (12), 5195-5204Can Luminescent Ru(II) Polypyridyl Dyes Measure pH Directly?
Laura Tormo, Nelia Bustamante, Gonzalo Colmenarejo and Guillermo OrellanaAnalytical Chemistry2010 82 (12), 5195-5204Two molecularly engineered Ru(II) complexes for direct pH optosensing in environmental or physiological media based on luminescence lifetime measurements—namely, Na2[Ru(bpds)2(F15ap)] and Na2[Ru(pbbs)2(pyim)] (where bpds = 2,2′-bipyridine-4,4′-disulfonate,...
Luminescent Low-Valent Rhenium Complexes with 1,2-Bis(dialkylphosphino)ethane Ligands. Synthesis and X-ray Crystallographic, Electrochemical, and Spectroscopic Characterization
Stephania J. Messersmith, Kristin Kirschbaum and Jon R. KirchhoffInorganic Chemistry2010 49 (8), 3857-3865Luminescent Low-Valent Rhenium Complexes with 1,2-Bis(dialkylphosphino)ethane Ligands. Synthesis and X-ray Crystallographic, Electrochemical, and Spectroscopic Characterization
Stephania J. Messersmith, Kristin Kirschbaum and Jon R. KirchhoffInorganic Chemistry2010 49 (8), 3857-3865A series of low-valent rhenium phosphine complexes with the general formula [Re(dmpe)3−x(depe)x]2+/+ (x = 0−3), where dmpe is 1,2-bis(dimethylphosphino)ethane and depe is 1,2-bis(diethylphosphino)ethane, were synthesized and characterized. The reaction of ...
Excited State Localization and Internuclear Interactions in Asymmetric Ruthenium(II) and Osmium(II) bpy/tpy Based Dinuclear Compounds
Yvonne Halpin, Danilo Dini, Hamid M. Younis Ahmed, Lynda Cassidy, Wesley R. Browne and Johannes G. VosInorganic Chemistry2010 49 (6), 2799-2807Excited State Localization and Internuclear Interactions in Asymmetric Ruthenium(II) and Osmium(II) bpy/tpy Based Dinuclear Compounds
Yvonne Halpin, Danilo Dini, Hamid M. Younis Ahmed, Lynda Cassidy, Wesley R. Browne and Johannes G. VosInorganic Chemistry2010 49 (6), 2799-2807The synthesis of two asymmetric dinuclear complexes with the formula [M(bpy)2(bpt)Ru(tpy)Cl]2+, where M = Ru (1a), Os(2a); bpy = 2,2′-bipyridyl; Hbpt = 3,5-bis(pyridin-2-yl)1,2,4-triazole and tpy = 2,2′,6′,2′′-terpyridine, is reported. The compounds ...
Full Text HTMLTools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Received: August 03, 2009
ACS
Network
Facebook
Tweet This
CiteULike
Newsvine
Digg This
Delicious
