Propagating Fronts of Polymerization in the Physical Chemistry Laboratory

John A. Pojman , William W. West and Jennifer Simmons
Department of Chemistry and Biochemistry, University of Southern Mississippi, Hattiesburg, MS 39406
J. Chem. Educ., 1997, 74 (6), p 727
DOI: 10.1021/ed074p727
Publication Date (Web): June 1, 1997

Abstract

Here we report a simple and inexpensive experiment with propagating fronts of addition polymerization that demonstrates a method of testing the steady-state model of polymerization and includes the effects of heat losses and gravity on a chemical reaction. The experiment we describe involves a novel approach to polymeric materials synthesis but requires no more than test tubes, two inexpensive chemicals, a ruler, and a stopwatch.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Physical Chemistry

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Kinetics

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This article has been cited by 2 ACS Journal articles (2 most recent appear below).

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History

  • Received: August 03, 2009

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